• Title/Summary/Keyword: 에너지 정의

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Growth and Optical Properties of PbSnSe Epilayers Grown on BaF2(111) (PbSnSe 단결정 박막의 성장과 광학적 특성)

  • Lee, Il-Hoon
    • Journal of Korean Ophthalmic Optics Society
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    • v.9 no.1
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    • pp.35-41
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    • 2004
  • This study investigated the crystal growth, crystalline structure and the basic optical properties of $PbSnSe/BaF_2$ epilayers. The PbSnSe epilayer was grown on $BaF_2$(111) insulating substrates using a hot wall epitaxy (HWE) technique. It was found from the analysis of X-ray diffraction patterns that $PbSnSe/BaF_2$ epilayer was grown single crystal with a rock-salt structure oriented along [111] the growth direction. Using Rutherford back scattering, the atomic ratios of the PbSnSe was found to be proper stoichiometric. The best values for the full width at half maximum (FWHM) of the DCXRD was 162 arcsec for PbSnSe epilayer. The epilayer-thickness dependence of the FWHM of the DCXRD shows that the quality of the $PbSnSe/BaF_2$ is as expected. The dielectric function ${\varepsilon}(E)$ of a semiconductor is closely related to its electronic energy band structure and such relation can be drawn from features around the critical points(CPs) in the optical spectra. The real and imaginary parts(${\varepsilon}1$ and ${\varepsilon}2$) of the dielectric function ${\varepsilon}$ of PbSe were measured, and the observed spectra reveal distinct structures at energies of the E1, E2 and E3 CPs. These data are analyzed using a theoretical model known as the model dielectric function (MDF). The optical constants related to dielectric function such as the complex refractive index ($n^*=n+ik$), absorption coefficient (${\alpha}$) and normal-incidence reflectivity (R) are also presented for $PbSnSe/BaF_2$.

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Effect of Typhoon 'Rusa' on the Natural Yeon-gok Stream and Coastal Ecosystem in the Yeong-Dong Province (영동지방 자연형 하천(강릉 연곡천)과 인근 연안 생태계에 대한 태풍 루사의 영향)

  • Yoon Yi-Yong;Kim Hung-sub
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.7 no.1
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    • pp.35-41
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    • 2004
  • The yeongok stream originates at the natural park, Mt. O-dae and flows to the East Sea of korea, normally maintaining I or II grade of water quality and its average water flux is 352,100 ㎥/d. However, the typhoon 'Rusa', which occured on 31 August 2002, changed its watercourse and configuration, and the ecosystem was deeply damaged. Moreover, the hydrological characteristics were once more transformed, and the ecosystem was secondarily damaged during repair-work of destroyed bridges and elevations. After the flood disaster, the species diversity diminished 17% for attached diatom and 44% for aquatic animals. However, the earth and sand, dug from river bed during intensive repair-work throughout the entire stream, made diversity drop to 32% for the diatom and the aquatic animals were wiped out. Especially, fishes were totally destroyed except for some species such as Moroco oxycephalus in the upper stream. The yeongok stream has little contamination source and short water residence time due to the short length and rapid slope, and consequently a temporary deterioration of water quality caused by repair-work may be rapidly recovered, but it needs a long time to restore the damaged ecosystem.

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Assessment of Carbon Emission for Quantification of Environmental Load on Structural Glued Laminated Timber in Korea (국산 구조용 집성재의 환경부하 정량화를 위한 온실가스 배출량 분석)

  • Chang, Yoon-Seong;Kim, Sejong;Son, Whi-Lim;Lee, Sang-Joon;Shim, Kug-Bo;Yeo, Hwanmyeong;Kim, Kwang-Mo
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.3
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    • pp.449-456
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    • 2016
  • This study was aimed to quantify the amount of carbon dioxide emissions and to suggest suitable plans which consider the carbon emission reduction in the manufacturing process of the domestic structural glued laminated timber. Field investigation on two glued laminated timber manufacturers was conducted to find out material flow input values such as raw materials, transportation, manufacturing process, and energy consumption during manufacturing process. Based on the collected data and the relevant literatures about life cycle inventory (LCI), the amount of carbon dioxide emission per unit volume was quantified. Results show that the carbon dioxide emissions for sawing, drying and laminating process are 31.0, 109.0, 94.2 kg $CO_2eq./m^3$, respectively. These results show 13% lesser amount of total carbon dioxide emissions compared with the imported glued laminated timber in Korea. Furthermore, it was decreased about 37% when the fossil fuel would be replaced with biomass fuel in drying process. Findings from this study is effectively used as the basic data on the life cycle assessment of wooden building.

