• Transactions of the Korean Society of Automotive Engineers
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• v.12 no.6
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• pp.119-126
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• 2004

In order to elucidate the modes of double-droplet combustion speed in premixed spray flame, the difference between flame propagation speed and droplet cluster disappearance speed are experimentally investigated using a premixed spray burner system, It was confirmed that flame speed concerned with premixed-mode combustion in the spray flame was approximately 2.0 m/s in average while mean disappearance speed of droplet clusters, which were dominated by diffusion-mode combustion in downstream of the flame, was evaluated as much as 0.45 m/s. It was clarified that both characteristics of premixed-mode and diffusion-mode combustion in spray flames are of much difference in nature, even though both speed, which are supposed to depend on local properties of the spray itself and flow conditions surrounding droplet clusters, are scattered in experiments.

• Korean Chemical Engineering Research
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• v.45 no.6
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• pp.611-618
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• 2007

We demonstrate the sol-gel coating technique of colloidal clusters for producing hollow micro-particles with complex morphologies. Cross-linked amidine polystyrene (PS) microspheres were synthesized by emulsifier-free emulsion copolymerization of styrene and divinylbenzene. The amidine PS particles were self-organized inside toluene-in-water emulsion droplets to produce large quantities of colloidally stable clusters. These clusters were coated with thin silica shell by sol-gel reaction of tetraethylorthosilicate (TEOS) and ammonia, and the organic polystyrene cores were removed by calcination at high temperature to generate nonspherical hollow micro-particles with complex morphologies. This process can be used to prepare hollow particles with shapes such as doublets, tetrahedra, icosahedra, and others.