• Title/Summary/Keyword: 액상법

Search Result 437, Processing Time 0.03 seconds

Infrared Absorption and Reflection Properties of Silver Nanoparticles Synthesized by Liquid Reduction Method (액상환원법을 이용하여 합성된 은 나노입자의 적외선 흡수 및 반사 특성)

  • Hong, Min Ji;Park, Min Ji;Kim, Jong Hwa;Rokade, Ashish A.;Jin, Young Eup;Lee, Gun-Dae;Park, Seong Soo
    • Applied Chemistry for Engineering
    • /
    • v.28 no.5
    • /
    • pp.587-592
    • /
    • 2017
  • Uniform and optimum sized silver nanoplates were synthesized through the liquid phase reduction method by using silver nitrate solution as a starting chemical, dimethylformmide (DMF) as a reducing solvent, and polyvinylpyrrolidone (PVP) as reducing and surfactant agents. Synthesized and also film samples were characterized by using SEM, TEM, UV-Vis-NIR spectroscopy, particle size analyzer (PSA), and XRD. Triangle nanoplates with the size of 100~200 nm were found from the sample synthesized at $70^{\circ}C$ for 72 h using silver nitrate, DMF and 26 wt% PVP. The sample could reflect near-infrared light because it showed the maximum absorbing peak at about 1,000 nm. When the content or particle size of silver nanoplates increased in coating solutions, the transmittance decreased and the reflectance increased in film samples.

Numerical Analysis of Cold Storage System with Array of Solid-Liquid Phase Change Module (저온의 고-액상변화 모듈 용기의 배열에 따른 축냉시스템의 수치해석)

  • Mun, Soo-Beom
    • Journal of the Korean Society of Marine Environment & Safety
    • /
    • v.21 no.5
    • /
    • pp.577-582
    • /
    • 2015
  • This paper is the fundamental study for the application of cold storage system to the transportation equipment by sea and land. This numerical study presents the solid-liquid phase change phenomenon of calcium chloride solution of 30wt %. The governing equations are 1-dimensional unsteady state heat transfer equations of $1^{st}$ order partial differential equations. This type of latent heat storage material is often usable in fishery vessel for controlling the temperature of container with constant condition. The governing equation was discretized with finite difference method and the program was composed with Mathcad program. The main parameters of this solution were the initial temperature of heat storage material, ambient temperature of cold air and the velocity of cold air. The data of boundary layer thickness becomes thin with the increasing of cold air flowing velocity and also the heat storage completion time become shorten.

Effects of Applying Cattle Slurry and Mixed Sowing with Legumes on Productivity, Feed Values and Organic Stock Carrying Capacity of Whole Crop Barley and Rye (액상우분뇨 시용과 콩과작물의 혼파가 청보리와 호밀의 생산성, 사료가치 및 단위면적당 유기가축 사육능력에 미치는 영향)

