• Title/Summary/Keyword: 액체 수소

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Preliminary Economic Analysis for H2 Transportation Using Liquid Organic H2 Carrier to Enter H2 Economy Society in Korea (수소경제사회 실현을 위한 액체 유기 수소캐리어를 이용한 수소 수송 관련 예비 경제성 평가)

  • LEE, BOREUM;LEE, HYUNJUN;MOON, CHANGHWAN;MOON, SANGBONG;LIM, HANKWON
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.2
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    • pp.119-127
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    • 2019
  • Reliable $H_2$ supply is necessary for entering a $H_2$ society. Among the various $H_2$ storage and transportation methods, liquid organic $H_2$ carrier (LOHC) is in the spotlight because of a lot of advantages compared to conventional one such as compressed $H_2$ and liquefied $H_2$. Therefore, we performed preliminary economic analysis of $H_2$ supply cost using LOHC for a $H_2$ production capacity of $300Nm^3\;h^{-1}$ employing itemized cost estimation and sensitivity analysis to evaluate economic viability of this technology in Korea.

Thermal Analysis of a Liquid Hydrogen Vessel with Multi-Layer-Insulation and Vapor-Cooled Shield (다층단열재와 증기냉각쉴드를 사용한 액체수소 저장용기의 열해석)

  • Jung, Il-Kwon;Kang, Byung-Ha
    • Transactions of the Korean hydrogen and new energy society
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    • v.16 no.3
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    • pp.284-289
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    • 2005
  • Thermal analysis of cryogenic-capable vessels with insulations have been carried out to store liquid hydrogen($LH_2$). The combined insulations of MLI(Multi-Layer Insulation) and VCS(Vapor-Cooled Shield) under high vacuum are considered in the analysis for various volumes of vessels. Vapor-Cooled Shields(VCS) are installed at cylinder wall as well as disc side of the $LH_2$ vessels. The results indicate that optimal distribution of boiloff vapor from $LH_2$ vessel into two sides of VCS exists based on the evaporation loss. As the volume of $LH_2$ vessel is increased, mass flow rate of boiloff is increased while the evaporation loss per unit volume is decreased.

System Analysis of Expander Cycle Hydrogen Rocket Engine (팽창기 사이클 수소 로켓엔진의 시스템 해석)

  • Ha, Donghwi;Roh, Tae-Seong;Lee, Hyoung Jin;Yoo, Phil Hoon
    • Journal of the Korean Society of Propulsion Engineers
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    • v.24 no.5
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    • pp.21-33
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    • 2020
  • In this study, the program for system analysis of an expander cycle rocket engine using liquid hydrogen as a fuel was developed. The properties of hydrogen were considered by the ratio of isomers with temperature. The analysis procedure was established with the open and closed types of the expander cycle engine and the simulation methods were suggested for each component. To validation of the analysis program, we compared the performance of the engine operating point and the analysis results performed overseas for Vinci and SE-21D, which are expander cycle engines. As a result of the analysis, the main performance factors of the system, such as the mass flow of the propellant, specific thrust, and power, except for some of the inaccurate input information, showed high accuracy with an error of around 1-2%.

Numerical Study on the Effects of Gravity Direction and Hydrogen Filling Rate on BOG in the Liquefied Hydrogen Storage Tank (액체수소 저장 탱크의 중력 방향 및 수소 충전율이 BOG에 미치는 영향에 관한 수치적 연구)

  • YOUNG MIN SEO;HYUN WOO NOH;DONG WOO HA;TAE HYUNG KOO;ROCK KIL KO
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.4
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    • pp.342-349
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    • 2023
  • In this study, a numerical simulations were conducted to analyze the phase change behavior of a liquid hydrogen storage container. The effects of gravity direction and hydrogen filling rate on boil-off gas (BOG) in the storage container were investigated. The study employed the volume of fluid, which is the phase change analysis model provided by ANSYS Fluent (ANSYS, Canonsburg, PA, USA), to investigate the sloshing phenomenon inside the liquefied hydrogen fuel tank. Considering the transient analysis time, two-dimensional simulation were carried out to examine the characteristics of the flow and thermal fields. The results indicated that the thermal flow characteristics and BOG phenomena inside the two-dimensional liquefied hydrogen storage container were significantly influenced by changes in gravity direction and hydrogen filling rate.

Study on Properties of High Energetic and High Dense Cyclic Hydrocarbons by the Structure (고에너지 고밀도 고리탄화수소 화합물의 구조에 따른 물성 연구)

  • Cho, Joon-Hyun;Kwon, Tae-Soo;Jeong, Deok-Jin;Oh, Chang-Ho;Park, Dae-In;Han, Jeong-Sik
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.11a
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    • pp.463-466
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    • 2008
  • The weapon systems with a liquid propulsion engine have been used for various purposes and demands of the liquid fuel with variety of properties for its operational purposes and environment. The cyclic hydrocarbons including norbornane or dicyclopentane structures have many applications to the guided weapon systems due to the high density and high energy characteristics, also efforts have been given in many fields. In this study, the cyclic hydrocarbons that we designed and fabricated were investigated to obtain tendency on the structures.

