• Korean Chemical Engineering Research
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• v.60 no.3
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• pp.433-438
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• 2022

A carbon cycle model based method is proposed in order to evaluate the effectiveness of various policies and projects to achieve carbon neutrality. The proposed model was validated by properly reproducing the increase in the concentration of carbon dioxide in the atmosphere and the rise of the global average temperature from the data of anthropogenic carbon emissions and deforestation since the industrial revolution. As a case study, a carbon cycle impact assessment was performed for deforestation, reforestation, and afforestation. It was verified that the increase of carbon dioxide in the atmosphere is attributed not only to fossil fuel usage, but also to deforestation, and that even if deforestation is immediately followed by reforestation, it takes very long to return to the initial concentration. The proposed method is expected to be eventually applicable to simulation of potential climate control in the future, contributing to safety verification of various climate engineering techniques.

• Proceedings of the Korea Water Resources Association Conference
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• 2023.05a
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• pp.436-436
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• 2023

산업혁명을 거치면서 높은 화석연료를 사용하는 제조업 중심의 산업구조와 많은 자원을 필요로 하는 도시의 집중 현상으로 지구 온난화에 따른 이상기후 발생이 증가하고 있다. 이러한 기후변화는 홍수, 태풍, 폭염 및 폭설 등의 자연재해 발생 빈도 및 규모를 증가시켜 피해가 커지고 있다. 특히 인구 및 시설들이 집중해 있어 도시의 집중 현상은 이러한 재해에 더욱 취약한 구조가 됨에 따라 피해의 규모를 가중 시키고 있는 실정이다. 전 세계적으로 기후변화 문제의 심각성을 인식하고 이를 해결하기 위해 선신국에 의무를 부여하는 교토의정서(1997년) 채택에 이어, 선진국과 개도국이 모두 참여하는 파리협정(2015년)을 채택하였고 2016년 협정이 발효되었다. 파리협정의 목표는 산업화 이전 대비 지구 평균온도 상승을 2℃보다 아래로 유지하고, 나아가 1.5℃로 억제하기 노력하는 것을 강제하는 것으로 2050년까지 탄소 순배출량을 '0'으로 만든다는 탄소중립사회로의 전환이 본격적으로 시작되었다. 본 연구에서는 기후변화로 인한 물부족 및 수실오염과 같은 도시의 수자원 문제 해결을 위해 IoT 기반 센서 및 네트워크 기반 수자원 플랫폼을 개발하였다. 도시 수자원 시설 데이터를 기반으로 대체 수자원 확보 및 수요 중심의 물 관리를 통해 효율적인 물 배분이 될 수 있도록 하였으며 이러한 스마트 물 관리에 따른 대체 수자원 확보 및 효율적 물 배분이 탄소 저감에 미치는 효과에 대해 분석하였다. 연구대상 지역은 세종 6-4구역으로 LID 특화지구로 조성되었으며 1,000 세대의 주민이 생활하는 공동주택이다. 물 순환(LID) 시설에서 확보된 물을 물 공급 시설과 연계하여 공동주택에서 활용함으로써 감소된 상수 사용량을 온실가스 배출량으로 환산하여 탄소 저감량을 계산하였다. 실제 주민들(1,000세대)이 사용하고 있는 상수량 데이터와 전력거래소 온실가스 배출계수를 활용하였으며 물순환(LID) 시설로 확보하여 대체할 수 있는 상수량은 10%로 가정하였다. 연구대상 지역(1,000세대)의 연간 상수공급량은 331,603m³이며, 연간 전력사용량은69,637kWh이다. 온실가스 배출량은 31.963tCO₂eq이며, 온실가스 저감량은 3.2tCO₂eq로 산정되었다. 추후 LID 시설에 대한 상수 대체량과 온실가스 저감효과 정량화가 필요하다.

