• Journal of the Korean Chemical Society
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• v.29 no.5
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• pp.496-502
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• 1985

The solvent extraction and cleanup processes for the simultaneous gas-liquid cliromatographic determination of 16 kinds of organochlorine pesticide residues were investigated. The pesticides were extracted out from-various crops with the aqueous acetone solution acidified (pH < 1.5) by adding conc. $H_3PO_4$. Most of the pesticides were partitioned from the solution with petroleum ether. Evaporated the extracting solvent, the residues were dissolved in ethylether-petroleum ether (6 : 94) eluent and eluted through the Florisil column activated at 650$^{\circ}$C for 2.5hrs. The extraction efficiency was over 94% and impurities were effectively removed by the column chromatography.

• Fire Science and Engineering
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• v.31 no.6
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• pp.1-7
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• 2017

Currently, flammable liquids account for more than 87 wt% of the hazardous materials in circulation in Korea, and paint products are the most commonly used mixed hazardous materials. Therefore, one of the most urgent and important issues is that we have to secure the safety for manufacturing, storage and transport of paint products. In this study we investigated and analyzed the domestic hazardous materials safety management method, the international GHS test method and so forth. We tested risks for a variety of oil paints and found a relation between the results. Furthermore, the risk test method and criteria adapted for domestic situation was presented. Paints were classified as hazardous or non-hazardous according to the results of the flash point test, the amount of flammable liquid or the UN-combustion persistence test. It was revealed from the test results of 6 kind of oil-based paints using different resins that they were hazardous materials with very high risks and belonged to the Category 1 or the Category 2.

• Fire Science and Engineering
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• v.23 no.5
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• pp.9-16
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• 2009

Chemical products have had an favorable influence on our everyday life, and contributed very much to the development of human culture. According to the rapid change of industry and the development of scientific technique the using chemical products are increasing more and more. Chemical products can have any hazardous property such as flammability or explosiveness. There are occurring many accidents in the international trade due to the different classification and labelling of chemicals produced in various countries. The main purpose of this work is the development of global standard test methods for the chemicals, and the classification and labelling in building block approach by means of the basic technical data. Oxidizing solids, combustible solids, spontaneously combustible materials, water-prohibitive materials, flammable liquids, self-reactive materials and oxidizing liquids have been classification The first Experiment have tested Oxidizing solids of third five. The results have been classified according to the hazard material safety regulation and the UN regulation, and summarized in a data-base.

• Proceedings of the Korean Nuclear Society Conference
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• 1996.05b
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• pp.707-712
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• 1996

중대사고시 원자로 압력용기내 또는 원자로 공동(cavity) 내에서의 노심용융물은 주입되는 물로 인하여 물과 접촉하는 표면이 냉각되면서 피막층(crust)이 형성된다. 이러한 피막층의 형성은 노심용융물과 냉각수 사이의 열전달 현상에 영향을 미치며 중대사고 발생시 사고 진행에 중요한 역할을 한다. 본 연구에서는 이러한 용융물의 피막층 형성의 해석모델을 수립하기 위해 전이현상과 전도와 대류를 포함하는 2차원 열전달과 상변화를 수반하는 문제를 포함하는 운동량방정식과 에너지방정식을 2차원으로 구성하였으며 에너지방정식은 엔탈피의 함수로 나타내었다. 그리고 이러한 2차원 지배방정식을 해석하기 위해 유한차분법 및 SIMPIER 알고리즘을 이용하였다. 비교대상으로는 한국원자력연구소에서 수행한 냉각수의 비등과 기체주입 효과가 고려되지 않은 실험을 대상으로 하였다. 계산결과 용융물의 피막층은 파동(wave) 형태로 형성되었으며 일정시간이 경과하면 변화가 없는 안정한 상태가 되었다. 용융물 내에서의 온도분포는 액체상태일 경우에는 하부가열면과 상변화가 일어나는 경계면부근을 제외하고는 거의 일정한 온도분포를 나타내고 있으며 용융물이 고화된 피막층에서는 급격한 온도변화를 보여주고 있다.

