• 제목/요약/키워드: 에너지 정의

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Comparison Study on the Removal of Cationic Dyes from Aqueous Suspension of Maghnia Montmorillonite (Maghnia 산 Montmorillonite 수용액으로부터 양이온 염료의 제거 비교연구)

  • Elaziouti, A.;Laouedj, N.
    • Journal of the Korean Chemical Society
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    • v.54 no.3
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    • pp.300-309
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    • 2010
  • The ability of sodium-exchanged clay particles as an adsorbent for the removal of commercial dyes, Methylene blue (MB) and Malachite green oxalate (MG) from aqueous solutions has been investigated under various experimental conditions. The effect of the experimental parameters, such as pH solution, agitation time, adsorbate concentration and adsorbent dose were examined. Maximum adsorption of dyes, i.e. >90% has been achieved in aqueous solutions using 0.03 g of clay at a pH of 7 and 298 K for both dyes. The adsorption process was a fast and the equilibrium was obtained within the first 5 min. For the adsorption of both MB and MG dyes, the pseudo-second-order reaction kinetics provides the best correlation of the experimental data. The adsorption equilibrium results follow Langmuir and Dubini-Radushkevich (D-R) isotherms with high regression coefficients $R^2$ > 0.98. The mean free energies $E_a$ of adsorption from D-R model were 3.779 and 2.564 kj/mol for MB and MG respectively, which corresponds to a physisorption process.

Discovery of Sub-pc Scale Plasma Torus in the Nearby Radio Galaxy 3C 84 with the KVN and VERA Array (KaVA)

  • Wajima, Kiyoaki;Kino, Motoki;Kawakatu, Nozomu
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.2
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    • pp.32.4-33
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    • 2016
  • 활동성은하핵(AGN)의 거대 블랙홀 주변에 존재하는 플라스마 디스크의 구조나 물리적인 상태를 관측으로 직접 찾는 것은 AGN 중심부분에서의 제트 형성, 방출과정이나 에너지 수송과정을 조사하기 위해 중요한다. 지금껏 주로 센치미터파장 영역의 다주파 VLBI 관측으로 우리은하에서 가까운 AGN 속에 존재하는 10 pc 정도의 플라스마 디스크가 발견되어 있다만, AGN의 활동성을 정하고 있는 1 pc 이하의 스케일에서의 디스크 구조를 직접 관측한 결과는 아직 없다. 우리는 2015년8월부터 KVN 및 KVN과 일본 VERA로 구성되는 한일공동 VLBI 관측망(KaVA)을 이용해서 전파 은하 3C 84(z = 0.0176, 1 mas = 0.36 pc)의 밀리미터파장 모니터링을 진행하고 있다. KVN과 KaVA를 이용하면 1 pc 이하의 스케일로 3C 84의 중심구조를 고감도에서 분해할 수 있다. 이번 발표에서는 KVN 및 KaVA로 거의 동시에 실시한 관측결과를 중심으로 보고한다. 관측은 2016년2월22일(KaVA 43 GHz) 및 23일(KVN 86 GHz)에 실시되었다. 양 주파수의 이미지에서 종래의 센치미터 ~ 밀리미터파장 VLBI관측으로도 검출되어 있는 중심핵(C1) 및 남쪽에 약 3 mas 떨어져서 위치하는 로브(C3) 성분 뿐만 아니라 C1으로부터 북쪽에 약 2.5 mas 떨어져서 위치하는 새로운 성분(N1)을 검출하였다. N1의 검출 수준은 43, 86 GHz 모두 $6{\sigma}$이며, 양 주파수 사이에서 광학적으로 두꺼운 스펙트럼을 가지고 있다. 과거의 관측으로 측정된 C3의 겉보기 속도는 빛의 속도의 약 23%이며, 남북 로브의 구조와 운동의 대칭을 가정하면 N1이 도플러 분사출 효과 때문에 어두워지고 있는 가능성은 낮다. 따라서 C3에 대응하는 북쪽 N1로브로부터의 복사가 블랙홀 주변의 플라스마 디스크로 인해 저주파수에서 강한 흡수를 받고 있는 결과고 생각된다.

