• Title/Summary/Keyword: 에어로졸 화염

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Effects of Ultrasonic Standing Wave on the Ultrasonically-atomized Aerosol Flame Injected through a Slit-jet Nozzle (Slit-jet 노즐을 통과한 초음파 무화 에어로졸 화염에 정상초음파가 미치는 영향)

  • Ahn, Hyun Jong;Kang, Yun Hyeong;Kim, Jeong Soo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.24 no.6
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    • pp.53-60
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    • 2020
  • In liquid-fuel spray combustion, an experimental study was conducted to observe the effect of ultrasonic excitation on the ultrasonically-atomized liquid fuel flame by controlling pressure field through an ultrasonic standing wave. Flame of the ultrasonically-atomized kerosene aerosol was visualized by using a high speed camera, DSLR, and Schlieren photography. The amount of fuel consumed was obtained by a precise flow-rate measurement technique during combustion, through which the ratio of carrier gas (air) to fuel mass was able to be obtained, too. As a result, it could be found that the combustion reaction-rate of the liquid-fuel aerosol was increased by applying an ultrasonic standing wave to the secondary flame zone of the flame.

A Behavior of the Ultrasonically-atomized Kerosene Lifted-flame According to the Position of Ultrasonic Standing-wave Field (정상초음파장의 위치에 따른 초음파 무화 케로신 부상화염의 거동)

  • Chang Han Bae;Jeong Soo Kim
    • Journal of the Korean Society of Propulsion Engineers
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    • v.27 no.1
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    • pp.1-8
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    • 2023
  • A study was conducted to scrutinize the behavior of the ultrasonically-atomized kerosene lifted-flame according to the carrier gas flow-rate and position of ultrasonic standing wave (USW). The combustion region of the kerosene-aerosol generated through a slit-jet nozzle was visualized using a DSLR, ICCD, high-speed camera, and Schlieren technique, and the fuel consumption was measured by using a precision balance. As a result, the flame was confined within the region bounded by the USW-field, and the fuel consumption decreased as the position of the USW field increased.

Synthesis of Carbon-Supported Pt-Ru Catalysts using a Flame Spray Pyrolysis Method for Fuel Electrode of Low Temperature Fuel Cell (화염분무열분해 공정을 이용한 저온 연료전지 연료전극용 탄소담지 Pt-Ru 촉매의 제조)

  • Lee, Hyun-Min;Lee, Dong-Geun
    • Particle and aerosol research
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    • v.8 no.2
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    • pp.69-74
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    • 2012
  • This study describes how successfully a conventional flame aerosol synthesis was used to continuously synthesize Pt-Ru catalysts supported by carbon agglomerates. Nearly spherical catalysts produced in the flame were mainly composed of metallic Pt and Ru with the molar ratio of 1:1 and those sizes were controllable from ~1.5 nm to ~2.0 nm. Nevertheless, only Pt peaks were found from X-ray diffraction experiments, suggesting that amorphous-like Ru was well mixed in the crystalline Pt lattices. It was found from Cyclo-voltamograms and CO stripping experiments that the electrochemical properties of the catalysts are at least comparable to that of a conventional commercial sample.

Preparation of TiO2:Fe,V nanoparticles by flame spray pyrolysis and photocatalytic degradation of VOCs (화염분무열분해법을 이용한 TiO2:Fe,V 나노분말의 제조 및 VOCs 분해 특성)

  • Chang, Han Kwon;Jang, Hee Dong;Kim, Tae-Oh;Kim, Sun Kyung;Choi, Jin Hoon
    • Particle and aerosol research
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    • v.5 no.1
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    • pp.1-7
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    • 2009
  • Fe- and V-doped titanium dioxide nanoparticles consisting of spherical primary nanoparticles were synthesized from a mixed liquid precursor by using the flame spray pyrolysis. The effects of dopant concentration on the powder properties such as morphology, crystal structure, and light adsorption were analyzed by TEM, XRD, and UV-Vis spectrophotometer, respectively. As the V/Ti molar ratio increased, pure anatase particles were synthesized. On the contrary, rutile phase particles were synthesized as the Fe/Ti ratio increased. Photocatalytic property of as-prepared $TiO_2:Fe,V$ nanoparticles was investigated by measuring the removal efficiency for volatile organic compounds (VOCs) under the irradiation of visible light. After 2 hrs under visible light, the removal efficiencies of benzene, p-xylene, ethylbenzene, and toluene were reached to 21.9%, 21.4%, 19.8% and 17.6% respectively.

