• Korean Chemical Engineering Research
• /
• v.44 no.5
• /
• pp.547-554
• /
• 2006

The overall objective of this research was to find out the role of rapid mixing conditions in the species of hydrolyzed Al(III) formed by Al(III) coagulants and to evaluate the distribution of hydrolyzed Al(III) species by coagulant dose and coagulation pH. When an Al(III) salt was added to water, monomeric Al(III), polymeric Al(III), precipitate Al(III) was formed by Al(III) hydrolysis. The method of hydrolyzed Al(III) species characterization analysis was based on timed spectrophotometer with ferron as a color developing reagent. The hydrolytic species were divided into monomer, polymer, precipitate from the reaction kinetics. And then, the color intensity for monomeric Al(III) was read 3 min after mixing. With standard Al solution containing monomeric Al(III) only, the Al-ferron color intensity slightly increased with until about 3 min. During the rapid mixing period, for purewater, formation of dissolved Al(III) (monomer and polymer) was similar to rapid mixing condition, but for raw water, the species of Al(III) hydrolysis showed different result. During the rapid mixing period, for high coagulant dose, Al-ferron reaction increases rapidly. The kinetic constants, Ka and Kb, derived from Al-ferron reaction. The kinetic constants followed very well the defined tendencies for coagulation condition. For pure water, when the rapid mixing time increased, the kinetic constants, Ka and Kb showed lower values. Also, for raw water, when the rapid mixing time increased, the kinetic constants, Ka and Kb showed lower values.

• Journal of Welding and Joining
• /
• v.12 no.3
• /
• pp.41-47
• /
• 1994

본 공에서는 3회에 걸쳐 7000계열을 중심으로 하여 알루미늄 합금의 용접특성을 용접방법, 각종 결함과 대책, 시효경화와 응력부식균열 등으로 나누어 기술하였다. 7000계열의 고강도 알루미늄 합금은 수송기기 분야의 최대 기술적 과제인 연비개선과 고속화 실현을 해결할 수 있는 차량 차체의 경량소재로 수요가 증가하고 있다. 또한 거의 완벽한 재활용이 가능하여 환경문제로 인한 물자 재활용의 계속적인 요구를 해결할 수 있어 그 잠재성은 매우 크다. 그러나 현재 국내에서는 7000계열 등 고강도 알루미늄 용접의 기술수준이 선진국에 비해 떨어지기 때문에, 이에 대한 기술개발에 보다 많은 관심을 기울어야 할 것으로 사료된다.

• Journal of the korean academy of Pediatric Dentistry
• /
• v.48 no.4
• /
• pp.397-404
• /
• 2021

The purpose of this study was to evaluate the effect of a hemostatic agent containing aluminum chloride on the shear bond strength of resin-modified glass ionomer cement (RMGIC) to the dentin of primary teeth. Thirty-six extracted non-carious human primary teeth were collected in this study. Dentin surfaces were cut and polished. The specimens were randomly divided into 4 groups; group I: RMGIC without conditioning; group II: polyacrylic acid (PAA), RMGIC; group III: aluminum chloride, RMGIC; group IV: aluminum chloride, PAA, RMGIC. All teeth were thermocycled between 5.0℃ and 55.0℃ for 5000 cycles. Fifteen specimens from each group were subjected to shear bond strength test and 3 specimens from each group were inspected using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy. The mean shear bond strength of each group was as follows: 4.04 ± 0.88 MPa in group I, 8.29 ± 1.40 MPa in group II, 1.39 ± 0.47 MPa in group III, 6.24 ± 2.76 MPa in group IV. There were significant differences among all groups (p < 0.001). SEM image of the dentinal tubules were partially exposed in group III and group IV. Fully exposed dentinal tubules were found in group II. In conclusion, aluminum chloride decreased the shear bond strength of RMGIC to dentin, regardless of PAA conditioning.

• Journal of Korean Society of Environmental Engineers
• /
• v.34 no.5
• /
• pp.295-303
• /
• 2012

Removal of total nitrogen (T-N) and total phosphorus (T-P) was evaluated in a DEPHANOX process by adding Al(III) to the separator to maintain T-P in the final effluent below 0.2 mg/L. pH in each reactor was maintained 7~8 after addition of Al(III) to the levels of 5, 10, 15 mg/L. The removal efficiency of COD and T-N decreased at higher Al(III) dose, but T-P removal efficiency increased from 76.28 to 84.02, 94.66% at Al(III) dose of 5, 10, 15 mg/L, respectively. T-P in effluent showed 0.17 mg/L at Al(III) dose of 15 mg/L. Minimum 15 mg/L of Al(III) was required to maitain T-P below 0.2 mg/L in the final effluent.