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Estimation Model of the Carbon Dioxide Emission in the Apartment Housing During the Maintenance period (공동주택 사용부문의 이산화탄소 배출량 추정모델 연구)

  • Lee, Kang-Hee;Chae, Chang-U
    • KIEAE Journal
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    • v.8 no.4
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    • pp.19-27
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    • 2008
  • The carbon dioxide is brought from the energy consumption and regarded as a criteria material to estimate the Global Warming Potential. Building shares about 30% in national energy consumption and affects to environment as much as the energy consumption. But there is not enough data to forecast the amount of the carbon dioxide during the maintenance stage. Various factors are related with the energy consumption and carbon dioxide emission such as the physical area, the building exterior area, the maintenance type and location. Among these factors, the building carbon-dioxide emission can be estimated by the overall building characteristics such as the maintenance area, the number of household, the heating type, etc., The physical amount such as the thickness of the insulation and window infiltration could explained the limited scope and might not be use to estimate the total carbon-dioxide emission energy because the each value could not include or represent the overall building. In this paper, it provided the estimation model of the carbon-dioxide emission, explained by the overall building characteristics. These factors are shown as the maintenance area, no. of household, the heating type, the volume of the building, the ratio of the window to wall area etc., For providing the estimation model of th carbon-dioxide emission, it conducted the corelation analysis to filter the variables and suggested the estimation model with the power model and multiple regression model. Most of the model have a good statistics and fitted in the curve line.

Principles and Comparative Studies of Various Power Measurement Methods for Lithium Secondary Batteries (리튬이차전지 출력측정법의 원리 및 측정법간 비교 연구)

  • Lee, Hye-Won;Lee, Yong-Min
    • Journal of the Korean Electrochemical Society
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    • v.15 no.3
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    • pp.115-123
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    • 2012
  • As the market of lithium secondary batteries moves from mobile IT devices to large-format electric vehicles or energy storage systems, the strengthened battery specifications such as long-term reliability longer than 10 years, pack-level safety and tough competitive price have been required. Moreover, even though high power properties should also be achieved for hybrid electric vehicles, it is not easy to measure accurate power values at various conditions. Because it is difficult to choose a proper measurement method and its experimental condition is more complex comparing to capacity measurement. In addition, the power values are very sensitive to power duration time, state-of-charge (SOC) of cells, cut-off voltages, and temperatures, whereas capacity values are not. In this paper, we introduce three kinds of power measurement methods, hybrid pulse power characterization (HPPC) suggested by US FreedomCar, so-called J-pulse by Japan electric vehicle association standards (JEVS) and constant power measurement, respectively. Moreover, with pouch-type unit cells for HEV, experimental power data are discussed in order to compare each power measurement.

Robust Speech Recognition Parameters for Emotional Variation (감정 변화에 강인한 음성 인식 파라메터)

  • Kim Weon-Goo
    • Journal of the Korean Institute of Intelligent Systems
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    • v.15 no.6
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    • pp.655-660
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    • 2005
  • This paper studied the feature parameters less affected by the emotional variation for the development of the robust speech recognition technologies. For this purpose, the effect of emotional variation on the speech recognition system and robust feature parameters of speech recognition system were studied using speech database containing various emotions. In this study, LPC cepstral coefficient, met-cepstral coefficient, root-cepstral coefficient, PLP coefficient, RASTA met-cepstral coefficient were used as a feature parameters. And CMS and SBR method were used as a signal bias removal techniques. Experimental results showed that the HMM based speaker independent word recognizer using RASTA met-cepstral coefficient :md its derivatives and CMS as a signal bias removal showed the best performance of $7.05\%$ word error rate. This corresponds to about a $52\%$ word error reduction as compare to the performance of baseline system using met - cepstral coefficient.

Determination of Design Parameters with SWAN Model at Southwest Coast (SWAN모형을 이용한 남서 도서해역에서의 설계 파라메타 추출)

  • Kim, Kang-Min;Kang, Suk-Hyung;Lee, Joong-Woo;Lee, Hoon;Kwon, So-Hyun
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • v.29 no.1
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    • pp.253-260
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    • 2005
  • Recently, the storms which hit Korean Peninsula are getting bigger, and the damages from the storms are wide spreaded. Thus, and approach with disaster prebention to offshore area and/or opened island area is neccessary. The existing wave design parameter was calculated with linear regular wave models inputting deep water design wave or wind sources. so it wasn't able to deal with wind-induced waves, interactions with waves, and redistribution of wave energy simultaneously. In this study, we made numerical simulation with SWAN(Simulation Waves Nearshore) Model which can consider development of waves and winds and their interference. The result from this model shows much different with those from existing model's. so the result from this study, especially in this modeling area, could be used for harbor design and coastal disaster prevention field in the future.

