• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.311-311
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• 2011

$TiN{\times}$박막은 우수한 내마모성 및 내부식성, 높은 경도 그리고 열적 안정성 등으로 인하여, 절삭공구 및 기계적 부품의 하드코팅, 2차 연료 전지용 확산방지막의 코팅재료로서 광범위하게 사용되어지고 있다. 일반적으로 $TiN{\times}$ 박막은 화학 기상 증착법(CVD)을 이용하였으나, 최근에는 대면적에 균일한 코팅이 가능하고 기판과 박막상의 부착력이 우수하며, 프로세스를 제어하기 쉬운 물리적 기상 증착법(PVD)의 스퍼터링법에 대한 관심이 고조되고 있다. 그러나 스퍼터링법으로 증착된 $TiN{\times}$ 박막의 물성은 주상구조와 국부적 표면결함을 포함하는 박막의 미세구조에 의존하기 때문에 주상구조 사이에 존재하는 Void 와 Pinhole 그리고 crack들이 원인으로 작용하여, 내부식성 및 기계적 특성이 급속도로 저하되는 단점이 있다. 이러한 단점을 보완하기 위해서, 본 연구에서는 기판온도를(RT, $200^{\circ}C$, $400^{\circ}C$)증가시켜 실험 하였다. 이는 온도증가에 따른 박막의 치밀화가 이루어지고 결함이 감소하여 내부식성 특성향상이 기대되어진다. 또한 플라즈마 밀도를 높이기 위해서, 기존 DC 마그네트론 스퍼터링법에 전자기장을 추가로 인가하였다. 이는 플라즈마 밀도증가에 따른 고반응성의 질소 래디컬의 생성율 증가에 기인하여 박막 형성시 질화반응을 촉진시킴으로써 박막의 치밀화 및 내부식성 특성향상이 기대되어진다.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.11a
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• pp.27-32
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• 2010

Performance test of a full-scale turbopump assembly for a 75 ton class liquid rocket engine was carried out at full speed. Model fluid was used as a working medium: liquid nitrogen for the oxidizer pump, water for the fuel pump, and hot air for the turbine. The turbopump was operated stably, satisfying the performance requirements. Head coefficient and flow coefficient of the pumps remained constant at the speed-increasing period. In terms of performance characteristics of pumps and turbine, the results from the turbopump assembly test showed a good agreement with those from the turbopump component tests.

• The Bulletin of The Korean Astronomical Society
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• v.37 no.2
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• pp.151.1-151.1
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• 2012

우주발사체와 발사지원설비를 연결하여 추진제 공급과 전기신호 송수신 등을 가능하게 하는 메커니즘을 엄브리칼 장치라고 한다. 국내 우주발사체의 경우 액체산소와 케로신을 추진제로 사용하며, 질소, 공기 및 헬륨 등의 가스를 밸브구동, 공간 퍼지, 추진제 가압에 이용한다. 본 논문에서는 우주센터의 발사대설비에 적용된 엄브리칼 장치 중 추진제 및 고압가스 공급을 위한 자동체결장치(auto coupling device)의 구성, 기능 및 발사 준비를 위한 프로세스에 대해 기술하고 있다. 자동체결장치는 발사체 하부 두 곳에 연결되며, 산화제 공급측의 체결장치(coupling device 1)와 연료 공급측의 체결장치(CD 2)로 구성된다. 이 장치는 발사체와의 접촉면에서 기밀을 확보한 상태에서 내부의 탱크, 밸브, 인터스테이지 등에 추진제 및 각종 가스를 공급하는 통로역할을 하며, 발사준비가 완료된 후에는 발사체 이륙 전 또는 이륙과 동시에 발사체로부터 자동으로 분리된다. 각각의 체결장치 구성품으로는 발사체 이륙시 발생하는 고온의 화염으로부터 장치를 보호하는 PD(protective device), 접촉면에 기밀을 제공하고 추진제 누출을 방지는 MCP(multi-channel plate), 접촉면을 보호하기 위한 덮게, 각종 연결 배관의 전진과 후진을 위한 캐리지, 발사체와의 체결을 지지하는 그립 등이 있다. 발사 준비를 위해서 사전에 장치의 독립운용시험을 통해 각 구성품의 상태와 기능을 점검하고 장치의 작동성을 검증한다. 이후 발사체를 모사하는 기체 및 관제설비와 종합적으로 연계 시험과 모사시험을 수행하여 최종적으로 발사준비상태를 확인하게 된다. 이러한 자동체결장치의 운용 경험은 한국형발사체의 지상지원설비 개발에 활용할 수 있을 것이다.

• Transactions of the Korean hydrogen and new energy society
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• v.30 no.6
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• pp.601-607
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• 2019

Ammonia would be formed in natural gas containing small amount of nitrogen reforming process in the process natural gas, which might damage the Pt catalyst and Prox catalyst. In the article, the effect of nitrogen contents on the formation of ammonia in the reforming process has been studied. In the experiments, Ru based and Ni based catalysts were used and the concentration of ammonia in the reformate gas at various gas hourly space velocity was measured. Experimental result shows that relatively higher ammonia concentration was measured with Ru based catalyst than with Ni based catalyst. It also shows that the concentration of ammonia increased rapidly after most of the methane converted into hydrogen. Based on the experimental results to reduce ammonia concentration it might be better to finish methane conversion at the exit position of the reforming reactor to minimize the contact time of catalyst and nitrogen with high concentration of hydrogen.

