• Title/Summary/Keyword: 암모니아 제어

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일체형원자로 SMART의 수화학 설계 특성

  • 최병선;김주평;조봉현;이영진;이두정
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05a
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    • pp.411-416
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    • 1998
  • 출력운전 동안 원자로 냉각재의 정화 없이 운전하는 SMART원자로의 수화학 설계 요건을 정립하기 위하여 핵연료 피복관 및 계통재질의 부식을 최소화하고 부식 생성물의 방사화에 의한 방사선 준위의 상승을 억제하기 위한 수화학 운전 변수에 대한 정성적인 분석을 시도하였다. 원자로냉각재 의 pH 제어 계통을 구성하는 재질의 부식에 따른 건전성, 부식생성물의 거동 및 원자로 냉각재의 방사선 준위 측면에서 수화학 설계 요건이 적절한지의 여부를 살펴보았다 분석 결과, 원자로냉각재의 pH 제어는 암모니아를 이용하므로 높은 pH(= 9.5∼10.6)에서 운전이 가능하며, 계통재질의 부식을 최소화하며 방사선 준위의 상승을 억제할 수 있었다. 또한 SMART 증기발생기 튜브에 사용된 titanium 합금은 주어진 운전 조건하에서 Inconel-600보다 내 부식성이 매우(약 12 배) 우수하였다.

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Effects of Enzyme Complex on Odor Emission from Swine Slurry and Swine Buildings (효소복합체가 양돈슬러리 및 돈사 악취발생에 미치는 영향)

  • Jung, K.H.;Han, J.C.;Kwack, S.J.;Jung, J.D.;Lee, J.W.;Kim, D.H.
    • Journal of Animal Environmental Science
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    • v.14 no.1
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    • pp.15-22
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    • 2008
  • This study was carried out to investigate the effect of enzyme complex on odor emission from swine slurry and the process of making swine liquid manure. Ammonia and hydrogen sulfide concentrations were significantly decreased by using the enzyme complex of liter per ton level of liquid swine slurry in the manure storage tank according to the time. Characteristics of liquid swine slurry were affected by the enzyme complex, total nitrogen and ammonia nitrogen contents were reduced compare with control. Ammonia and hydrogen sulfide concentrations in the finishing pig building and offensive odor compound on the boundary line of swine farm were significantly decreased by spraying in swine finishing building. In conclusion, the results obtained from this study suggest that using the enzyme complex of liter per ton level of liquid swine slurry for making liquid swine manure may improve the quality of swine liquid fertilizer and reduce odor emission. Also farm scale enzyme complex treatment may improve air quality in finishing pig building and deduce offensive odor compound of swine farm.

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The Numerical Study on the Flow Control of Ammonia Injection According to the Inlet NOx Distribution in the DeNOx Facilities (탈질설비 내에서 입구유동 NOx 분포에 따른 AIG유동제어의 전산해석적 연구)

  • Seo, Deok-Cheol;Kim, Min-Kyu;Chung, Hee-Taeg
    • Clean Technology
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    • v.25 no.4
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    • pp.324-330
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    • 2019
  • The selective catalytic reduction system is a highly effective technique for the denitrification of the flue gases emitted from the industrial facilities. The distribution of mixing ratio between ammonia and nitrogen oxide at the inlet of the catalyst layers is important to the efficiency of the de-NOx process. In this study, computational analysis tools have been applied to improve the uniformity of NH3/NO molar ratio by controlling the flow rate of the ammonia injection nozzles according to the distribution pattern of the nitrogen oxide in the inlet flue gas. The root mean square of NH3/NO molar ratio was chosen as the optimization parameter while the design of experiment was used as the base of the optimization algorithm. As the inlet conditions, four (4) types of flow pattern were simulated; i.e. uniform, parabolic, upper-skewed, and random. The flow rate of the eight nozzles installed in the ammonia injection grid was adjusted to the inlet conditions. In order to solve the two-dimensional, steady, incompressible, and viscous flow fields, the commercial software ANSYS-FLUENT was used with the k-𝜖 turbulence model. The results showed that the improvement of the uniformity ranged between 9.58% and 80.0% according to the inlet flow pattern of the flue gas.

Ammonia flow control for NOx reduction in SCR system of refuse incineration plant (소각로의 NOx 제어용 SCR 시스템의 암모니아 공급량제어)

  • Kim, In-Gyu;Yeo, Tae-Gyeong;Kim, Hwan-Seong;Kim, Sang-Bong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.22 no.2
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    • pp.451-457
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    • 1998
  • This paper describes a modelling method for SCR(selective catalystic reduction) system in refuse incineration plant. We consider the SCR system as a single input and single output system. For modelling the SCR system, an auto regressive exogeneous(ARX) modelling method is used. In this case, we should design the white noise input for modelling and put it on the system as an input$(NH_3)$, and take an outlet NOx as an output. From these two relations, we design the ARX model with 45 second delay time and transform to a discrete system with sampling time of 0.5 second. Using the obtained SCR model, we verify that the outlet NOx is deeply related with stoker`s moving in boiler of refuse incineration plant.

