• Title/Summary/Keyword: 에너지 및 연료 기술

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Preparation of Bio-oil from Ginkgo Leaves through Fast Pyrolysis and its Properties (은행잎 바이오매스로부터 급속 열분해를 통한 바이오-오일 생산 및 특성 연구)

  • In-Jun Hwang;Jae-Rak Jeon;Jinsoo Kim;Seung-Soo Kim
    • Clean Technology
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    • v.29 no.3
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    • pp.200-216
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    • 2023
  • Ginkgo leaves are considered waste biomass and can cause problems due to the strong insecticidal actions of ginkgolide A, B, C, and J and bilobalide. However, Ginkgo leaf biomass has high organic matter content that can be converted into fuels and chemicals if suitable technologies can be developed. In this study, the effect of pyrolysis temperature, minimum fluidized velocity, and Ginkgo leaf size on product yields and product properties were systematically analyzed. Fast pyrolysis was conducted in a bubbling fluidized bed reactor at 400 to 550℃ using silica sand as a bed material. The yield of pyrolysis liquids ranged from 33.66 to 40.01 wt%. The CO2 and CO contents were relatively high compared to light hydrocarbon gases because of decarboxylation and decarbonylation during pyrolysis. The CO content increased with the pyrolysis temperature while the CO2 content decreased. When the experiment was conducted at 450℃ with a 3.0×Umf fluidized velocity and a 0.43 to 0.71 mm particle size, the yield was 40.01 wt% and there was a heating value of 30.17 MJ/kg, respectively. The production of various phenol compounds and benzene derivatives in the bio-oil, which contains the high value products, was identified using GC-MS. This study demonstrated that fast pyrolysis is very robust and can be used for converting Ginkgo leaves into fuels and thus has the potential of becoming a method for waste recycling.

Depolymerization of Kraft Lignin over a Ru-Mg-Al-oxide Catalyst (Ru-Mg-Al-oxide 촉매 상에서 크라프트 리그닌의 저분자화 연구)

  • Kim, Han Ung;Limarta, Susan Olivia;Jae, Jungho
    • Clean Technology
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    • v.27 no.2
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    • pp.190-197
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    • 2021
  • Kraft lignin is a by-product of the pulp and paper industry, obtained as a black liquor after the extraction of cellulose from wood through the Kraft pulping process. Right now, kraft lignin is utilized as a low-grade boiler fuel to provide heat and power but can be converted into high-calorific biofuels or high-value chemicals once the efficient catalytic depolymerization process is developed. In this work, the multi-functional catalyst of Ru-Mg-Al-oxide, which contains hydrogenation metals, acid, and base sites for the effective depolymerization of kraft lignin are prepared, and its lignin depolymerization efficiency is evaluated. In order to understand the role of different active sites in the lignin depolymerization, the three different catalysts of MgO, Mg-Al-oxide, and Ru-Mg-Al-oxide were synthesized, and their lignin depolymerization activity was compared in terms of the yield and the average molecular weight of bio-oil, as well as the yield of phenolic monomers contained in the bio-oil. Among the catalysts tested, the Ru-Mg-Al-oxide catalyst exhibited the highest yield of bio-oil and phenolic monomers due to the synergy between active sites. Furthermore, in order to maximize the extent of lignin depolymerization over the Ru-Mg-Al-oxide, the effects of reaction conditions (i.e., temperature, time, and catalyst loading amount) on the lignin depolymerization were investigated. Overall, the highest bio-oil yield of 72% and the 3.5 times higher yield of phenolic monomers than that without a catalyst were successfully achieved at 350 ℃ and 10% catalyst loading after 4 h reaction time.