• Journal of the Korean Institute of Gas
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• v.8 no.2 s.23
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• pp.42-47
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• 2004

The axisymmetric methane-air counterflow flame in microgravity was simulated to investigate effects of the global strain rate on the flame structure. The flame shapes and profiles of temperature and the axial velocity for the mole fraction of methane in the methane-nitrogen fuel stream, Xm= 20, 50, $80\%$, and the global strain rate, ag= 20, 60, 90 $s^{-1}$ each mole fraction were compared. The profiles of the temperature and axial velocity of the axisymmetric simulations were in good agreement with those of OPPDIF, an one-dimensional flamelet code. It was confirmed that the flame is stretched more and the flame radius increases and the flame thickness decreases as the global strain rate increases.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2008.11a
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• pp.153-156
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• 2008

Ignition and combustion performance of a gas-turbine engine were changed by various high-altitude condition. A goal of this study is to make the small test facility to simulate high-altitude condition. To perform the low pressure condition, a diffuser was used in various diffuser front of primary nozzle pressure. To perform the low temperature, heat exchanger was used in various mixture ratio of cryogenic air and ambient temperature air. The experimental result shows that high-altitude conditions can be controled by diffuser front of primary nozzle pressure and mixture ratio of cryogenic air and ambient temperature air.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2012.05a
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• pp.300-303
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• 2012

Global warming has been a serious problem due to excessive emissions of carbon dioxide from the increase of energy consumption. The present study investigates an energy generation mechanism that does not produce carbon dioxide and oxides of nitrogen. A reaction mechanism including sodium borohydride and hydrogen peroxide has been introduced and as a result, thermal energy can be generated from combustion of hydrogen with oxygen. Sodium borohydride dissolved in water reacting with liquid hydrogen peroxide may reveal maximum adiabatic reaction temperature of 1795 K at a mixture ratio of 0.89.

• Korean Journal of Metals and Materials
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• v.47 no.11
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• pp.722-727
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• 2009

The bipolar plates are not only the major part of the polymer electrolyte membrane fuel cell (PEMFC) stack in weight and volume, but also a significant contributor to the stack costs. Stainless steels are considered to be good candidates for bipolar plate materials of the PEMFC due to their low cost, high strength and easy machining, as well as corrosion resistance. In this paper, 316L stainless steel with and without nitrogen ion implantation were tested in simulated PEMFC environments for application as bipolar plates. The results showed that the nitride formed by nitrogen ion implantation contributed the decrease of the interfacial contact resistance without degradation of corrosion property. The combination of excellent properties indicated that nitrogen ion implanted stainless steel could be potential candidate materials as bipolar plates in PEMFC. Current efforts have focused on optimizing the condition of ion implantation.

• Journal of the Korean Institute of Gas
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• v.27 no.3
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• pp.52-58
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• 2023

With the increasing awareness of the importance of carbon neutrality in response to global climate change, the utilization of hydrogen as a carbon-free fuel source is also growing. Hydrogen is commonly used in fuel cells (FC), but it can also be utilized in internal combustion engines (ICE) that are based on combustion. Particularly, ICEs that already have established infrastructure for production and supply can greatly contribute to the expansion of hydrogen energy utilization when it becomes difficult to rely solely on fuel cells or expand their infrastructure. However, a disadvantage of utilizing hydrogen through combustion is the potential generation of nitrogen oxides (NOx), which are harmful emissions formed when nitrogen in the air reacts with oxygen at high temperatures. In particular, for the EURO-7 exhaust regulation, which includes cold start operation, efforts to reduce exhaust emissions during the warm-up process are required. Therefore, in this study, the characteristics of nitrogen oxides and fuel consumption were investigated during the warm-up process of cooling water from room temperature to 88℃ using a 2-liter direct injection spark ignition (SI) engine fueled with hydrogen. One advantage of hydrogen, compared to conventional fuels like gasoline, natural gas, and liquefied petroleum gas (LPG), is its wide flammable range, which allows for sparser control of the excessive air ratio. In this study, the excessive air ratio was varied as 1.6/1.8/2.0 during the warm-up process, and the results were analyzed. The experimental results show that as the excessive air ratio becomes sparser during warm-up, the emission of nitrogen oxides per unit time decreases, and the thermal efficiency relatively increases. However, as the time required to reach the final temperature becomes longer, the cumulative emissions and fuel consumption may worsen.

• Journal of the Korean Wood Science and Technology
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• v.46 no.1
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• pp.48-59
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• 2018

This study was conducted to suggest the effective management and recycling processes of coffee waste, which can be easily obtained from coffee shops and coffee-related products industries. Prior to the fabrication of pellets, the potential of coffee waste as a raw material of pellet was investigated through the examination of its chemical compositions and fuel characteristics. Major gradient included in coffee waste was holocellulose, followed by fat/oil and protein. Coffee waste contained a small quantity of ash (0.7%), such as calcium, sodium, potassium and magnesium. Interestingly, coffee waste was easily dried probably due to its porous structure. Pellets fabricated with coffee waste and larch sawdust showed good fuel characteristics, such as moisture content, ash content, density and durability. The pellets exceed greatly the minimum requirements of $1^{st}$-grade wood pellet standard designated by National Institute of Forest Science (NIFOS). Particularly, the high calorific value of coffee waste showed the potential as a raw material of pellet. However, owing to high nitrogen and sulfur contents, coffee waste is like to be used as a raw material of wood pellet for combined heat and power plants equipped with a reduction system of $NO_x$ and $SO_x$ gases. On the other hand, 91 wt% larch sawdust and 9 wt% coffee waste are required to fabricate the $1^{st}$-grade wood pellets designated by NIFOS. Pellets fabricated with the conditions are estimated to have nitrogen content of 0.298% and sulfur content of 0.03%. Lastly, if amounts of coffee waste and sawdust in the production of wood pellets are adequately adjusted according to its purchasing price, the manufacturing cost of pellet can effectively be reduced. In addition, it is expected tp prepare the effective recycling process of waste and to relieve the environmental burden with the reduction of waste from the commercialization of coffee waste/larch pellets.