• Korean Chemical Engineering Research
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• v.48 no.5
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• pp.621-626
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• 2010

In this study, imidazole-based ionic liquid on polystyrene was prepared and its catalytic performance in the cycloaddition of $CO_2$ with allyl glycidyl ether(AGE) to produce allyl glycidyl carbonate was investigated. The ionic liquid was generated on the polystyrene-based polymer through the immobilization of imidazole. The prepared catalyst was characterized using a number of instrumental analysis including EA, FT-IR, TGA and SEM. The immobilized ionic liquid showed very good catalytic activity for the cycloaddition of $CO_2$ with AGE, having 80% of AGE conversion with over 96% of the carbonate selectivity at $120^{\circ}C$ under 1.48 MPa $CO_2$ pressure. The immobilized ionic liquid can be used for the reaction up to four consecutive runs without significant loss of its catalytic activity.

• Journal of the Korean Society of Radiology
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• v.17 no.6
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• pp.827-833
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• 2023

CT(Computed Tomography) contrast agents are commonly used in general hospitals and university hospitals when taking radiographic examinations. The CT contrast medium contains a mixture of a substance called "Iodine", which absorbs radiation energy and makes it appear white in the CT image, further improving the image quality. In addition, the CT contrast agent, which moves like blood in the blood vessels, clearly differentiates it from muscle and water, so CT contrast agents are widely used in hospitals. These CT contrast agents absorb X-rays, but in order to absorb X-rays, they must have a high density or a high radiation absorption coefficient. Since the CT contrast agent is injected into the blood vessels, if the density is high, the blood vessels are strained and the patient is in shock. For this reason, it is necessary to match the density similar to that of water and always pay attention to side effects. In addition, the amount of CT contrast medium is adjusted according to the patient's body shape, and the remaining contrast medium is discarded. However, This study tried to find out the idea of recycling it as a radiation shielding material. Since the CT contrast medium has a high radiation absorption coefficient at a density similar to that of water, the amount to absorb radiation is adjusted, the amount of contrast medium and the amount of water are adjusted, and the amount of radiation absorbed is determined by mixing with water. In addition, a study was conducted to find out the result of the difference in radiation absorption in various ways by comparing the radiation quality coefficient and absorption coefficient with other substances or materials in an environmentally friendly method harmless to the human body by mixing CT contrast medium and water.

• Journal of the Korean Society of Propulsion Engineers
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• v.2 no.2
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• pp.83-87
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• 1998

To reduce the supersonic jet noise from the liquid rocket engine, water injetion silencers were designed and tested. Test variables were the mass flow rate of water jet, the length of primary pipe and the diameter of expansion pipe. Followings are the results of this study. 1. From the same mass flow rate of water, longer primary pipe was more effective to reduce the noise. 2. Noise level was significantly reduced with increasingly water flow rate. 3. The optimum water flow rate was 10～12 times of the propellant flow rate. 4. By installing expansion pipe, noise level was reduced approximately 30㏈ compared to without expansion pipe

• Journal of the Korean Electrochemical Society
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• v.18 no.2
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• pp.51-57
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• 2015

We report the effect of the impurities including water and bromide in the propylmethylpyrrolidinium bis(trifluoromethanesulfonyl)imide (PMPyr-TFSI) on the electrochemical performance of lithium ion batteries. The several kinds of PMPyr-TFSI electrolytes with different amount of impurities are applied as the electrolyte to the cell with the high potential electrode, $LiNi_{0.5}Mn_{1.5}O_4$ spinel. It is found that the impurities in the electrolytes cause the detrimental effect on the cell performance by tracing the cycleability, voltage profile and Coulombic efficiency. Especially, the polarization and Coulombic efficiency go to worse by both impurities of water and bromide, but the cycleability was not highly influenced by bromide impurity unlike the water impurity.