• Journal of the Korean Wood Science and Technology
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• v.48 no.2
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• pp.181-195
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• 2020

Characteristics of carbonized biomass obtained from a Wood charcoal briquette manufacturing process using an open hearth kiln are analyzed in this research, and differences in the characteristics based on the results of a mechanical screening process and the position within the kiln. One type of biomass and five types of carbonized biomass were collected from a Wood charcoal briquette manufacturer. After screening and grinding processes were performed on samples of 1 type of biomass and 5 types of carbonized biomass extracted from a Wood charcoal briquettes manufacturer to classify by particle size, fixed carbon, ash, volatile matters, elemental composition, and high heating value (HHV) were measured. Experimental results showed that the carbonized biomass collected from the middle layer had the highest HHV, 20.4 MJ/kg, and therefore had the highest fuel quality. In terms of particle size, the carbonized biomass below 100 mesh had the lowest ash content and the highest HHV, carbon content, and fixed carbon content. Correlation analyses showed that ash content had negative correlations with HHV, volatile matters, fixed carbon, and carbon content, which suggested that ash content affected negatively on fuel quality.

• Journal of the Korean Electrochemical Society
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• v.12 no.2
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• pp.142-147
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• 2009

The influence of graphitization of carbon support on the electrochemical corrosion of carbon and sintering of Pt particles are investigated by measuring $CO_2$ emission at a constant potential of 1.4 V for 30 min using on-line mass spectrometry and cyclic voltammogram. In comparison to commercial Pt/C (from Johnson Matthey), highly graphitized carbon nanofiber (CNF) supported Pt catalyst exhibits lower performance degradation and $CO_2$ emission. As the more carbon corrosion occurred, the more prominent changes were detected in electrochemical characteristics of fuel cell. This indicates that the carbon corrosion affects significantly the fuel cell durability. From the observed results, CNF is considered to be more corrosion resistant material as a catalyst support. However, CNF shows higher aggregation of Pt particles under repeated cyclic voltammetry between 0 and 0.8 V where the carbon corrosion is not initiated.

• Applied Chemistry for Engineering
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• v.22 no.2
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• pp.167-172
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• 2011

In this work, the effect of surface treatment on mesoporous carbons (MCs) supports was investigated by analyzing surface functional groups. MCs were prepared by a conventional templating method using mesoporous silica (SBA-15) for using catalyst supports in direct methanol fuel cells (DMFCs). The MCs were treated with different phosphoric acid ($H_3PO_4$) concentrations i.e., 0, 1, 3, 4, and 5 M at 343 K for 6 h. And then Pt-Ru was deposited onto surface treated MCs (H-MCs) by chemical reduction method. The characteristics of Pt-Ru catalysts deposited onto H-MCs were determined by specific surface area and pore size analyzer, X-ray diffraction, X-ray photoelectron, transmission electron microscopy, and inductive coupled plasma-mass spectrometer. The electrochemical properties of Pt-Ru/H-MCs catalysts were also analyzed by cyclic voltammetry experiments. From the results of surface analysis, an oxygen functional group was introduced to the surface of carbon supports. From the results, the H4M-MCs carbon supports surface treated with 4 M $H_3PO_4$ led to uniform dispersion of Pt-Ru onto H4M-MCs, resulting in enhancing the electro-catalytic activity of Pt-Ru catalysts.

• Journal of Advanced Marine Engineering and Technology
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• v.39 no.7
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• pp.716-721
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• 2015

As the severity of environmental pollution has increased, restrictions on air pollution have been strengthened. Stringent regulations have been imposed, not only on marine diesel engines but also on automotive and industrial power plants. Thus, biofuels have been directly applied in practical engines and used in training ships for basic research. Even though a high biofuel percentage cannot be used in a training ship engine for safety reasons, because this type of engine is larger than those used in institutional laboratories, the results will provide important basic information that will allow organizations to determine the status of a large output. Biodiesel fuel was studied to determine how it would affect the combustion characteristics and exhaust emissions of a marine diesel generator engine. The main results can be summarized as follows. Because the physical and chemical compositions of biofuels are similar to those of diesel fuel, it was found that their practical use was possible in a training ship. The specific fuel consumption and NOx increased, whereas a tendency was found for carbon monoxide and soot to decrease. In addition, no significant pressure change difference was found between the diesel fuel and biofuels.