SEM EVALUATION AND SHEAR BOND STRENGTH OF ER : YAG LASER IRRADIATION ON ENAMEL SURFACE (Er : YAG 레이저 조사가 법랑질 표면 변화와 전단강도에 미치는 영향)

  • Lim, Hyoung-Soo;Lee, Chang-Seop;Lee, Sang-Ho
    • Journal of the korean academy of Pediatric Dentistry
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    • v.28 no.3
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    • pp.374-382
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    • 2001
  • The purpose of this study was to investigate the surface morphology and measure shear bond strength of Er : YAG lased enamel. To determine the most effective energy density of laser for improving bonding strength of human enamel, 24 specimen were lased from 30mJ to 150mJ at 1Hz used focused, defocused beam. After irradiation, the lased specimen were observed scanning electron microscope. To determine the resin shear bond strength of Er : YAG lased enamel, the 90 specimen were divided into 3 groups. The Control group was etched with 37% phosphoric acid for 15seconds and rinsed. Group 1 was only laser irradiaton(60mJ, 10Hz), Group 2 was irradiated as Group 1 regimen, followed 37% phosphoric acid etching. The following results were obtained: 1. In both focused and defocused Er : YAG lased enamel surface are similar to acid-etched enamel more than 60mJ in SEM evaluation. 2. The more increased laser energy, the more observed fissuring surface. 3. The highest mean shear bond strength value was observed in control group with the statistical significance(p<0.05) between all the other groups and the shear bond strength in group 1 was the lowest with significant difference among the other groups.

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Study on the Long-term Reliability of Solar Cell by High Temperature & Humidity Test (고온고습 시험을 통한 태양전지의 장기 신뢰성에 관한 연구)

  • Kang, Min-Soo;Jeon, Yu-Jae;Kim, Do-Seok;Shin, Young-Eui
    • Journal of Energy Engineering
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    • v.21 no.3
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    • pp.243-248
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    • 2012
  • In this study, The report analysed the characteristics of power drop and damage of surface in solar cell through high temperature and humidity test. The solar cells were tested during the 1000hr in $85^{\circ}C$ temperature and 85% humidity conditions, that excerpted standard of PV Module(KS C IEC-61215). An analysis of the cell surface through EL(Electroluminescence), the cell has partly change of surface in yearly. Single-crystalline Solar cell efficiency is decreased from 17.7% to 15.6% and decreasing rate is 11.9%. On the other hand, Poly-crystalline Solar cell efficiency is decreased from 15.5% to 14.0% and decreasing rate is 9.3%. A comparison of the fill factor for analysis of electro characteristic in yearly, Single-crystalline Solar cell efficiency is decreased from 78.7% to 78.1% and decreasing rate is 4.7%. On the other hand, Poly-crystalline Solar cell efficiency is decreased from 78.1% to 76.7% and decreasing rate is 1.8%. Single-crystalline has more bigger power drop than poly-crystalline by the silicon purity and silicon atom arrangement. Also, FF decreasing rate has more bigger drop than efficiency decreasing rate for the reason that the damage of surface by exterior environmental factor is the more influence in cell than other reason that is decreasing FF by damage of p-n junction.