  • Jo, Ik-Hwan;HwangBo, Soon;Lee, Sung-Hoon
    • Korean Journal of Organic Agriculture
    • /
    • v.18 no.3
    • /
    • pp.419-432
    • /
    • 2010
  • This study was conducted to determine effects of applying cattle slurry and mixed sowing with legumes such as hairy vetch or forage pea on productivity, feed values and organic stock carrying capacity of whole crop barley and rye as winter forage crops, and to obtain organic forages together with higher soil fertility. Experimental plots consisted of 7 treatments, which were non-fertilizer, chemical fertilizer (containing phosphate and potassium: P+K), chemical fertilizer (containing nitrogen, phosphate and potassium: N+P+K), organic fertilizer, cattle slurry, cattle slurry application (mixture with hairy vetch), and cattle slurry application (mixture with forage pea) plots. Each treatment was triplicates, and seven treatments were allocated in a completely randomized block design. For whole crop barley or its mixture crops, annual dry matter (DM), crude protein (CP), and total digestible nutrients (TDN) yields of N+P+K plots were significantly (P<0.05) higher than other plots except for cattle slurry plots. The CP content of barley or its mixture crops was significantly higher tor N+P+K plot (9.8%) and mixture plots with legumes (8.6~9.7%) than those of other treatments. As 450 kg Hanwoo heifers were fed diets included 70% whole crop barley or 70% mixture crops with legumes, mixture plots are capable of raising average 1.7 to 1.8 heads/ha a year. For rye or its mixture crops, annual DM, CP, and TDN yields represented 6.9~7.1, 0.5~0.6 and 4.3~4.4 ton/ha, respectively. The N+P+K plot contained 10.8% CP, which was higher (P<0.05) than all other treatments. In case of 450 kg Hanwoo heifers fed diets included 70% rye or 70% mixture crops with legumes, mixture plots can rear average 1.9 heads/ha a year. When it was considered based on crop yields and organic stock carrying capacity, applying cattle slurry to whole crop barley or rye had the comparable yields and feed values to chemical fertilizer application. Moreover, whole crop barley and rye within cattle slurry plots had a greater combination with hairy vetch and forage pea, respectively, and their mixture crops with legumes had higher crude protein and TDN yields within cattle slurry plots. In conclusion, it would be expected that mixed sowing with legumes in the application of cattle slurry to grass crops could be substituted for imported organic grains as dietary protein sources in feeding organic livestock.

Evaluation of Carrying Capacity for Hanwoo Heifers When Fed Whole Crop Barley and Rye as Influenced by Organic Fertilizer Application and Mixed Sowing with Legumes (유기질비료 시용과 두과 사료작물의 혼파에 따른 청보리와 호밀의 생산성과 단위면적당 한우 사육능력 추정)

  • Jo, Ik-Hwan
    • Journal of The Korean Society of Grassland and Forage Science
    • /
    • v.32 no.2
    • /
    • pp.117-124
    • /
    • 2012
  • This study was conducted to estimate Hanwoo carrying capacity when whole crop barley or rye as winter forage crops was grown on different applying sources (chemical fertilizer, cattle or organic fertilizer) and mixed sowing combination with hairy vetch or forage pea during the period of 2008~2010. The experimental plots within whole crop barley or rye were consisted of 7 treatments, which were non-fertilizer, chemical fertilizer (P+K), chemical fertilizer (N+P+K), organic fertilizer, cattle slurry, cattle slurry with hairy vetch, and cattle slurry with forage pea. Each plot was triplicates and experimental treatments were allocated in the randomized complete block design. For whole crop barley, annual mean dry matter (DM) and total digestible nutrients (TDN) yields were the highest in N+P+K plots, but there were no significant differences among organic fertilizer, cattle slurry and mixed sowing with legumes. The TDN and RFV were the highest in mixed sowing plots of forage pea plus cattle slurry application. As 450 kg Hanwoo heifers were fed diets included 70% whole crop barley, organic fertilizer, cattle slurry application and mixed sowing with legumes plots is capable of raising average 2.5 to 2.9 heads/ha a year. For whole crop rye, annual DM, crude protein, and TDN yields of application groups and mixed sowing treatment with legumes showed 6.69~7.13, 0.46~0.51 and 3.95~4.18 ton/ha, respectively. In case of 450 kg Hanwoo heifers fed diets included 70% forage rye, it is estimated that cattle slurry application (mixed sowing with legumes) plots can rear average 3.1~3.3 heads/ha a year. It can be concluded that, on the basis of DM yield, not only mixed sowing with legumes by applying cattle slurry rather than single sowing of whole crop barley or whole crop rye enhanced production yield and feed values, but also it could be a substitute for imported grains as dietary protein sources in the case of feeding Hanwoo.

