• Title/Summary/Keyword: 암모니아/물

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Fabrication and Characteristics of ZnO-based thin film sensors with high selectivity for TMA gas (TMA 가스 선택성 향상을 위한 ZnO계 박막센서의 제작 및 특성)

  • Park, Sung-Hyun;Choi, Woo-Chang;Kim, Sung-Woo;Ryu, Jee-Youl;Choi, Hyek-Hwan;Lee, Myong-Kyo;Kwon, Tae-Ha
    • Journal of Sensor Science and Technology
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    • v.9 no.1
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    • pp.36-43
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    • 2000
  • In oder to enhance the selectivity of TMA(trimethylamine) gas, the ZnO-based films which were doped with $Al_2O_3$, $TiO_2, $In_2O_3$ and $V_2O_5$ catalysts with various weight percents were deposited in oxygen by RF magnetron sputtering method. To improve electrical stability of sensors, the ZnO-based films were annealed in oxygen at $700^{\circ}C$ for 1 hour. The TMA selectivity of sensors was defined by the magnitude($S_{TMA}/S_{DMA}$ and $S_{TMA}/S_{NH3}$) of TMA sensitivity relative to DMA and sensitivity ammonia($NH_3$) sensitivity, respectively. The $ZnO+Al_2O_3(4\;wt.%)+TiO_2(1\;wt.%)+In_2O_3(1\;wt.%)$ sensor showed high $S_{TMA}/S_{DMA}$ of 5.9 and $S_{TMA}/S_{NH3}$ of 26 to 160 ppm at the working temperature of $300^{\circ}C$ respectively.

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The Ammonia Removal Capacity of a Few Kinds of Filter Media in a Water Reuse quaculture System (순환 여과식 양식 시설에 이용될 수종의 여과 재료의 효능에 관한 연구)

  • KIM In-Bae;KIM Pyong-Kih;CHEE Young-Ok
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.20 no.6
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    • pp.561-567
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    • 1987
  • The purpose of this study was to find out the removal capacity of harmful ammonia by different filter media in the submerged biological filters in a given space of chamber. Four materials, pile cloth, corrugated skylight roofing plate, embossed plastic plate, and gravel, were used as the experimental filter media. Each filter medium was placed in two aquariums, each aquarium measuring $90cm\times60cm\times60cm\;(depth)$. Under the normal operating condition, the average of mean ammonia removal rates during the first and second functioning periods by each filter material which occupied tile space in the filter chamber (aquarium) was as follows: 1. Pile cloth: $8.381\;g{\cdot}m^{-3}.\;day^{-1}$ 2. Corrugated skylight roofing plate: $7.834\;g{\cdot}m^{-3}.\;day^{-1}$ 3. Embossed plastic plate: $7.797\;g{\cdot}m^{-3}.\;day^{-1}$ 4. Gravel: $7.051\;g{\cdot}m^{-3}.\;day^{-1}$ Thus, there were no significant differences between the media, but at the time of practical application of these materials, some other factors such as investment cost, easiness for the removal of excess detritus accumulated in tile interstices of filter media, etc. should be fallen into consideration. When large units are required, in particular, removal of excess detritus from tile gravel bed is extremely difficult, and in case of pile cloth filters the installation work is much complicated and a problem in supporting the structure when drained also exists. In these respects, corrugated skylight roofing plate and embossed plastic plate seem to be more optimal, but again in practice the local situation for the availability and the price of the materials should be rechecked and the fitness of tile materials in the particular filter chambers under use or under consideration for construction must be taken into account.

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Study on the Morphological Change and Reduction Plan of Nitrogen and Phosphorous in Litter and Manure of Cow House (우사의 깔짚과 퇴비에 있는 질소와 인의 형태적 변화와 저감 방안에 관한 연구)

  • Kim, Younjung;Ryoo, Keon Sang
    • Journal of the Korean Chemical Society
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    • v.65 no.4
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    • pp.249-253
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    • 2021
  • Litter and manure were obtained at a cow house of a livestock farm in Andondg city. We examined the change of formation of nitrogen and phosphorous from these samples and tried to suggest a more useful and realistic way for removing them. Constituent and its content of sample were identified by XRF. NO2-, NO3-, and PO43- ions and NH4+, T-P and T-N released from sample were analyzed using ion chromatograph and UV/Vis spectrometry, respectively. As the results of this study, the ammonia nitrogen in the early stage of cow excretion is a need to make an ammonia gas state that can be immediately volatile by increasing the pH. Nitrogen and phosphorous, the main source of nutrition in green algal bloom can be removed by transforming insoluble salts such as calcium phosphate (CaHPO4·3H2O) and struvite (NH4MgPO4·6H2O), respectively, with addition of Ca and Mg after stimulating fermentation of manure.

A Study on Changes in Pore Water Quality of Polluted Sediment due to Mixing Ratio of Granulated Coal Ash (석탄회 조립물 혼합비율에 따른 오염 퇴적물의 간극수 수질 변화에 관한 연구)

  • Lee, In-Cheol;Woo, Hee-Eun;Kim, Kyeongmin;Lee, Jun-Ho;Kim, Kyunghoi
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.30 no.5
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    • pp.201-206
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    • 2018
  • This study investigated the changes in pore water quality of polluted sediment by mixing ratio of granulated coal ash. The mesocosm experiments were carried out with 0%, 10%, 30% and 50%, respectively, of the material mixture ratio relative to the sediments. According to the results of the experiments, pH increased depending on the mixing ratio. Phosphate and ammonia concentrations were significantly decreased in the mixing ratio of 30% and 50% compared to the control (p < 0.05). The concentration of hydrogen sulfide was reduced by 72% at the mixing ratio of 10%, and it was not detected at the mixing ratio of 30% and 50%. This study was confirmed that granulated coal ash can change the pore water quality of polluted sediments in proportion to the amount of material. However, the effect of the mixing ratio between 30% and 50% was not significantly different, thus it is concluded that mixing of 30% of the volume of the sediment is economically feasible.

