• Journal of Adhesion and Interface
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• v.12 no.4
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• pp.117-124
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• 2011

This study was made on the poly(vinyl acetate) (PVAc) and poly(vinyl acetate- ethylene) (VAE) emulsion polymer blend which used PVA as protective colloid, and the PVA used as protective colloid was existed in each emulsion film before blend and even in the film after the blend consecutively. It makes us expect excellent adhesive power among particles that form the blend. Emulsion blends with different Tg are important target of concerning, and PVAc/VAE emulsion blend suggested simple and excellent research method. As a result of blend, elongation was lowered by the increase of PVAc, and the plasticizer used in making PVAc affected on the Tg of blend and lowered Tg of VAE emulsion, and the synergy effect of two blends was seen for the tensile strength, thermal resistance, and adhesive strength.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.22 no.1
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• pp.81-86
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• 2021

The cosmetic industry is technology-intensive in the field of fine chemistry and continues to grow globally. The functional aspects have been mainly emphasized in the past to increase the market share in these cosmetics industries. Recently, however, efforts have been made to attract the attention of consumers to the visual effects as well as the excellent performance of cosmetics at home and abroad. Accordingly, cosmetic manufacturers are trying various technologies that encapsulate the cosmetic emulsion and modify the shape, color, and texture of the emulsion capsule. The basic and easiest method of encapsulating emulsion is dropping the emulsion through the nozzle from emulsion storage. On the other hand, the existing method of encapsulating emulsion has a limit in reducing the size of the capsule. In this study, the limit was shown by theory and numerical analysis method, and the emulsion encapsulation phenomena occurring in the micro-channel were studied to apply microfluidics as an alternative.

• Explosives and Blasting
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• v.25 no.1
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• pp.45-52
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• 2007

When emulsion explosives(1kg/cartridge) are loaded into a long vertical borehole at open blasting site, they undergo an Impact corresponding to 117.6J of shock energy. After shocking. the crystallization of emulsion nay happen immediately. Furthermore, it nay cause a desensitization, arising from increase in the density of emulsion explosive by the breakage of sensitizer. In this paper, some experimental work was performed using PVC pipe equipment(50mm diameter and 12m lengths) to investigate the effects of loading impart of emulsion explosive. It is shown that detonation energy decreases up to 26% of the normal state value and this effect is less than 3% of the total performance of emulsion explosives in borehole blasting.

• Explosives and Blasting
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• v.21 no.3
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• pp.73-80
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• 2003

암반발파에 사용하고 있는 전기식 뇌관과 비전기식 연결뇌관 및 번치 커넥터(Bunch connector), 점화구, 에멀젼류 폭약이 지상에서 기폭 될 때 발생하는 소음을 비교 분석하였다. 에멀젼류 폭약의 폭발소음과 화공품의 기폭소음에 대한 추정식을 도출하였다. 에멀젼류 폭약의 폭발 소음 예측은 반대수 자승근 환산식, 번치 커넥터, 전기식 뇌관 및 비전기식 연결뇌관 및 점화구는 전대수식이 적합한 것으로 판단된다. 소음원으로부터 동일한 거리에서의 소음은 점화구, 비전기식 연결뇌관, 전기식 뇌관 및 번치 커넥터 순으로 높았다. 소음원으로부터 약20∼30m거리의 범위에서 번치 커넥터의 기폭소음은 에멀젼류 폭약 0.250kg의 폭발소음보다 약15.6∼20.2dB(A) 낮고, 비전기식 연결뇌관 보다 약13.5∼16.0dB(A) 높고, 전기식 뇌관 보다는 약6.5∼7.5dB(A) 높게 됨을 알 수 있었다. 점화구는 약20m 거리에서 약 7dB(A)이하 이었다. 에멀젼류 폭약의 폭발과 번치 커넥터의 기폭소음에 미치는 주(主)소음원은 에멀젼류 폭약의 약량과 번치 커넥터의 도폭선임을 확인하였다.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.40 no.3
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• pp.221-226
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• 2014

IIn this study, O/W type nano-emulsions were prepared by phospholipid-nonionic surfactant mixtures and octyldodecylmyristate using the phase transition low-energy emulsification method. The nano-emulsions were formed only in the very narrow area of the concentration of mixed surfactant and oil molar ratio of around 1 : 1. The particle size of the emulsions was decreased as adding the aqueous phase into the emulsions after phase inversion point unlike the emulsions formed only with nonionic surfactant. Nano-emulsion was stable at room temperature for more than a month. Thus, the nano-emulsions containing phospholipids can be widely used as a cosmetic formulations.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.41 no.4
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• pp.315-324
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• 2015