Characteristics of Wakes in a Viscous Liquid Medium of a Simulated GTL Process (모사된 GTL공정의 점성액체 매체에서 wake의 특성)

  • Lim, Dae Ho;Jang, Ji Hwa;Kang, Yong;Jun, Ki Won
    • Korean Chemical Engineering Research
    • /
    • v.49 no.5
    • /
    • pp.571-576
    • /
    • 2011
  • Characteristics of bubble driven wakes were investigated in a simulated GTL process(0.102 m ${\times}$ 1.5 m in height) with viscous liquid medium. Effects of gas velocity(0.04 ~ 0.12 m/s) and liquid viscosity(0.001 ~ 0.050 $Pa{\cdot}s$) on the wake characteristics such as rising velocity, frequency, size and holdup were determined by employing a resistivity probe method. The wake phase formed behind the rising multi-bubbles as well as single bubbles were detected effectively from the conductivity fluctuations measured by the probe. Compressed, filtered and regulated air and aqueous solutions of Carboxy Methyl Cellulose(CMC) were used as a dispersed gas phase and a continuous liquid medium, respectively. It was found that the rising velocity and size of wake phase increased with an increase in gas velocity or liquid viscosity. The holdup and frequency of wake phase increased with increasing gas velocity due to the increase of gas input into the process with increasing gas velocity. However, the values of holdup and frequency of wake phase decreased with increasing liquid viscosity, since the size of bubbles and thus that of wakes increased with increasing liquid viscosity. The ratio of wake holdup to that of gas phase, which was in the range of 0.25 ~ 0.48, increased with an increase in liquid viscosity but decreased with gas velocity. The wake characteristics were well correlated in terms of operating variables within this experimental conditions.

Simulation of Solitary Wave-Induced Dynamic Responses of Soil Foundation Around Vertical Revetment (고립파 작용하 직립호안 주변에서 지반의 동적응답에 관한 수치시뮬레이션)

  • Lee, Kwang-Ho;Yuk, Seung-Min;Kim, Do-Sam;Kim, Tae-Hyeong;Lee, Yoon-Doo
    • Journal of Korean Society of Coastal and Ocean Engineers
    • /
    • v.26 no.6
    • /
    • pp.367-380
    • /
    • 2014
  • Tsunami take away life, wash houses away and bring devastation to social infrastructures such as breakwaters, bridges and ports. The targeted coastal structure object in this study can be damaged mainly by the tsunami force together with foundation ground failure due to scouring and liquefaction. The increase of excess pore water pressure composed of oscillatory and residual components may reduce effective stress and, consequently, the seabed may liquefy. If liquefaction occurs in the seabed, the structure may sink, overturn, and eventually increase the failure potential. In this study, the solitary wave was generated using 2D-NIT(Two-Dimensional Numerical Irregular wave Tank) model, and the dynamic wave pressure acting on the seabed and the estimated surface boundary of the vertical revetment. Simulation results were used as an input data in a finite element computer program(FLIP) for elasto-plastic seabed response. The time and spatial variations in excess pore water pressure, effective stress, seabed deformation, structure displacement and liquefaction potential in the seabed were estimated. From the results of the analysis, the stability of the vertical revetment was evaluated.

Bore-induced Dynamic Responses of Revetment and Soil Foundation (단파작용에 따른 호안과 지반의 동적응답 해석)

  • Lee, Kwang-Ho;Yuk, Seung-Min;Kim, Do-Sam;Kim, Tae-Hyeong;Lee, Yoon-Doo
    • Journal of Korean Society of Coastal and Ocean Engineers
    • /
    • v.27 no.1
    • /
    • pp.63-77
    • /
    • 2015
  • Tsunami take away life, wash houses away and bring devastation to social infrastructures such as breakwaters, bridges and ports. The coastal structure targeted object in this study can be damaged mainly by the wave pressure together with foundation ground failure due to scouring and liquefaction. The increase of excess pore water pressure composed of oscillatory and residual components may reduce effective stress and, consequently, the seabed may liquefy. If liquefaction occurs in the seabed, the structure may sink, overturn, and eventually increase the failure potential. In this study, the bore was generated using the water level difference, its propagation and interaction with a vertical revetment analyzed by applying 2D-NIT(Two-Dimensional Numerical Irregular wave Tank) model, and the dynamic wave pressure acting on the seabed and the surface boundary of the vertical revetment estimated by this model. Simulation results were used as input data in a finite element computer program(FLIP) for elasto-plastic seabed response. The time and spatial variations in excess pore water pressure ratio, effective stress path, seabed deformation, structure displacement and liquefaction potential in the seabed were estimated. From the results of the analysis, the stability of the vertical revetment was evaluated.

