• Title/Summary/Keyword: 알칼리계

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The Microstructure and Durable Properties of the Composites with the Ground Granulated Blast Furnace Slag (고로슬래그 미분말을 사용한 몰탈의 미세구조와 내구특성)

  • Kim, Won-Ki;Soh, Jung-Sub;Kim, Dong-In;Kim, Hoon-Sang;Kim, Hong-Joo
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2004.05a
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    • pp.143-148
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    • 2004
  • 고로슬래그 미분말과 플라이 애쉬와 같은 재료들이 콘크리트의 내구성과 장기강도 증진을 목적으로 혼합재로서 사용되고 있다. 본 연구에서는 고로슬래그 사용 몰탈의 내구성 증진 특성을 활용하기 위하여 고로슬래그 미분말에 알칼리 자극제를 첨가한 알칼리 활성화 슬래그계 무기결합재 사용 몰탈의 내구성과 물리적 특성을 평가하였다. 실험결과, 몰탈의 초기 압축강도 발현에 알칼리 자극제가 큰 영향을 미치는 것을 확인하였다. 또한 알칼리 자극제가 첨가된 몰탈의 화학적 저항성을 평가하기 위하여 공시체를 재령 28 일 후, 5% 황산($H_2SO_4$) 용액에 침지하여 압축강도 및 질량 변화를 관찰하였다. 그 결과, 보통포틀랜드 시멘트로 제조한 몰탈의 경우, 황산용액 침지 후 압축강도가 54% 감소하였다. 반면 고로슬래그 미분말을 첨가한 몰탈의 경우, 약 10% 강도가 감소하였다. 질량변화의 경우, 보통포틀랜드 시멘트로 제조한 공시체는 17%, 고로슬래그 미분말을 첨가한 몰탈은 3%의 질량변화를 보였다. 이 결과로서 고로슬래그 미분말을 첨가한 몰탈의 경우, 화학적 저항성과 물리적 특성이 우수한 것을 확인하였다.

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Effect of Sarcoplasmic Protein and NaCl on Heating Gel from Fish Muscle Surimi Prepared by Acid and Alkaline Processing (산과 알칼리 공정으로 제조한 어육 수리미의 가열 겔에 미치는 근형질단백질과 NaCl의 영향)

  • 박주동;윤수성;정춘희;조민성;최영준
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.32 no.4
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    • pp.567-573
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    • 2003
  • Surimi yields from acid and alkaline processing of 5 fishes were compared to those from conventional processing Effect of sarcoplasmic protein and NaCl on heating gel from acid and alkaline surimi were also investigated by punch test and color. Yield of alkaline surimi was higher than that of conventional surimi. However, the breaking force, deformation and whiteness of heating gel from alkaline surimi were lower than those of heating gel from conventional surimi. The sarcoplasmic protein increased a breaking force and a deformation of gel. A breaking force was decreased, but deformation not significantly with NaCl concentration. Myosin heavy chain (MHC) and actin were greatly degraded in acid processing. Alkaline process for surimi is a valuable way of increasing the utilization of frozen and pelagic fishes, and making kamaboko-type products.

Pore and Efflorescence Characteristics of Alkali Activated Slag-Red Mud Cement Mortar depending on Red Mud Content (레드머드 대체율에 따른 알칼리활성화 슬래그-레드머드 시멘트 모르타르의 기공 및 백화특성)

  • Kang, Suk-Pyo;Kang, Hye-Ju
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.3
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    • pp.261-268
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    • 2017
  • Red mud is an inorganic by-product obtained from the mineral processing of alumina from Bauxite ores. A highly alkali inorganic waste product with a pH level over 11, red mud in its original state negatively impacts the ecosystem, so appropriate treatment is necessary. The development of alkali activated slag-red mud cement can be a representative study aimed at recycling the strong alkali of the red mud as a construction material. However, Alkali-activated binders that use sodium activators have been reported to be more vulnerable to efflorescence. Therefore, in this study, the compressive strength, pore characteristics, water absorption, elution characteristics, and efflorescence properties of alkali-activated slag cement mortar were assessed according to their red mud substitution ratio.

Comparison of pretreatment of fallen leaves for application evaluation by Bio-ethanol raw material (바이오에탄올 원료로서 활용평가를 위한 낙엽의 전처리 비교)

  • Choi, Hyoyeon;Kim, Jaehyung;Pak, Daewon
    • Journal of Energy Engineering
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    • v.23 no.3
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    • pp.241-246
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    • 2014
  • This study is to compare characteristics of saccharification reactions applying to enzymatic hydrolysis of pretreated fallen leaves for bio-ethanol production. It experimented pretreatment of acid, alkaline in the chemical. This experiment includes preteatment of acid and alkaline in chemical, soaking, shaking and autoclaving method, which were applied to biomass. In result, the glucose production from alkaline-NaOH method was 263 mg glucose/ g biomass comparing with them of acid-HCl method. Thus, alkaline-NaOH method is superior than the acid-HCl method for chemical preteatment of fallen leaves. Also, when various chemical treatments were compared, they were all. Based on the results of this study, we found that leaves, one of biomass, are possible in pretreatment and enzymatic hydrolysis process, and they are likely to affect bio-ethanol production in the future.