In this study, we prepared liquid crystal emulsion composed of amphiphilic substance $C_{14-22}$ alcohol, $C_{12-20}$ alkyl glucoside, behenyl alcohol and studied liquid crystal emulsion of properties and in vitro skin permeation. The results of formulation experiments, the clear liquid crystalline structure was observed in the ratio of $C_{14-22}$ alcohol 0.8%, $C_{12-20}$ alkyl glucoside 3.2%, behenyl alcohol 4% in the formulation. The results of physical property measurements, the viscosity of liquid crystal emulsion and O/W emulsion applied as a control group was respectively $1871.26{\sim}1.15Pa{\cdot}s$, $1768.69{\sim}1.14Pa{\cdot}s$ and the shear stress of O/W emulsion was 178.68 ~ 909.18 Pa, that of liquid crystal emulsion was 190.45 ~ 919.38 Pa. The storage modulus of O/W emulsion was 3428.53 ~ 9157.45 Pa, that of liquid crystal emulsion was 4487.82 ~ 8195.59 Pa. The tan (delta) value of O/W emulsion which means a ratio of viscosity to elasticity was 0.43 ~ 0.19, and that of liquid crystal emulsion was 0.23 ~ 0.25. The water content value on the skin for liquid crystal emulsion was significantly higher from 1 h to 6 h compared with that of O/W emulsion and the transepidermal water loss on the skin was significantly superior in skin moisture loss suppression from 30 min to 4 h compared with that of O/W emulsion. The results of skin permeation using glycyrrhizic acid, the result of skin permeation amount of liquid crystal emulsion for 24 h was $64.58{\mu}g/cm^2$, that of O/W emulsion was $37.07{\mu}g/cm^2$, that of butylene glycol solution was $41.05{\mu}g/cm^2$. Hourly permeability results, it is showed that skin penetration effect of the liquid crystal emulsion increases after 8 h. These results suggest that liquid crystal emulsions are effective for skin moisturizing effect and function as potential efficacy ingredient delivery system for the transdermal delivery.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.35 no.2
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• pp.103-110
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• 2009

The objective of this study is to analyze the influences of fatty alcohols and fatty acids on rheological properties of oil in water (O/W) emulsions using viscosity and rheograms. As the chain length of fatty alcohols and fatty acids lengthened, the viscosity of emulsions was increased. The influence of fatty alcohols on viscosity enhancement was stronger than that of fatty acids. Both stearyl alcohol and cetearyl alcohol, which have carbon chain length similar to lipophilic portion of surfactant used in emulsion preparation, had showed the best increase in viscosity of O/W emulsions. O/W emulsions prepared with fatty alcohols and fatty acids were pseudo-plastic fluid and they showed shear thinning behaviour like as the common cosmetic emulsions. O/W emulsions prepared with cetyl alcohol, cetearyl alcohol and stearyl alcohol were thixotropic fluids and thixotropy increased with an increase in the concentration of fatty alcohols and fatty acids. Also O/W emulsions prepared with fatty alcohols were more thixotropic than those prepared with fatty acids. For the sake of viscosity increase related to O/W emulsions stability and spreadability enhancement related to payoff, it is thought that fatty alcohols are more useful than fatty acids in the O/W emulsions as the emulsion stabilizer.

• Proceedings of the Membrane Society of Korea Conference
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• 1995.10a
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• pp.31-32
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• 1995

한외여과분리의 중요한 응용분야의 하나인 oil/water 에멀젼의 분리에 대하여 연구하였다. Oil/water 에멀젼의 한외여과분리 원리를 제안하고, 상용되고 있는 하나의 절삭유를 대상으로 분리가능성을 조사하였다. 사용된 한외여과분리 모듈은 상업적으로 이용되고 있는 IRIS 3042 분리막이 장착된 평판형이었다. 한외여과 실험에서 공급압력, 공급유량, 공급에멀젼의 oil농도등을 변화시키면서 투과액의 oil농도, 투과속도등을 측정하여 분리성능을 조사하였다.

• Applied Chemistry for Engineering
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• v.17 no.2
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• pp.132-137
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• 2006

Polyurethane acrylate hybrid emulsions were prepared by seeded polymerization techniques. In the synthesis, seeded polyurethane dispersion containing a carboxylic group was used to endow hydrophilicity to the hybrid emulsion and various acrylates such as methyl methacrylate (MMA), 2-hydroxy ethylmethacrylate (2-HEMA), n-butyl acrylate (n-BA) and acrylic acid (AAc) were used to endow hydrophobicity. The particle size and distribution of various emulsion particles such as polyurethane acrylate hybrid emulsion, polyurethane dispersion homopolymer, acrylate emulsion, and physical blending emulsion were measured by a particle size analyzer. The average particle size of hybrid emulsion was greater than physical blending emulsion. And tensile strength, 100% modulus, elongation, and swelling properties of the polyurethane acrylate hybrid emulsion were studied and compared with those of polyurethane homopolymer, acrylate emulsion, and physically blended compositor, respectively. To improve chemical and physical resistance, this paper review a melamine hardener and compares it for effects on the physical properties of cured coating.

• Journal of the Korean Applied Science and Technology
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• v.35 no.3
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• pp.985-1001
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• 2018

In this study, we tried the various experiments using the emulsifier, electrolyte, stabilizer and gelling agent in order to improve a stability of low viscosity W/O emulsion. As a result, when we used polyglyceryl-4 diisostearate/polyhydroxystearate/sebacate as a main emulsifier, PEG-30 dipolyhydroxystearate and cetyl PEG/PPG-10/1 dimethicone as a co-emulsifier for stable emulsification system, 0.5 % sodium chloride as an electrolyte, 1 % distearyldimonium chloride as a stabilizer, 0.5 % glyceryl behenate/eicosadioate as an oil gelling agent, emulsion particle is the best. Also, we got the stable and low viscosity W/O emulsion maintained at a constant viscosity at 2,000 cps or less. In addition, we were able to examine the possibility of development of low viscosity fluids type sunscreens with excellent feeling and stability through the application of inorganic sunscreen agents.