Comparative Bioreactor Studies in Terms of Oxygen Transfer between Suspended and Immobilized Fungal Systems for Cyclosporin A Fermentation (Cyclosporin A 생산을 위한 액체배양과 고정화배양의 생물반응기에서의 산소전달 비교 연구)

  • 전계택
    • KSBB Journal
    • /
    • v.9 no.2
    • /
    • pp.211-223
    • /
    • 1994
  • In fermentations with a 4-liter stirred tank bioreactor, a better than two-fold enhancement of the gas-liquid mass transfer coefficient$(k_La)$ in the celite-immobilized fungal cultures of Tolypocladium in flatum over the parallel conventional free-cell was observed at identical biomass concentrations, despite the higher specific oxygen uptake rate of the immobilized fungi during exponential growth. As a result oxygen sufficient conditions, i. e., dissolve oxygen(D.O.) concentrations exceeding 75% air saturation, could be maintained throughout exponential growth period of the immobilized culture, in contrast to the suspended fungal culture, whose D.O. levels fell below 50% air saturation. A linear monotonic dependence of $k_La$ upon impeller agitaion rate was found for both immobilized and conventional cultivation modes over a range of 250 to 550rpm, the slope being a function of biomass concentration for the free but not for the immobilized cell system In contrasts oxygen transfer rate was a much weaker function of aeration rate up to about 2.5 vvm for both culture configurations. Above this level, aeration rate had no further effect on the mass transfer. In addition, the immobilized cultures sustained good morphological and physiological states, leading to almost two times higher cyclosporln A (CyA) productivity overt the parallel free cell system. These experiments suggest that the celite-immobilized fungal system in a stirred tank reactor has considerable promise for scaling up cyclosporin A production in terms of high-density cultivation.

  • PDF

Irregular Waves-Induced Seabed Dynamic Responses around Submerged Breakwater (불규칙파동장하 잠제 주변지반의 동적거동에 관한 수치해석)

  • Lee, Kwang-Ho;Ryu, Heung-Won;Kim, Dong-Wook;Kim, Do-Sam;Kim, Tae-Hyung
    • Journal of Korean Society of Coastal and Ocean Engineers
    • /
    • v.28 no.4
    • /
    • pp.177-190
    • /
    • 2016
  • In case of the seabed around and under gravity structures such as submerged breakwater is exposed to a large wave action long period, the excess pore pressure will be generated significantly due to pore volume change associated with rearrangement soil grains. This effect will lead a seabed liquefaction around and under structures as a result from decrease in the effective stress. Under the seabed liquefaction occurred and developed, the possibility of structure failure will be increased eventually. Lee et al.(2016) studied for regular waves, and this study considered for irregular waves with the same numerical analysis method used for regular waves. Under the condition of the irregular wave field, the time and spatial series of the deformation of submerged breakwater, the pore water pressure (oscillatory and residual components) and pore water pressure ratio in the seabed were estimated and their results were compared with those of the regular wave field to evaluate the liquefaction potential on the seabed quantitatively. Although present results are based on a limited number of numerical simulations, one of the study's most important findings is that a more safe design can be obtainable when analyzing case with a regular wave condition corresponding to a significant wave of irregular wave.

Improved single crystal growth methods for oxide materials by MBE, LPE and $\mu$ - PD techniques (MBE, LPE와 $\mu$ - PD 기술에 의한 산화물재료의 개선된 단결정 성장방법)

  • ;Masahito Yoshizawa
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.5 no.4
    • /
    • pp.378-385
    • /
    • 1995
  • The growth processes of improved methods for MBE, LPE and $\mu$ - PD methods are discussed taking the oxide materials, especially those of Bi - Sr - Ca - Cu family $LiNbO_3$ and $K_3Li_2Nb_5O_{15}$ family as examples. It is suggested that the crystal growth far from equilibr iu m including composition homogeneity has been achieved to satisfy in understanding and controlling the atomic interfaces.

  • PDF