Design of Environment Control and Automated Management Systems for Animal Production : A Review (축산을 위한 환경제어 및 자동화 사양관리 시스템 설계에 관한 문헌연구)

  • Chang, Dong-Il;Kim, Soung-Rai;Chang, Hong-Hee
    • Korean Journal of Agricultural Science
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    • v.22 no.1
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    • pp.24-41
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    • 1995
  • The objective of this study were to review and analyze the application technologies of electronics and microprocessor for environment control and automated management systems of livestock production of the advanced countries, and to select the appropriate and applicable technologies for our systems among the analyzed. In this study, the environment control systems were analyzed mainly on the poultry production systems; and the automated management systems on swine and dairy production systems. According to the results, the advanced technologies reviewed and analyzed could be applicable for designing our animal production systems, if those were modified and remodeled for our situation.

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Evaluation of Odor Reduction in the Enclosed Pig Building Through Spraying Biological Additives (생물학적 첨가제 살포에 의한 밀폐형 돈사에서의 악취 저감 평가)

  • 김기연;최홍림;고한종;이용기;김치년
    • Journal of Animal Science and Technology
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    • v.48 no.3
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    • pp.467-478
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    • 2006
  • Maintenance of an optimal air quality in the enclosed pig building is potentially important in terms of pig performance and farmer health. The objective of this on-site experiment is to evaluate and compare efficiencies of currently utilized biological additives to reduce odor emissions from the enclosed pig building. As a result, generally all the additives except for salt water, artificial spice and essential oil were proved ineffective in reducing odor generation. The beneficial effects of salt water, artificial spice and essential oil on odor reduction were highlighted on ammonia, odor intensity and offensiveness, and sulfuric odorous compounds, respectively. To efficiently utilize odor masking agent such as the artificial spice, ventilation rate should keep slightly lower than the optimal level. Essential oil functioned well as not only masking agent but also antimicrobial agent for reducing odor. To precisely quantify odor concentration, it should be measured by not the odor sensor but the olfactometry technique.

Steady & Pulse Mode Fire Tests of Hydrazine Thrusters (단일 하이드라진 추력기 연소시험 성능평가)

  • 이성택;이상희;최영종;류정호
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 1998.04a
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    • pp.31-31
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    • 1998
  • 위성체의 보조추진시스템은 임구궤도까지의 궤도진입 및 임무궤도상에서의 속도 또는 자세제어에 필요한 임펄스를 제공한다. 단일하이드라진 추력기는 하이드라진(H$_2$H$_4$)과 자발적 촉매(Shell 405)의 발열 및 흡열 열분해 반응에 의해 발생하는 질소($N_2$), 수소(H$_2$), 암모니아(NH$_3$), 혼합가스를 노즐을 통해 방출하므로써 요구되는 impulse를 얻는다. 단일하이드라진 추력기 설계는 주입기, 촉매대, 노즐과 기타 설계 형태에 따른 다지관, 링, 스크린, 지지판 등의 부수적인 부품으로 구성된다. 추력기 제작 과정은 크게 piece-parts 기계가공, HEA(Head End Assembly)와 TCA(Thrust Chamber Assembly)로 구성되고 각 세부공정마다 전수시험 및 검사를 가진다. 연소시험설비는 최소 모사진 공 수준이 고도 100,000 ft(8.4 torr)를 만족시킬 수 있는 진공설비, 시험제어부, 성능변수 측정 및 처리부, 추진제 가압 공급부, 기타 환경 안전 및 부대 설비로 구성된다. 추력기 연소성능시험 절차는 추진제 충전 및 오염 여부 표본 검사, 가압 및 공급 라인 이상여부 확인, 추력기 장착, 추진제 가압 및 공급, 시험장치 보정, 진공 모사 및 연소성능시험, data 처리 등으로 구성된다.

