• Title/Summary/Keyword: 액체 질소

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Transient State Theory of Significant Liquid Structure Applied to Nitrogen Oxides (액체 구조의 천이상태이론의 질소산화물들에 대한 적용)

  • Kim, Sang-Hyung;Pak, Hyung-Suk;Kim, Kak-Choong;Chang, Sei-Hun
    • Journal of the Korean Chemical Society
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    • v.11 no.3
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    • pp.105-110
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    • 1967
  • The transient state theory of significant liquid structure is applied to nitrous oxide and nitrogen tetroxide. The partition functions for the two liquids are derived according to the transient state theory. The various thermodynamic properties; such as, molar volumes, vapor pressures, entropies of vaporization, and critical point properties agree well with the experimental values.

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Development of bearing/sealing test facility for turbopump system (터보펌프 시스템용 베어링/실 시험설비 개발)

  • 우관제;김경호;우유철
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2003.10a
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    • pp.25-28
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    • 2003
  • The bearing/sealing test (BST) facility is intended for tests of bearing and seal for turbopump of liquid rocket engine (LRE) in various media (water, liquid nitrogen, liquid oxygen). The bearing test for serviceability is fulfilled with the estimation of the flow rate of cooling medium through the test bearing separator and with the simulation of axial and(or) radial loading. The purpose of seals test is the determination of magnitude of leakages through the seal and a time variation of this magnitude.

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Statistical Thermodynamical Calculation of the Surface Entropy of Liquids (액체 포면 엔트로피의 통계 열역학적 계산)

  • Park, Sung-Hye;Pak, Hyung-Suk;Chang, Sei-Hun
    • Journal of the Korean Chemical Society
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    • v.8 no.4
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    • pp.183-187
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    • 1964
  • The excess molar surface entropies of each surface layers are calculated applying the modified significant structure theory of liquid. The calculated excess molar surface entropy for the first top surface layer is slightly greater than the entropy of surface formation of ideal molecules,$^5$ the latter is equal to Rln2. The excess entropy for the second surface layer is small and that for the third layer is negligible at low temperatures. The surface tensions of argon, nitrogen, methane, benzene and halogens are calculated applying the modified significant structure theory of liquid.

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Behavior of Liquid Nitrogen in the Cryogenic Storage Tank (초저온액화가스 저장탱크 내에서의 액화질소의 거동)

  • Park Byung Whee;Lee Hyun Chul;Park Doo Seon;Son Moo Ryong
    • Journal of the Korean Institute of Gas
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    • v.2 no.3
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    • pp.37-48
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    • 1998
  • A cryogenic liquid stored in the closed cryogenic tank has been studied at various liquid levels. The change of pressure, temperature, and liquid-vapor ratio in the tank depended on the liquid levels. The various phenomena were shown at different liquid levels as follows: (1) liquid level was increased with condensation of vapor: (2) liquid was vaporized in spite of liquid level going up for a certain initial period and then condensation of vapor occurred at higher pressure; (3) liquid was vaporized without liquid level change; (4) liquid was vaporized with liquid level decreasing. If the tank is full with cryogenic liquid, it is extremely dangerous because of soaring the pressure. Therefore the tank must be filled with $90\%$ liquid according to the safety rules. If the tank was filled with $0\%$ ullage, the pressure increment as high as 80bar during first 5 days. With $90\%$ liquid level, however, the pressure was increased as low as 1.5bar in the same period. No matter what the liquid level is, it is very dangerous if the tank is locked-up with filled cryogenic liquid for a long time.

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Effect of Nitrogen Injection Pressure on Lqiufied Engine Performance (질소 분사 압력이 액화질소 엔진의 성능 특성에 미치는 영향)

  • Shin, Donggil
    • Journal of Energy Engineering
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    • v.26 no.1
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    • pp.28-33
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    • 2017
  • A liquid nitrogen engine is a highly clean power engine, which does not emit any hazardous substances in its fumes. Additionally, it has an advantage over electric vehicles, as its energy density is larger than that of a battery. The use of an existing liquid nitrogen engine is typically limited to the reciprocation type. In this study, the concept of a nitrogen engine equipped with a scroll expander is introduced. The engine's efficiency was shown to increase when the scroll expander was utilized in the engine, while also adding to the simplification of the structure. Therefore, compared to the existing reciprocation-type engine, the engine with the scroll expander has the potential to be both technically and economically more competitive. In this study, the performance of a liquid nitrogen engine equipped with a scroll expander was analyzed while altering the injection pressure profile of liquid nitrogen.