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Temperature Dependence of Optical Energy Gaps of $CdGaInS_4:Er^{3+}$ Single Crystals for Optoelectronic device (광전 소자용 $CdGaInS_4:Er^{3+}$ 단결정의 광학적 에너지 갭의 온도의존성)

  • Kim, Hyung-Gon;Kim, Byung-Chul;Bang, Tae-Hwan;Hyun, Seung-Cheol;Kim, Duck-Tae;Son, Gyeong-Chun
    • Proceedings of the KIEE Conference
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    • 2000.07e
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    • pp.56-59
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    • 2000
  • $CdGaInS_4$ and $CdGaInS_4:Er^{3+}$ single crystals crystallized in the rhombohedral(hexagonal) structure. with lattice constants $a=3.913{\AA},\;c=37.245{\AA}$ for $CdGaInS_4$, and $a=3.899{\AA}$ and $c=36.970{\AA}$ for $CdGaInS_4:Er^{3+}$. The optical absorption measured near the fundamental band edge showed that the optical energy band structure of these compounds had a direct and indirect band gap. the direct and indirect energy gaps are found to be 2.771 and 2.503 eV for $CdGaInS_4$, and 2.665 and 2.479 eV for $CdGaInS_4:Er^{3+}$ at 10 K. The temperature dependence of the optical energy gap was well represented by the Varshni equation. In $CdGaInS_4$, the values of ${\alpha},\;{\beta}$ of the direct and the indirect energy gap were found to be $7.57{\times}10^{-4}eV/K$. $6.53{\times}10^{-4}eV/K$ and 240K. 197K. and the values of ${\alpha}$ and ${\beta}$ of the direct and the indirect energy gap in the $CdGaInS_4:Er^{3+}$ were given by $8.28{\times}10^{-4}eV/K,\;2.08{\times}10^{-4}eV/K$ and 425 K, 283 K, respectively.

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The Effect of Ta-substitution on the Bi-O Bonding and the Electrical Properties of $Bi_4$$Ti_3$$O_{12}$ Thin Films ($Bi_4$$Ti_3$$O_{12}$ 박막에서 Bi-O 결합과 전기 물성에 대한 Ta 치환의 영향)

  • 고태경;한규석;윤영섭
    • Journal of the Korean Ceramic Society
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    • v.38 no.6
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    • pp.558-567
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    • 2001
  • 본 연구에서는 알콕사이드를 전구물질로 하는 졸겔공정을 이용하여 Bi 과잉 12 mol%의 조성인 B $i_4$ $Ti_3$ $O_{12}$ 박막과 B $i_4$ $Ti_{3-x}$T $a_{x}$ $O_{12}$(x=0.1, 0.2, 0.3) 박막을 제조하였다. XPS 분석에 따르면 Ta 치환 x=0.2에서 Bi 4f의 photoemission 곡선이 낮은 결합에너지로 이동하였고 피크 강도가 감소하는 현상이 관측되었다. 이는 x=0.1과 0.2 사이에서 Bi-O 결합이 길어져 인장상태 하에 있었음을 나타내었다. B $i_4$ $Ti_3$ $O_{12}$(BIT) 박막의 유전상수와 유전손실은 100 kHz에서 340, 0.05이었고, B $i_4$ $Ti_{3-x}$T $a_{x}$ $O_{12}$ 박막에서 이들 값은 x=0.1에서 가장 높았으며, 각각 480, 0.13이었다. B $i_4$ $Ti_3$ $O_{12}$ 박막의 잔류분극과 항전계는 1.24$\mu$C/$ extrm{cm}^2$, 31.4 kV/cm 이었으나, Ta 치환 x=0.2에서 이들 값은 각각 19.7$\mu$C/$\textrm{cm}^2$, 49.5 kV/cm 에 이르렀다. 또한, B $i_4$ $Ti_3$ $O_{12}$ 박막의 누설전류 밀도는 ~$10^{-6}$ A/$\textrm{cm}^2$ 정도이었으며, Ta 치환은 누설전류를 감소시켜 Ta 치환 x=0.2 이상에서 BIT 박막에 비해 한 차수 정도 낮아졌다. Ta 치환에 따른 B $i_4$ $Ti_3$ $O_{12}$ 전기 물성에서 변화는 Bi-O 결합에서 관측된 인장상태로의 전이와 연관성이 있었으며, 덧붙여 치환에서 생성된 전자에 의한 정공보상이 이에 영향을 끼쳤다. 정공보상이 이에 영향을 끼쳤다.끼쳤다.