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Control of Wastewater Treatment Removing Phosphate Based on ASM No. 2 Simplified Model and Investigation of Luxury Uptake Limitation (ASM No. 2 간략화 모델에 기초한 인산염의 제어 및 인섭취 제한현상에 대한 고찰)

  • Kim, Shin-Geol;Choi, In-Su;Koo, Ja-Yong
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.2
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    • pp.181-189
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    • 2008
  • Phosphate is the limiting factor leading to the eutrophication in nature and has been usually removed by the luxury uptake of PAOs(Phosphate accumulating organisms). The purpose of this study was the control of wastewater treatment removing phosphorus. The control of wastewater treatment process was performed by optimal and adaptive control. They were performed as followings. Firstly the inflow phosphate concentration was measured and the optimal aeration time was calculated by simplified ASM No. 2 for the phosphate to be 1.0 mg/L in effluent. It was optimal control. But when the phosphate concentration in effluent was not 1.0 mg/L, adaptive control was necessary to coincide the objective of control with real value. Then it was performed as the objective phosphate concentration in effluent was changed according to calculation of errors and it was adaptive control. The wastewater treatment process had been controlled by them for about one month. The range of phosphate concentration in effluent 0.2$\sim$3.2 mg/L and the average of it was 1.0 mg/L. The limitation of luxury uptake occurred two times while wastewater treatment process was running. After the analysis of laboratory tests, we knew the reasons were the shortage of ammonia nitrogen and the excessive aeration.

GSMBE 방법으로 Si(110) 기판 위에 성장된 GaN 박막의 미세구조 연구

  • Lee, Jong-Hun;Kim, Yeong-Heon;An, Sang-Jeong;No, Yeong-Gyun;O, Jae-Eung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.193.1-193.1
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    • 2015
  • 실리콘 (Si) 기판 위에 고품질의 갈륨질화물 (GaN) 박막을 성장시키기 위한 노력이 계속되고 있다. 실리콘 기판은 사파이어 기판 보다 경제적인 측면에서 유리하고, 실리콘 직접화 공정에 GaN 소자를 쉽게 접목 가능하다는 장점이 있다. GaN 박막은 2차원 전자 가스형성을 통한 고속소자, 직접 천이형 밴드갭을 이용한 발광소자 및 고전압 소자로써 활용 가능한 물질이다. 종래에는 Si(100) 및 Si(111) 기판 위에 GaN 박막 성장에 대한 연구가 주로 진행되었다. 하지만 대칭성과 격자 불일치도 등 결정학적 특성을 고려할 때 Si(100) 기판 위에 고품질의 GaN 박막을 성장시키는 것은 쉽지 않다. Si(111) 기판은 실리콘 소자 직접화 공정에 적합하지 못한 단점을 가지고 있다. 반면, 최근 Si(110) 기판 위에서 비등방적 변형 제어를 통한 고품질 GaN 박막 성장이 보고 되어 실리콘 집적 소자와 결합한 고전압 소자 및 고속소자 구현에 관한 연구가 진행되고 있다. 본 연구에서는 투과전자현미경 연구를 바탕으로 Si(110) 기판 위에 성장된 GaN의 미세구조에 관한 연구를 소개한다. 열팽창계수의 차이에 의한 GaN 박막 내 결함 생성을 줄이기 위하여 AlN 완충층이 사용되었다. GaN 박막을 암모니아 ($NH_3$) 유량이 다른 조건에서 성장시킴으로써 GaN 박막 미세구조의 암모니아 유량 의존성에 관한 연구를 진행하였다. GaN 박막에서 투과전자현미경 연구와 X-ray 회절 연구를 통하여 결함 거동 및 결정성을 확인하였다. $NH_3$ 유랑이 증가함에 따라 GaN의 성장 거동이 3차원에서 2차원으로 변화됨을 관찰하였다. 또한, 전위밀도의 증가도 확인되었다. $NH_3$ 유량이 낮은 경우 GaN 전위는 AlN와 GaN 경계에 주로 위치하고 GaN 표면 근처에는 전위밀도가 감소하였으나, $NH_3$ 유량이 높을 경우 GaN 박막 표면까지 전위가 관통됨을 확인하였다.

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Study on Environmental Factors for Movable Cultural Properties in Museum (박물관 환경 분석을 통한 동산문화재 영향인자에 대한 연구)

  • Kim, Il-Kyu;Seo, Yong-Soo;Lee, Ju-Hyun
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.9
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    • pp.811-816
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    • 2009
  • Along with research into the latest preservation treatments for items of cultural heritage, studies of the preservation environment and the effect of damage are also increasing. This study conducted comprehensive research into the temperature, humidity, acids, ammonia, reduced sulfur compounds, aldehydes with various ingredients in the exhibition hall, show case, and storage of three type museum. As a result, temperature, humidity, TVOCs, acetaldehyde frequently exceeded the domestic and international standards for a museum preservation environment and indoor air quality. Also, formaldehyde, chloride, and ammonia exceeded the standards intermittently. Temperature, humidity, TVOCs, acetaldehyde were evaluated to be the major influential factors. In order to control the major factors, apart from temperature and humidity, that cause damage in the museum environment, it is deemed necessary to complement this system with an effective air filter or remover.