The Separation of Ce, Pr, Nd and Sm from Rare Earth Oxides (1차 분리된 희토류산화물 중 Ce, Pr, Nd 및 Sm의 분리)

  • Yong-Kuen Lee;In-Wha Woo;Young-Gu Ha
    • Journal of the Korean Chemical Society
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    • v.24 no.6
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    • pp.434-443
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    • 1980
  • The purpose of this work was to separate Ce, Pr, Nd and Sm from rare-earth oxides by column chromatography. Rare earth solution were adsorbed into the Amberlite IR-120 resin and were eluted by the ammonia alkali solution of the EDTA. As a result of determinating rare earth metals of each fraction, Ce was separated very effectively and Nd and Sm partially separaed but Pr never separated.

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Simulation and Cost Estimation of Energy Transportation at Ambient Temperature Using an Absorption System (흡수식을 이용한 상온에너지수송의 모사 및 비용평가)

  • 김성수;오민규;전상현;강용태
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.15 no.12
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    • pp.1028-1034
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    • 2003
  • The objectives of this paper are to study the effect of key parameters on the cycle performance and capacity and to estimate the cost of latent and sensible energy transportation systems. The overall conductance (UA) of each component, the ambient temperature and the absorber inlet temperature are considered the key parameters. It is concluded that COP of the solution transportation using an absorption system (STA) at ambient temperature is 10% higher than that of the conventional sensible system. It is also found that the cost of STA system can be reduced 7.5 times to that of sensible energy transportation for one year of operation with 10 km transportation distance.

Non-Pt transition metal electrode catalyst for Oxygen Reuction Reaction of Polymer Electrolyte Membrane Fuel Cell (고분자 전해질 연료전지의 산소환원반응을 위한 비백금계 전이금속 전극 촉매)

  • Kim, Jy-Yeon;Lee, Sang-Beom;Park, Kyung-Won
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.383-385
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    • 2009
  • 비백금계 코발트 전이금속 촉매를 탄소지지체에 담지한 뒤, 암모니아 분위기에서 $500^{\circ}C$에서 3시간 동안 열처리하는 과정을 통해 코발트 질화물 촉매를 제조했다. 제조된 촉매들의 구조와 형태를 각각 XRD, HE-TEM등을 통해 분석하였고, 전위 측정기를 이용한 CV, LSV 결과로부터 촉매의 전기화학적 산소 환원특성을 분석하여, 기존의 연료전지 양극 촉매로 사용되는 고가의 백금촉매를 대체하기 위한 비백금계로서의 가능성을 확인하였다.

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Instability Analysis of Marangoni Convection for $NH_3-H_2O$ Absorption Process Accompanied by Heat Transfer (열전달을 수반하는 $NH_3-H_2O$ 흡수과정에서의 Marangoni 대류 불안정성 해석)

  • 김제익;최창균;강용태
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.15 no.2
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    • pp.126-131
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    • 2003
  • Convective instability driven by surface tension is analyzed in an initially quiescent water absorbing ammonia gas with heat transfer using the linear stability analysis. The propagation theory is adapted to find the critical conditions of the onset of Marangoni convection. In this theory, the solutal penetration depth is chosen as the length scale factor. The results show that the liquid layer becomes more stable with decreasing the Schmidt number and increasing the Lewis number. It is also found that there is a critical Biot number to make the liquid layer be most unstable, and there is a linear relationship between the thor-mal Marangoni number and the solutal Marangoni number.

Thermal Analysis of a Combined Absorption Cycle of Cogeneration of Power and Cooling for Use of Low Temperature Source (저온 열원의 활용을 위한 흡수 발전/냉각 복합 사이클의 열적 해석)

  • Kim, Kyoung-Hoon
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.23 no.6
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    • pp.413-420
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    • 2011
  • Thermodynamic cycles using binary mixtures as working fluids offer a high potential for utilization of low-temperature heat sources. This paper presents a thermodynamic performance analysis of Goswami cycle which was recently suggested to produce power and cooling simultaneously and combines the Rankine cycle and absorption refrigeration cycle by using ammoniawater mixture as working fluid. Effects of the system parameters such as concentration of ammonia and turbine inlet pressure on the system are parametrically investigated. Results show that refrigeration capacity or thermal efficiency has an optimum value with respect to ammonia concentration as well as to turbine inlet pressure.

Effects of Dietary Antimicrobial Agents, Probiotics or Yucca Extract on Urease Activity and Ammonia Production in the Chicken Intestine (사료중 항균제, 생균제 또는 유카 추출물이 닭의 장내 요소 분해효소 활성과 암모니아 생산에 미치는 영향)

  • 김규일;여진모
    • Korean Journal of Poultry Science
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    • v.22 no.2
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    • pp.105-115
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    • 1995
  • The balance of microbial populations in the gastrointestinal (GI) tract of all warm-blooded animals is critical to the maintenance of health and resistance to disease. The composition of the populations can be altered by diet and environment, making the host animal susceptible to disease, and reducing growth rate and feed efficiency. Some feed additives including antimicrobial agents, prohiotics or yucca extract have been used to promote growth and feed utilization. There is evidence that part of growth-promoting effect of those feed additives results from the suppression of microbial urease activity or ammonia production in the GI contents of animals. Over 200 microbial species have been known to produce urease and the product of urea hydrolysis, ammonia, is toxic to animals. Carefully tested probiotics or other urease-suppressing agents can be a possible alternative to antimicrobial agents including antibiotics as growth promotants used for animals feeds.

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