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Manufacturing of $BaTiO_3$ Nano-powder by Solid Reaction and Its Evaluations (고상 반응법을 이용한 $BaTiO_3$ 나노 분말 제조 및 특성 평가)

  • Son, Yong-Ho;Woo, Duck-Hyun;Yoon, Man-Soon;Ur, Soon-Chul;Ryu, Sung-Lim;Kweon, Soon-Yong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.217-217
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    • 2008
  • $BaTiO_3$는 perovskite 구조를 가지는 대표적인 강유전체 재료로서 MLCC (Multi Layer Ceramic Capacitor), PTC thermistor 등에 널리 사용되어지고 있으며, 그 특성을 향상시키기 위하여 많은 연구가 진행되고 있다. 현제 $BaTiO_3$ 분말 제조의 대표적인 합성법으로는 하소와 분쇄공정이 없는 수열합성법이 대표적이나, 나노 사이즈로 제작시 $BaTiO_3$는 마이크로 크기와 달리 입방정상으로 우세한 상태로 존재한다. 이는 제조과정 중의 hydroxyl defect의 영향과 나노 분말의 표면에너지 증가 때문이라고 보고된다. 따라서 본 연구는 이러한 문제점을 해결하기 위해 일반적인 세라믹 제조 방법인 고상반응법을 이용한 나노 사이즈의 $BaTiO_3$ 제조를 위한 최적의 공정 조건을 확립하기 위하여 본 연구를 진행하였다. 조성은 $BaTiO_3$와 반응온도를 낮추기 위한 anatase의 $TiO_2$를 사용하였고, $BaCO_3/TiO_2$ 의 조성비 (1. 1.01, 1.02, 1.03)를 제어하여 혼합한 후, 24h ball-mill 하여 하소 온도 ($860^{\circ}C{\sim}1000^{\circ}C$) 변화에 따른 입자 사이즈와 입도 분포를 측정하였다. 제조된 $BaTiO_3$분말의 결정 구조 분석을 위하여 XRD (X-ray diffraction) 분석을 수행 하였는데, 분석 결과로부터 제조된 분말들이 정방정 (tetragonal)의 perovskite구조를 갖고 있음을 확인하였다. 또한 분말의 미세구조 확인을 위하여 SEM (scanning electron microscope) 관찰을 수행하였는데, 나노 사이즈의 구형 분말을 얻을 수 있음을 확인할 수 있었다.

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Pseudo Dynamic Test for the Seismic Performance Enhancement of Circular RC Bridge Piers Retrofitted with Fibers (섬유보강 원형 철근콘크리트 교각의 내진성능 향상에 관한 유사동적 실험)

  • 정영수;박종협;박희상;조창백
    • Journal of the Korea Concrete Institute
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    • v.14 no.2
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    • pp.180-189
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    • 2002
  • The objective of this experimental research is to assess the seismic performance of circular RC bridge pier specimens retrofitted with fibers which were designed as a prototype of Hagal bridge in the city of Suwon, Korea. Pseudo dynamic test has been done for four(4) test specimens which were nonseismically or seismically designed by the related provisions of the Korea roadway bridge design specification, and four nonseisemic test specimens retrofitted with fibers in the plastic hinge region. Glass and carbon fiber sheets were used for the seismic capacity enhancement of circular test specimens. Important test parameters were confinement steel ratio, load pattern, and retrofitting. The seismic behavior has been analyzed through the displacement ductility, energy analysis, and capacity spectrum. Approximate 7.7 ∼8.7 displacement ductility was observed for nonseismic test specimens retrofitted with fibers subjected to Korea Highway Cooperation artificial earthquake motions. It is concluded that these retrofitted test specimens could have sufficient seismic capacity in the region of moderate seismic zone.