• Journal of the Korea Organic Resources Recycling Association
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• v.30 no.4
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• pp.101-108
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• 2022

This study analyzed the physicochemical properties and combustion characteristics of dry food waste to evaluate the possibility of using food waste as a solid refuse fuel (SRF). The characteristics of dry food waste as a fuel were analyzed by comparing the difference in properties with SRF, and the combustion characteristics after conversion into fuel were identified. Ultimate analysis, proximate analysis, calorific value analysis, and TGA analysis were conducted using two types of food waste and two types of SRF, and the following results were obtained. The moisture content and ash content of dry food waste were 1.7~10.0 wt.% and 7.8~11.7 wt.%, respectively, which satisfied the quality standards for SRF. The low calorific value of dry food waste was 4,000 ~ 4,720 kcal/kg, which was higher than the quality standard of 3,500 kcal/kg for SRF. As a result of TGA analysis of dry food waste, the combustion reaction started at about 200 ℃ and the highest burning rate was at about 500 ℃. After moisture evaporation between 100 and 200 ℃, initial volatile matter, carbon and residual volatile matter were released and burned between 200 and 500 ℃. Based on the high calorific value and low moisture and ash content of dry food waste, it is considered that it is possible to convert dry food waste into SRF through the application of efficient drying technology and strict quality standard inspection in the future.

• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.159.1-159.1
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• 2010

활성탄은 입자내 공극이 잘 발달된 무정형 탄소로써 흡착성 및 촉매성이 뛰어나 폐유를 연료로 전환하는 과정에 회분, 중금속 및 기타 이물질 제거에 우수한 효과를 나타내며 이러한 연구가 간헐적으로 진행되고 있다. 본 연구에서는 활성탄을 활용하여 이온정제유, 감압정제유, 재생연료유를 대상으로 흡착성 실험을 진행하였으며 물리적 및 화학적 성분 변화를 통해 활성탄이 정제연료유에 미치는 영향 및 분자체 작용에 대한 연구를 진행하였다.

• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.198.1-198.1
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• 2010

고분자전해질 연료전지(PEMFC)의 핵심부품인 스택의 MEA는 전극과 멤브레인 전해질, GDL(Gas Diffusion Layer)로 구성되며, 전극은 Anoth극과 Cathod극으로 나뉘어 각각의 전극 특성에 적합한 전극촉매를 적용하게 된다. Anoth극과 Cathod극은 탄소 지지체 위에 원하는 사양의 희유금속이 도포되어 존재하는데 이들 희유금속은 그 희귀성으로 인해 사용 후 반드시 재사용되어야 한다. 사용된 전극에서의 희유금속 회수는 산침출, 불순물제거, 추출, 탈거 공정으로 이루어지며, 산침출 시 산화제로 사용된 NaOCl로 인한 침출용액 내의 Na+ 이온의 증가는 불순물제거 공정에 의해 반드시 제거되어야 한다. 따라서 본 연구에서는 CCG 방식으로 전극촉매를 GDL에 코팅한 MEA로부터 백금족 희유금속을 회수 시 MEA에 포함되어 있는 소량의 불순물을 제거하고자 한다.

• Journal of the Korean Institute of Gas
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• v.18 no.1
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• pp.1-7
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• 2014

In this study, plasma reformer technology with a LPG injector was investigated. It was developed with injection of LPG fuel and air in a region where the plasma discharge to make the thermal decomposition carbon fuel and to generate additional hydrogen. As a result of reforming test, when power is 70~100W supply, about HC 0.7% of the full reformed gas and hydrogen was generated from 1.2 to 1.5 %.