A Study on Design of Optimal Location for Renewable Energy Facility Using GIS (GIS를 사용한 재생에너지설비 최적 위치 설계에 관한 연구)

  • Jung, Moon-Seon;Moon, Chae-Joo;Chang, Young-Hak;Kim, Young-Gon;Lee, Sook-Hee
    • The Journal of the Korea institute of electronic communication sciences
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    • v.13 no.2
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    • pp.357-368
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    • 2018
  • For well over 100 years, oil has enabled remote communities to generate electricity and enjoy the benefits of a consistent electrical supply. Relying solely on oil for electricity generation has left island and remote communities exposed to several risks and drawbacks. Oil-based electricity generation is often more expensive and subject to price volatility, which can result in the use of risky fuel hedging strategies. The residents of islands and remote communities express concern over the future impacts of climate change or insist on their opinions for the corresponding action with reduction of carbon emissions. These risks and drawbacks can be overcomed with continuing cost reductions in solar, wind, and energy storage technologies by maker. Reducing costs is not always a straightforward process, relying on more diversely and renewably arranged renewable energy sources led to reduced local construction cost in every situation reviewed in this study. In this paper, a convenient and simple design solution which will facilitate the optimum location and transmission route of renewable energy facility using GIS(Geographic Information System) is proposed. The suggested solutions exercised to the case of geomoon island using GIS and identified by local site survey.

Finite Element Analysis of Gas Pipelines Depend on the Arctic of Active Region (극한지 활동층 변화에 따른 천연가스배관의 유한요소해석)

  • Yeom, Kyu Jung;Kim, Kyung Il;Kim, Young-Pyo;Oh, Kyu Hwan;Kim, Woo Sik
    • Journal of the Korean Institute of Gas
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    • v.18 no.5
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    • pp.72-77
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    • 2014
  • It is known that there is no demand for building the arctic environment in Korea. However, it is important to use the different energy source instead of fuel source due to global warming. It is now demanded of using gas of Alaska and Siberia for long term developing the natural gas. The design of gas pipelines in Korea is very different from the arctic region. The operation of gas in arctic region have to consider of arctic region such as permafrost and active regions. It is needed to understand of gas pipeline design with different arctic soil properties. Nowadays, the pipelines is designed with stress-based and but there is demanded for strain based design with more deformed pipeline. We study of arctic environment with different active region using Finite Element Method of thermal elasto-plastic analysis.

Understanding Thermal Runaway Phenomena in Overcharged Lithium-Ion Batteries (리튬이차전지의 과충전에 의한 열폭주 현상의 이해)

  • Minseo Lee;Ji-sun You;Kyeong-sin Kang;Jaesung Lee;Sungyool Bong
    • Journal of the Korean Electrochemical Society
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    • v.27 no.2
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    • pp.55-72
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    • 2024
  • Secondary batteries are used as an essential renewable energy source in our lives, such as electric vehicles and energy storage systems (ESS), as an alternative to fossil fuels due to global warming. However, cases of battery fires and explosions have been reported due to thermal runaway in secondary batteries due to various causes such as overdischarge, high-speed charging and discharging, and external short circuit, and great efforts are being made to find solutions suitable for each cause. In particular, as cases presumed to be caused by the overcharging process have been reported, this review will examine the chemical reactions of secondary batteries that can occur during the overcharging process and discuss risk investigation methods to check and prevent them.

Development and efficiency evaluation of 30kW scale syngas cogeneration system (30kW 급 합성가스 열병합 시스템 개발 및 효율 성능평가)

  • Park, Il-Gun;Kim, Sang-Tae;Noh, Gwi-Sung
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.4
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    • pp.1427-1433
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    • 2019
  • In this paper, Gas engine was tested for the energy of synthesis gas. As excess air ratio increase 1, 1.1, 1.2, 1.3, 1.4, 1.5, 1.6 in 1800 rpm and synthesis gas, thermal efficiency generally decrease and power generation was 34 kWm at λ 1.4. And excess air ratio increase 1, 1.1, 1.2, 1.3, 1.4 in power generation 34 kWm, thermal efficiency generally increase 34.2%, 36.9%, 37.2%, 37.4%, 38.1%. Total efficiency through power generation consumes 38.7 kg/h of fuel at 30 kWe load and recovers 57.3% of waste heat by recovering 57.3 kW of waste heat through 32.1% power generation efficiency and heat recovery from cooling water and exhaust gas. The total efficiency was 85.8%.