• Journal of the Korean Society of Food Science and Nutrition
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• v.44 no.2
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• pp.287-290
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• 2015

Antifungal activities of pomegranate were investigated. Seventy percent ethanol extracts of seeds, peels, and whole fruits of pomegranate showed similar antifungal activities against Candida albicans in liquid media, whereas extract of whole fruit showed relatively high antifungal activity in solid media. When 70% ethanol extracts were fractionated sequentially with chloroform and ethyl acetate, ethyl acetate fraction exhibited the highest anti-fungal activities against C. albicans. Ethyl acetate fractions of whole fruits and peel portions showed at least 36% and 25% growth against C. albicans, Candida glabrata, Candida tropicalis, and Candida lusitaniae in liquid media, respectively. These results indicate that pomegranate contains antifungal compounds soluble with organic solvents.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.08a
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• pp.171-171
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• 2011

헬륨냉동계통은 연구용 원자로인 하나로에서 냉중성자를 생산할 수 있도록 설치된 수조내기기 내의 감속재인 수소가 정상적으로 열 사이펀을 유지하기 위한 주요 계통이다. 헬륨냉동계통은 헬륨가스를 압축하는 헬륨 압축부분과 헬륨가스를 팽창시켜 저온을 생성시키는 헬륨 팽창부분으로 나누어진다. 헬륨 압축부분은 두 개의 스크류가 맞물려 회전하면서 약 1.05 bar(a)의 헬륨가스를 최대 13 bar(a)까지 압축시키는 압축기가 있으며, 헬륨 팽창부분인 냉동박스의 팽창 터빈은 self-acting gas bearing에 의해 구동되며, 저온모드 운전 시작시 헬륨 압축부분에서 일부의 가스는 팽창 터빈 축(shaft)으로 유입되어 회전속도가 서서히 증가하면서 고속으로 회전하여 극저온의 헬륨가스(14~18 K)를 생성하는 주요 기기이다. 헬륨을 팽창하는 부분인 냉동박스 내로 헬륨 압축가스를 유입하기 전에 압축된 헬륨가스 내 불순물의 순도를 분석하여 냉동박스의 주요 부품인 팽창터빈의 운전에 영향을 미치지 않는 것이 가장 중요하다. 따라서 헬륨 저압측에 헬륨가스 내 불순물 즉, 수소($H_2$), 수분($H_2O$), 질소($N_2$), 탄화수소류(CxHy) 및 오일(Oilaerosol) 등의 함량을 분석하기위해 가스 분석기가 설치되어 있으며, 냉동박스 내로 유입되기 전에 헬륨압축에서 순환되는 가스 내 불순물인 수분, 질소, 탄화수소류 및 오일은 10 vpm 이하이어야 하며, 수소 함량은 0.1 % 이내이어야 한다. 헬륨 압축부분에서 순환되는 가스의 불순물이 요구 조건에 만족하도록 헬륨 고압측과 헬륨 저압측에 cryogenic adsorber를 설치하여 가스 내 불순물을 제거하는 가스순도제어 작업을 수행해야 한다. cryogenic adsorber를 사용하기 위해서는 장치 내의 불순 가스를 공정진공도(1.33 X $10^{-3}$ mbar) 이하로 진공배기하는 작업이 매우 중요하다. 이는 계통의 헬륨가스가 오염되지 않도록 하는 것으로 cryogenic adsorber 내에는 액체질소를 충전하여 액체질소 온도에 노출된 활성탄층을 헬륨가스가 흐르면서 수분, 질소, 탄화수소류 및 오일 등이 제거된다. 이 논문에서는 헬륨냉동계통의 가스 순도 제어 작업을 통해 헬륨가스의 순도가 요구조건 이하로 만족하며, 팽창 터빈의 운전에 영향을 미치지 않음을 기술하고자 한다.