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Development of Hexafluoropropylene Hydrogenation with Pd/C Particles Prepared with 1-Hexyl-3-methylimidazolium Tetrafluoroborate (1-Hexyl-3-methylimidazolium Tetrafluoroborate으로 제조된 팔라듐 탄소촉매를 이용한 Hexafluoropropylene 수소화 반응)

  • Jeong, Ji Baek;Yoo, Kye Sang
    • Applied Chemistry for Engineering
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    • v.24 no.4
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    • pp.412-415
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    • 2013
  • Palladium on carbon powder was prepared using 1-hexyl-3-methylimidazolium tetrafluoroborate, one of room temperature ionic liquids. The synthesized particles were tested as a hexafluoropropylene hydrogenation catalyst. Moreover, the hydrogenation was performed under various reaction conditions to develop an optimum reaction process. The catalyst prepared by more than 3 wt% of palladium and the unity mole ratio of ionic liquid to palladium precursor showed higher catalytic activity. For reaction conditions, the complete hexafluoropropylene (HFP) conversion was achieved at these conditions; the volume flow ratio of hydrogen to HFP was higher than 1.25 and $GHSV_{HFP}$ was lower than 50000 mL/g-h.

A Study of Construction of a Hydrogen Peroxide Supply System for Liquid Rocket Engine (액체로켓엔진 산화제로서의 과산화수소 공급계 구축에 관한 연구)

  • Jeon, Jun-Su;Lee, Yang-Suk;Kim, Young-Mun;Choi, Yu-Ri;Ko, Young-Sung;Kim, Yoo;Kim, Sun-Jin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.14 no.2
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    • pp.63-70
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    • 2010
  • A construction process of hydrogen peroxide supply system was investigated to use hydrogen peroxide as an oxidizer of bi-propellant liquid rocket engine. To use hydrogen peroxide as a rocket propellant, it has to be in high concentration over 90%. It is very important to make the supply system free of pollutants, because highly concentrated hydrogen peroxide has a characteristic of hypersensitive reaction to pollutants such as dust and oil sludge. We suggested the cleaning and passivation process of main components to minimize pollutants of the supply system. In conclusion, we verified stability of the constructed supply system by leak test and hot test.

오일확산 펌프를 이용한 10-9 Pa 영역의 초고진공 구현

  • Jo, Bok-Rae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.141.1-141.1
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    • 2014
  • 오일 증기의 제트를 분사하여 잔류가스를 배기하는 오일확산펌프는, 구조가 간단하여 고장이 적고 저렴하며 소음 및 전기노이즈가 적게 발생하는 많은 장점을 가지고 있다. 그러나 오일의 증기압에 의해 그 도달압력이 10-9 Torr 이상으로 제한되어, 액체질소로 냉각되는 배플형태의 저온 트랩을 사용하지 않는 한 10-10 Torr영역의 초고진공 배기용으로는 사용하지 못하는 것으로 알려져 있다. 유회전펌프로 뒷받침 배기(foreline pumping)하는 700l/s의 배기속도를 가진 오일확산펌프에 300 liter/sec의 컨덕턴스를 가진 액체질소 트랩을 부착하여 메탈 실링을 사용하는 초고진공 챔버를 배기하였다. 액체질소트랩에 액체질소를 투입하면 $1{\times}10-8Pa$이하의 초고진공이 얻어졌으나, 액체질소가 증발하여 트랩의 온도가 상온으로 상승하면 압력도 $1{\times}10-7Pa$ 이상으로 상승하였다. 50 liter/sec의 배기속도를 가진 터보분자펌프로 오일확산펌프를 뒷받침 배기하면 액체질소를 투입하지 않은 상태에서 $5{\times}10-9Pa$이하의 초고진공이 얻어졌으며, 액체질소를 투입하여도 압력은 거의 변화하지 않았다. 잔류가스분석장치로 얻은 잔류가스 성분 스펙트럼은 수소가 잔류가스의 대부분을 차지하는 것을 보여주었다.

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One-Dimensional Modeling of Hydrogen Generator (수소발생기의 일차원 모델링)

  • Park, Jae Hyun;Lee, Hyojin;Valderrama, Edgar Willy Rimarachin;Yim, Chungsik;Yang, Heesung
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.2
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    • pp.74-86
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    • 2018
  • This paper presents the one-dimensional model of a hydrogen generator, where the alkali solution was supplied from the top to the dry aluminum powders. Hydrogen was produced as the solution moved downward and reacted with aluminum. The species conservation equations were considered for the hydrogen gas and alkali solution, while the energy conservation equation was applied to the gas-liquid-solid mixture as a single medium. The gas rising velocity and liquid penetration velocity were also included in the theoretical approach. The developed code was validated with the experimental data of the hydrogen production amount and collector pressure. Additionally, the model successfully predicted the various reactor properties, such as the concentrations, volume fractions, and temperatures, and is expected to help significantly in the design of a novel hydrogen generator.

A Theoretical Study on Boil-off Gas Generated from Cooling Process for Cryogenic Components Using Liquid Hydrogen (액체 수소를 활용한 극저온 부품의 냉각 과정에서 발생하는 BOG에 관한 이론적 연구)

  • DONG WOO HA;HYUN WOO NOH;YOUNG MIN SEO;TAE HYUNG KOO;ROCK KIL KO
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.6
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    • pp.615-622
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    • 2023
  • In this study, the theoretical analysis focused on the quantity of liquid hydrogen required for cooling down to 20 K, as well as the generation of boil-off gas (BOG) from the cooling process of the cryogenic components. The study involved calculating the amount of liquid hydrogen needed to achieve the desired temperature for the cryogenic components and subsequently determining the resulting BOG production at various reference temperatures. It was shown that it was important to efficiently lower the temperature of cryogenic parts through preliminary cooling. As a result, the reference temperature and pressure had an influence on the BOG generation on the cooling of cryogenic components using liquid hydrogen.