Development of New Techniques of Electrostatic Separation for Using of Clean Coal (청정석탄(淸淨石炭) 이용(利用)을 위한 정전선별(靜電選別) 기술개발(技術開發))

  • Baek, Sang-Ho;Jeon, Ho-Seok;Han, Oh-Hyung
    • Resources Recycling
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    • v.14 no.5 s.67
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    • pp.54-61
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    • 2005
  • In 2006, the coal usage that is used as energy source of power plant will meet 16,000 MW which is 30% of the whole energy usage. A Coal deposits among the fossil fuels is very plentiful in natural resources and has high economical efficiency but application technique is very inconvenient. Also when burned for utilization, it generate various toxic and untoxic air pollution materials; fly ash, bottom ash, sulfurous acid gas etc. In this study, we could establish a preparation of clean coal by triboelectrostatic separation. In this study, we made a bench-scale's triboelectrostatic separation equipment using electrostatic technology, and got an optimum conditions of various factors for increasing recovery rate and purification in separation. A test result, we got a clean coal that recovery rate is 68.10%, rejection rate of ash and sulfur content is 31.23% and 28.33%.

Saemangeum feasibility study for offshore wind in yeongeunhae Remote monitoring pungryeokgecheuk (새만금 연근해의 해상풍력 타당성 조사를 위한 원격감시 풍력계측)

  • Choi, Yeon-Sung;Choi, Yong-Won;Jeon, Chil-Hwan
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.2 no.3
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    • pp.3-8
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    • 2009
  • Environmental pollution caused by fossil fuel use and energy sources, the big concern is the rise of the current situation, one of the ways to overcome the interest in renewable energy is Gozo. Located on the west coast, especially the Saemangeum area and the northwest wind, the big advantage of the vast area that's got quite a number of wind turbines is expected. This study affirms that these expectations can be a wind energy resource survey sea area of the average wind speed of Kunsan 5 ~ 7m / s is enough, books are linked to the local marine wind farms can safely say that none of choejeokji said. In addition, the emergence of the wind resource to determine the density of the Weibull distribution is calculated using the number 1, the shape factor as a parameter to calculate the density of the wind a result, Gunsan Province was able to predict the emergence of the wind. In addition, by controlling the remote monitoring through the measurement exceeded the convenience and reliability at the same time you can achieve great results.

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Prediction for the quantity of wood pellet demand and optimal biomass power generation according to biomass power plant expansion and co-firing plan (바이오매스 발전설비 증설·혼소 계획에 따른 Wood pellet 소요량 예측 및 최적 바이오매스 발전량 연구)

  • kim, Sang-Seon;Lee, Bong-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.4
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    • pp.818-826
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    • 2017
  • In accordance with the New and Renewable Energy Supply Statistics, biomass power generation has surged since 2013, and use of wood pellet has the most sharply increased, 696Gwh in 2013, 2,764Gwh in 2014 and 2,512Gwh in 2015. Total domestic wood pellet consumption was 1.48million tons in 2015, of which wood pellets consumed for power generation account for about 1.08million tons, about 73%. In this study, we gained the result that the wood pellet would be consumed 2.61million tons in 2020, 6.85million tons in 2025, 11.39million tons in 2030. We also calculated the optimum biomass power generation, on the premise that the power plant co-fire 50% biomass, and the result was that 2.26million tons of wood pellets should be produced domestically in 2021 to operate the present licensed wood pellet power plant from this study.

Fabrication and thermal stability of flower-like CeO2 with high surface area via anisotropic crystallization of carbonate precipitation (탄산염 침전 전구체의 결정 이방성 제어를 통한 고 비표면적 flower-like CeO2 분말의 제조 및 고온 안정성 평가)

  • Kim, Hanbit;Shin, Tae Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.4
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    • pp.160-166
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    • 2019
  • Cerium oxide ($CeO_2$, often called as Ceria) is one of the valuable rare earth oxide materials, which has been widely used for high temperature applications such as solid oxide fuel cells, automotive three-way catalysts and oxygen storage capacity. Considering those application, it is important to improve high redox and thermal stability with high surface morphology because the high surface area of $CeO_2$ could improve the catalytic reactivity at high temperature conditions. Herein we successfully fabricated hierarchical flower-like $CeO_2$ deposited via controlling pathway of precipitation reaction to supply carbonate ion lead to the flower-like morphology. The hexagonal lattice system of precipitated precursor shows better thermal stability then orthorhombic one during thermal cycling condition.