다국가 시나리오를 포함하는 사용후 핵연료 관리(저장, 재처리, 처분)의 전략

  • Kim, Seong-Ho;O, Won-Jin;Park, Won-Jae
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2009.06a
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    • pp.35-36
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    • 2009
  • 지속가능 에너지원인 원자력은 또한 글로벌 에너지원의 특성을 갖추고 있다 핵연료는 원자로에 장전되는 신규 핵연료를 구성하고 있는 우라늄 채광 단계에서부터 연소 후에 발생하는 사용후 핵연료 (SNF 또는 SF) 관리 단계에 이르는 전과정에 걸쳐 핵연료 사이클로 파악되고 있다. 이러한 전과정 관점에서 볼 때, 핵연료 사이클에 관여하는 이해관계자는 자국뿐만 아니라 다국가 (multination)를 포함하고 있다. 특히, 후행 핵연료 사이클인 사용후 핵연료의 저장, 처리, 처분 단계에서는 다국가 시나리오를 배제하지 않는 사용후 핵연료 관리 전략의 도입이 고려될 수 있다. 여기서 다국가는 접경 국가, 인접 국가, 핵연료 공급 국가, 재처리 제공 국가, 재처리 위탁 국가, SNF 통과 허용 국가, SNF 저장 부지 제공 국가, SNF 향후 이용 국가 등이 될 수 있다 [김성호 2006]. 현재 우리나라에서는 여러 국가로부터 수입되고 있는 신규 핵연료 물질을 연소시켜 나온 사용후 핵연료를 부지내에 임시 저장하고 있다. 사용후 핵연료 발생량의 추산에 따르면, 2016년쯤에 현재 임시저장 용량이 포화될 예정이다 이러한 상황에서 다국가 시나리오를 포함한 관리 전략은 다국가 시나리오를 배제한 관리 전략과 다각적인 측면 에서 비교 검토될 필요성이 있다. 사용후 핵연료의 영구 처분장 부지 확보를 해결하기 위한 선행 단계로 공론화 단계가 지금 준비되고 있다. 예컨대, 단기 공론화 관리 방안의 하나로 비록 소극적인 입장이지만 타국 위탁 재처리 방식이 고려되고 있다 [KRS 2009] 이 연구에서는 단기적인 사용후 핵연료 관리 전략으로 여러 가지 다국가 수준의 저장, 처리, 처분 방식으로 바탕으로 다국가 시나리오들을 제안하려고 한다. 이들 다국가 시나리오를 포함한 관리 전략은 현재 다국가 시나리오를 배제한 국내 사용후 핵연료 처분장 부지 선정이 정치적/사회적 수용성 문제로 어려운 상황에 처할 경우에 해결책을 찾는 데에 기여하리라 본다. 또한, 부지 선정 단계에서 바라지 않는 난항이 나타나는 경우에 국가 차원의 한 대비책으로 다음을 제안한다: 한편으로는 자국 저장 시설이 추진되면서, 다른 편으로는 타국 저장 부지를 확보하는 전략이 검토되어야 한다. 이러한 이중 노선 (dual track) 전략은 여러 유럽 국가에서 이미 고려되고 있는 방안이다 [Greenpeace 2005] 다양한 다국성 정도 (a degree of multinationality) 의 저장, 처리, 처분 방식을 연결하는 가능한 다국가 시나리오 구조가 Fig.1에 제시되어 있다. 다국가 시나리오를 구성하는 기본 요소는 다음과 같다’ 1) 자국 임시 저장; 2) 자국 재처리; 3) 자국 중간 저장; 4) 자국 영구 처분; 5) 다국가 중간 저장; 6) 다국가 재처리; 7 ) 다국가 영구 처분. 이들 기본 요소들을 다국성 정도에 따라 결합하면 다양한 다국가 시나리오들이 얻어진다. 이들을 포함한 SNF 관리 전략은 크게는 1) 다국가 재처리 전략, 2) 다국가 저장 및 재처리 전략, 또는 3) 다국가 처분 전략 등으로 분류될 수 있다.

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Growth of CdS Single Crystal as Photoconductor and Its Physical Characteristics (광전도체의 CdS 단결정 성장과 물리적 특성)

  • Jeong, T.S.;Yu, P.Y.;Shin, Y.J.;Shin, H.K.;Kim, T.S.;Jeong, C.H.;Lee, H.;Shin, Y.S.;Hong, K.J.;Rheu, K.S.
    • Journal of Sensor Science and Technology
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    • v.2 no.1
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    • pp.109-115
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    • 1993
  • A CdS single crystal was grown by using sublimation method. Lattice constants, $a_{o}$ and $c_{o}$, obtained by using extrapolation were $4.131{\underline{8}}{\AA}$ and $6.712{\underline{2}}{\AA}$, respectively. The carrier density was${\sim}10^{23}m^{-3}$ and the mobility was $2.93{\times}10^{-2}m^{2}$/V sec from measured Hall data at room temperature. The mobility has a increasing tendency in proportion to $T^{1/2}$ from 33 K to 150 K and a decreasing tendency in proportion to $T^{-2}$ from 180 K to room temperature. The short wavelength band peak measured from photocurrent was due to intrinsic transition, and the energy value of this peak was equal to the energy band gap of CdS photoconductor.