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Catalytic oxidation kinetics of iron-containing carbon particles generated from diesel-sprayed hydrogen-air diffusion flame (디젤-분무 수소-공기 확산화염에서 생성된 철-함유 탄소입자의 촉매 산화반응 특성)

  • Kim, Yongho;Kim, Yong-Tae;Kim, Soo Hyung;Lee, Donggeun
    • Particle and aerosol research
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    • v.4 no.2
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    • pp.51-67
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    • 2008
  • In this study, we devoted to kinetic measurement of the catalytic oxidation of iron-containing flame soot particles and better understanding the role of catalytic particles on carbon oxidation in particular at low temperature, targeting on autothermal regeneration of diesel particulate filter by diesel exhaust gas. Carbon-based Fe-containing particles generated by spraying ferrocene-doped diesel fuel in an oxy-hydrogen flame are tested and compared with a commercial carbon black powder for thermogravimetric analysis (TGA), secondary ion mass spectrometry (SIMS), Fourier-transform infrared spectroscopy (FTIR), Induced coupled plasma-Atomic emission spectroscopy (ICP-AES), and High-resolution transmission electron microscopy (HR-TEM). As a result, we found that a small amount of the ferrocene addition led to significant reductions in a on-set temperature and an activation energy of the carbon oxidation as well. An oxygenated surface complex forming at the particle surface could be thought as active species that would be readily consumed in particular at low temperature.

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Preparation of CeO2 Nanoparticles using Flame Spray Pyrolysis (화염분무열분해법을 이용한 이산화세륨 나노분말 제조)

  • Kim, Sun Kyung;Park, Su-Ryeon;Chang, Hankwon;Jang, Hee Dong
    • Particle and aerosol research
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    • v.12 no.2
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    • pp.37-42
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    • 2016
  • $CeO_2$ nanoparticles were prepared by a flame spray pyrolysis from aqueous solution of cerium nitrate. The morphology, structure crystallinity and specific surface area of as-prepared nanoparticles were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), and Brunauer-Emmett-Telle (BET). The $CeO_2$ nanoparticles about 5 nm in diameter showed a cubic fluorite structure and polyhedral morphology. The average particle size increased as the cerium nitrate concentration increased. UV absorption performance of the as-prepared nanoparticles was measured by UV-visible spectroscopy. UV absorption of $CeO_2$ nanoparticles was more effective than that of commercial $TiO_2$ nanoparticles. Effect of dopants such as Ti and Zn to $CeO_2$ nanoparticles on UV absorption properties was also investigated. In case of $Ti/CeO_2$, and $Zn/CeO_2$ nanoparticles, they showed a little higher UV absorption values compared with $CeO_2$ nanoparticles. The as-prepared nanoparticles can be promising materials with high UV absorption value.

Stress-Free Pyrex-Based Optical Waveguide for Planar Lightwave Circuits on Silicon Substrate (실리콘 기판의 광집적회로를 위한 Pyrex 무응력 도파박막)

  • 문형명;정형곤;이용태;김한수;전영윤;정석종;윤선현;이형종
    • Korean Journal of Optics and Photonics
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    • v.9 no.3
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    • pp.156-161
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    • 1998
  • We developed aerosol flame deposition method and made stress-free Pyrex-based optical waveguide on silicon substrate using this method. Zr is doped to control the refractive index of Pyrex waveguide layers. The refractive index of the film changes from 1.460 to 1.475 as the content of Zr changes from 0 to 3 wt%. Er is doped to see the possibility of applying this Pyrex waveguide as PLC-type (Planar Lightwave Circuit) optical amplifier. The refractive index of the film changes from 1.460 to 1.465 as the content of Zr changes from 0 to 1 wt%. Light launching using a prism coupler to the fabricated waveguide showed good quality for application to PLC. The polarization dependence of refractive-index of the Pyrex film is measured to be less than $2{\times}10^{-4}$.

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Effects of an $Al_2$O$_3$Surfasce Protective Layer on the Sensing Properties of $SnO_2$Thin Film Gas Sensors (Al$_2$O$_3$ 표면 보호층이 박막형 $SnO_2$ 가스센서의 감지 특성에 미치는 영향)

  • Seong, Gyeong-Pil;Choe, Dong-Su;Kim, Jin-Hyeok;Mun, Jong-Ha;Myeong, Tae-Ho
    • Korean Journal of Materials Research
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    • v.10 no.11
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    • pp.778-783
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    • 2000
  • Effects of the $Al_2$O$_3$surface protective layer, deposited on the SnO$_2$sensing layer by aerosol flame deposition (AFD) method, on the sensing properties of SnO$_2$thin film ags sensors were investigated.Effects of Pt doping to the $Al_2$O$_3$surface protective layer on the selectivity of CH$_4$ gas were also investigated. 0.3$\mu\textrm{m}$ thick SnO$_2$thin sensing layers on Pt electrodes were prepared by R.F. magnetron sputtering with R.F. power of 50 W, at working pressure of 4mTorr, and at 20$0^{\circ}C$ for 30 min. $Al_2$O$_3$surface protective layers on SnO$_2$layers were prepared by AFD using a diluted aluminum nitrade (Al(NO$_3$).9$H_2O$) solution. The sensitivity of CO gas in the SnO$_2$gas sensor with an $Al_2$O$_3$surface protective layer was significantly decreased. But that of CH$_4$gas remained almost same with pure SnO$_2$gas sensor. This result shows that the selectivity of CH$_4$gas is increased because of the $Al_2$O$_3$surface protective layer. In the case of SnO$_2$gas sensors with Pt-doped $Al_2$O$_3$surface protective layers, low sensing property to CO gas and high sensing property to CH$_4$were observed. This results in the increasing of selectivity of CH$_4$gas selectivity are discussed.

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