Properties of Epoxy-Modified Mortars with Alkali Activators and Ground Granulated Blast Furnace Slag (알칼리자극제 및 고로슬래그미분말을 병용한 에폭시수지 혼입 폴리머 시멘트 모르타르의 성질)

  • Kim, Wan-Ki
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.1
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    • pp.85-92
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    • 2021
  • The purpose of this study is to investigate the properties of hardener-free epoxy-modified mortars(EMMs) using ground granulated blast furnace slag(GGBFS) and alkali activators. The hardener-free EMMs with a GGBFS content of 20% using 4 types of alkali activators were prepared with various polymer-binder ratios, and tested for strengths, water absorption, carbonation depth, chloride ion and H2SO4 penetration depth. The conclusions obtained from the test results are summarized as follows: The compressive strength of the EMMs with a GGBFS content of 20% attains a maximum at a polymer-binder ratio of 10%. The flexural strength of the hardener-free EMMs using Ca(OH)2 as a alkali activator is improved with increasing polymer-binder ratios. However, the flexural strength of the EMMs using NaCO3, Na2SO4 and Li2CO3 is gradually decreased with increasing polymer-binder ratios. Regardless of the type of alkali activator, the water absorption, chloride ion penetration and carbonation depth are remarkably decreased with increasing polymer-binder ratios due to the epoxy film formed in the EMMs. The H2SO4 penetration depth of the hardener-free EMMs with a GGBFS content of 20% is gradually increased with increasing polymer-binder ratio. In this study, the properties of hardener-free EMMs using Ca(OH)2 as a alkali activator are more excellent than those of other alkali activators.

Durability Characteristics of Ternary Cement Matrix Using Ferronickel Slag According to the Alkali-Activators (알칼리 활성화제 종류별 페로니켈슬래그를 사용한 3성분계 시멘트 경화체의 내구특성)

  • Cho, Won-Jung;Park, Eon-Sang;Jung, Ho-Seop;Ann, Ki-Yong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.2
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    • pp.190-197
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    • 2020
  • This paper evaluates the mechanical properties and durability of cement matrix blended with mineral admixtures and ferronickel slag(FNS) powder which is an industrial b y-product during ferronickel smelting process. The hydration heat, pore structure, compressive strength, length change, rapid chloride penetration test(RCPT), and freezing and thawing resistance of ternary blended cement matrix were investigated and compared with ordinary portland cement matrix. The result showed that the compressive strength of ternary blended cement matrix using ferronickel slag powder and mineral mixture was low in strength compared to the reference concrete, but recovered to a certain extent by using alkali activator. Length change of cement mortar using FNS powder have shown less shrinkage occurs than the reference specimen. In addition, irrespective of using the alkali-activators, all ternary mix are indicative of the 'very low' range for chloride ion penetrability according to the ASTM C 1202, and the freeze-thaw resistance also showed excellent results.

A Study on the Removing of $SiO_2$ in Ferromanganese Dust by Fritting Method (Fritting법에 의한 페로망간 분진내 $SiO_2$제거에 관한 연구)

  • 임종호;이승원
    • Resources Recycling
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    • v.9 no.1
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    • pp.63-69
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    • 2000
  • Ferromanganese dust is an oxide substance of Mn. If imprities are removed and oxidation degree is controlled, the dust can be recycled for soft ferrite materials. The ferromanganese dust contained about 7 kinds of impurities, expecially about 9000 ppm of $SiO_2$ contents of the ferromanganese dust from 9000 ppm to under 500 ppm by fritting method. The $SiO_2$ in ferromanganese dust can be converted into water soluble compounds by alkali fritting and removed by water leaching. KOH and NaOH were used. The most effective conditions to get rid of $SiO_2$ from the dust are that the weight ratio of alkali to ferromanganese dust is 1.75 and fritting is run at $550^{\circ}C$ for 1 hour.

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Preparation of Surface-anionized Poly(vinyl alcohol-co-methacrylic acid) Hydrogel Beads (표면에 음이온이 도입된 폴리(비닐 알코올-co-메타아크릴산) 하이드로젤 입자의 제조)

  • 윤주표;박연흠;이세근;박기홍;이철주
    • Polymer(Korea)
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    • v.27 no.2
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    • pp.159-166
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    • 2003
  • For the purpose of obtaining surface-anionized poly(vinyl alcohol) (PVA) hydrogel beads, vinyl acetate(VAc) and methacrylic acid(MMA) were copolymerized by the suspension polymerization technique and followed by the saponification. It was confirmed by $^1$H-NMR that the copolymerized microspheres contained carboxylic acid groups in their surface. poly(VAc-co-MAA) microspheres were completely saponified in the heterogeneous system. The saponification reaction was laster than that of PVAc microspheres. We observed the swelling property of saponified PVA microspheres treated in the acidic solution and in the alkaline solution successively. Saponified microspheres shrank in acidic solution and swelled in alkaline solution respectively, which was reversible. from the result, saponified microspheres were highly water-absorbing hydrogel beads and were certified -COOH group at their surface by $^1$H-NMR and FT-IR.