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The Effect of Feed Temperature On Permeate Flux During Membrane Separation (온도가 막분리 투과성능에 미치는 영향)

  • Kim, Kwang Soo;Moon, Deok Soo;Kim, Hyeon Ju;Lee, Seung Won;Ji, Ho;Jung, Hyeon Ji;Won, Hye Jung
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.17 no.1
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    • pp.13-19
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    • 2014
  • The feed temperature has an effect on the performance during desalination of seawater by membrane separation. When the permeate flux intends to increase using the waste heat, it is necessary to analyze the effect of feed temperature precisely on the membrane performance. The experiments were carried out to investigate the performance of membranes by varying the seawater temperature from $10^{\circ}C$ to $60^{\circ}C$. The increase of permeate flux with increase of feed temperature was interpreted as the change of water viscosity and the membrane itself. While the increase of permeate flux could be predicted by the viscosity change in case of nanoflitration membrane, there exists 30% difference between the experiment data and the prediction by the viscosity change in case of reverse osmosis (RO) membrane, which seems to be due to 8% decrease of the pore size in 60caused by the contraction of membrane with the increase of temperature. Therefore, the desalination of seawater should be carried out within the range that the elevation of temperature does not cause the alteration of membrane itself even for the purpose of increasing the permeate flux.

Low-iridium Doped Single-crystalline Hydrogenated Titanates (H2Ti3O7) with Large Exposed {100} Facets for Enhanced Oxygen Evolution Reaction under Acidic Conditions ({100} 단결정 수소화 티타네이트(H2Ti3O7)를 활용한 저함량 Irridium 수전해 양극 촉매 개발)

  • Sun Young Jung;HyukSu Han
    • Journal of the Microelectronics and Packaging Society
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    • v.30 no.1
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    • pp.79-89
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    • 2023
  • Development of efficient and stable electrocatalysts for oxygen evolution reaction (OER) under acidic conditions is desirable goal for commercializing proton exchange membrane (PEM) water electroyzer. Herein, we report iridium-doped hydrogenated titanate (Ir-HTO) nanobelts as a promising catalyst with a low-Ir content for the acidic OER. Addition of low-Ir (~ 3.36 at%) into the single-crystalline HTO nanobelts with large exposed {100} facets significantly boost catalytic activity and stability for OER under acidic conditions. The Ir-HTO outperforms the commenrcial benchmark IrO2 catalyst; an overpotential for delivering 10 mA cm-2 current density was reduced to about 25% for the Ir-HTO. Moreover, the catalytic performance of Ir-HTO is positioned as the most efficient electrocatalyst for the acidic OER. An improved intrinsic catalytic activity and stability are also confirmed for the Ir-HTO through in-depth electrochemical characterizations. Therefore, our results suggest that low-Ir doped single-crystalline HTO nanobelts can be a promising catalyst for efficient and durable OER under acidic conditions.

Life Cycle Environmental Analysis of Valuable Metal (Ag) Recovery Process in Plating Waste Water (폐도금액내 유가금속(Ag) 회수 공정에 대한 전과정 환경성 분석)

  • Da Yeon Kim;Seong You Lee;Yong Woo Hwang;Taek Kwan Kwon
    • Resources Recycling
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    • v.32 no.2
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    • pp.12-18
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    • 2023
  • In 2018, the demand for silver (referred to as Ag) in the electrical and electronics sector was 249 million tons. The demand stood at 81 million tons in the solar module production sector. Currently, due to the rapid increase in solar module installation, the demand for silver is increasing drastically in Korea. However, Korea's natural metal resources and reserves are insufficient in comparison to their consumption, and the domestic silver ore self-sufficiency rate was as low as 2.2% as of 2021. This implies that a recycling technology is necessary to recover valuable metal resources contained in the waste plating solution generated in the metal industry. Therefore, this study compared and analyzed, the results of the impact evaluation through life cycle assessment according to an improvement in the process of recovery of valuable metals in the waste plating solution. The process improvement resulted in reducing GWP (Global Warming Potential) and ADP(Abiotic Depletion Potential) by 50% and 67%, respectively. The GWP of electricity and industrial water was reduced by 98% and 93%, respectively, which significantly contributed to the minimization of energy and water consumption. Thus, the improvement in recycling technology has a high potential to reduce chemical and energy use and improve resource productivity in the urban mining industry.