Cryogenic Performance Test of LOX Turbopump in Liquid Nitrogen (액체질소를 이용한 산화제펌프의 극저온 성능시험)

  • Kim, Jin-Sun;Hong, Soon-Sam;Kim, Dae-Jin;Choi, Chang-Ho;Kim, Jin-Han
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.4
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    • pp.391-397
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    • 2010
  • Performance tests of a liquid-oxygen pump were carried out using liquid nitrogen (LN2) as a working fluid in a cryogenic turbopump test facility in Korea Aerospace Research Institute (KARI). The tests were performed at 30-55% of the design rotational speed, and the results were compared with those from a water test. The experimental results confirmed the similarity of the hydraulic performance, which allows the prediction of the pump performance at a design rotational speed of 20,000 rpm. The overall cavitation performance of the pump in the cryogenic environment was better than that in the water environment for all ranges of flow rates and rotational speeds. Critical cavitation number at the design flow rate was determined as 0.012 from the cryogenic test, and as 0.024 from the water test. The improved cavitation performance is due to the thermodynamic effect in cryogenic fluids.

헬륨냉동계통의 헬륨가스 순도 제어 운전

  • Choe, Ho-Yeong;Son, U-Jeong;Lee, Mun;An, Guk-Hun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.171-171
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    • 2011
  • 헬륨냉동계통은 연구용 원자로인 하나로에서 냉중성자를 생산할 수 있도록 설치된 수조내기기 내의 감속재인 수소가 정상적으로 열 사이펀을 유지하기 위한 주요 계통이다. 헬륨냉동계통은 헬륨가스를 압축하는 헬륨 압축부분과 헬륨가스를 팽창시켜 저온을 생성시키는 헬륨 팽창부분으로 나누어진다. 헬륨 압축부분은 두 개의 스크류가 맞물려 회전하면서 약 1.05 bar(a)의 헬륨가스를 최대 13 bar(a)까지 압축시키는 압축기가 있으며, 헬륨 팽창부분인 냉동박스의 팽창 터빈은 self-acting gas bearing에 의해 구동되며, 저온모드 운전 시작시 헬륨 압축부분에서 일부의 가스는 팽창 터빈 축(shaft)으로 유입되어 회전속도가 서서히 증가하면서 고속으로 회전하여 극저온의 헬륨가스(14~18 K)를 생성하는 주요 기기이다. 헬륨을 팽창하는 부분인 냉동박스 내로 헬륨 압축가스를 유입하기 전에 압축된 헬륨가스 내 불순물의 순도를 분석하여 냉동박스의 주요 부품인 팽창터빈의 운전에 영향을 미치지 않는 것이 가장 중요하다. 따라서 헬륨 저압측에 헬륨가스 내 불순물 즉, 수소($H_2$), 수분($H_2O$), 질소($N_2$), 탄화수소류(CxHy) 및 오일(Oilaerosol) 등의 함량을 분석하기위해 가스 분석기가 설치되어 있으며, 냉동박스 내로 유입되기 전에 헬륨압축에서 순환되는 가스 내 불순물인 수분, 질소, 탄화수소류 및 오일은 10 vpm 이하이어야 하며, 수소 함량은 0.1 % 이내이어야 한다. 헬륨 압축부분에서 순환되는 가스의 불순물이 요구 조건에 만족하도록 헬륨 고압측과 헬륨 저압측에 cryogenic adsorber를 설치하여 가스 내 불순물을 제거하는 가스순도제어 작업을 수행해야 한다. cryogenic adsorber를 사용하기 위해서는 장치 내의 불순 가스를 공정진공도(1.33 X $10^{-3}$ mbar) 이하로 진공배기하는 작업이 매우 중요하다. 이는 계통의 헬륨가스가 오염되지 않도록 하는 것으로 cryogenic adsorber 내에는 액체질소를 충전하여 액체질소 온도에 노출된 활성탄층을 헬륨가스가 흐르면서 수분, 질소, 탄화수소류 및 오일 등이 제거된다. 이 논문에서는 헬륨냉동계통의 가스 순도 제어 작업을 통해 헬륨가스의 순도가 요구조건 이하로 만족하며, 팽창 터빈의 운전에 영향을 미치지 않음을 기술하고자 한다.

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