• Analytical Science and Technology
• /
• v.16 no.2
• /
• pp.102-109
• /
• 2003

Microwave digestion and solid-state extraction were studied for determination of trace aluminum{Al(III)} in human urine samples. A mixed acid of nitric acid and hydrogen peroxide was added to urine samples, organic materials were destructed in a home microwave oven and dried in a drying oven. The dried residues were dissolved in a sulfuric acid solution. The solution was eluted through a XAD-4 resin column adsorbed with 8-hydroxyquinoline(Oxine, HQ). Al(III)-8-hydroxyquinolinate complex was formed in the column and eluted with 0.5 M nitric acid solution. The Al(III) eluted was determined by graphite atomic absorption spectrophotometry. Various experimental conditions of followings were investigated for the optimization : the type of acid to dissolve the residues, the amount of HQ adsorbed on the resin, the pH of sample solutions, the type and concentration of acid to elute the complex from column and so on. The contents of Al(III) in real samples were determinated by a calibration curve method. The recovery in standard spiked samples was 94~101% and the detection limit of this procedure was 0.05 ng/mL.

• Journal of Korean Society of Water and Wastewater
• /
• v.36 no.3
• /
• pp.177-186
• /
• 2022

In this study, newly improved Ferron assay test haved on timed spectrometry was used for the determination of hyolrolytic Al species presented in PACl coagulant. The color development reagent ferron was prepared by using conventional method and two newly developed methods. Then the ferron assay test was used to compare and analyze the distribution of Al(III) hydrolyzed species presented in the prepared PACl and alum. The preparing method of reagent A required an aging period of 7 days by adding a hydroxylamine hydroxide and a 1,10-phenanthroline monohydrate reagent, whereas the preparing method of reagent B was used as a coloring agent immediately without aging time. The regression analysis between UV absorbance and Al concentrations of conventional method and newly developed method of ferron reagents in low-concentration aluminum solutions and high-concentration aluminum solutions, showed the correlation coefficients of 0.999 or higher, as showing high correlations of conventional method and newly developed method. Applying Ferron assay test, Al species in the PACls and alum were classified as Ala(monomeric Al), Alb (polymeric Al), and Alc (colloidal and precipitated Al). Distribution of Al(III) hydrolyzed species according to the preparation of ferron colorimetric reagents was similar.

• Journal of the Mineralogical Society of Korea
• /
• v.20 no.2 s.52
• /
• pp.125-134
• /
• 2007

This study has been carried out in order to examine the precipitation characteristics of Fe, Mn and Al ions in coal mine drainage before removing heavy metals by using the froth flotation method. The removal rate of Fe(III), Mn(II) and Al(III) within 1 h accounted for over 99% in pH 5.0, 10.0, and $6.0{\sim}9.0$ respectively, and residual concentrations of which were under $1mgL^{-1}$. When sodium oleate as a collector was added to the solution of Fe, Mn, and Al ions, insoluble salts was not formed by the reaction of heavy metal and sodium oleate. So, we must remove the metals from coal mine drainage by using not the ion flotation method, but the precipitation flotation method

• Journal of Korean Society of Water and Wastewater
• /
• v.18 no.3
• /
• pp.331-336
• /
• 2004

The correlation between polymeric aluminum species of coagulant and its coagulation efficiency was investigated using several commercial polymeric Al(III) inorganic coagulants (Poly Aluminum Hydroxy Chloro Sulfate 2020 (PAHCS2020), Poly Aluminum Hydroxy Chloro Sulfate 2500 (PAHCS2500) which was introduced in Korean water treatment plants. The poly aluminum chloride (PAC), Poly Aluminum Hydroxide Chloride Silicate (PACS)) and the aluminum salts ($AlCl_3$, Alum ($Al_2(SO_4)_3$)) were used for the purpose of comparison. The comparison of the coagulation efficiency of each coagulant was made by turbidity removal through the standard jar testing procedure and the determination of the hydrolytic Al(III) species was made by the ferron method which can differentiate the monomeric aluminum species from the polymeric aluminum species. Overall, PAHCS2020 and PAHCS2500 showed the better performance in turbidity removal than the aluminum salts. The performance of coagulation was even better without adjustment of pH during the coagulation experiment. The positive correlation between polymeric aluminum species of coagulant and coagulation efficiency was found.

• Journal of the Korean Society of Manufacturing Process Engineers
• /
• v.15 no.1
• /
• pp.81-88
• /
• 2016

Recently, high-efficiency machining in the production of high-value products with complex shapes has constantly been required along with the need for hybrid machining. In this study, in addition to wire-cut Electric Discharge Machining (EDM) and vibration, we present the possibility of a hybrid process by carrying out an experiment with aluminum alloy, and the hybrid process determines the nature of the surface. The selected experimental parameters are waveform, amplitude, peak current, and two-dimensional (2D) vibration. The experimental results give the guideline for selecting reasonable machining parameters. The surface roughness was improved about 20% with increases in the amplitude of the vibration.

• Composites Research
• /
• v.28 no.4
• /
• pp.191-196
• /
• 2015

In this study, the static analysis and experiment were carried out on DCB specimens manufactured with aluminum foam in order to investigate the fracture toughness at the adhesive joint of the structure bonded with adhesive. In case of static analysis, all specimen models were shown to have the maximum reaction force when the forced displacement proceeded as much as 5 mm. The maximum reaction forces became 0.25 kN, 0.28 kN and 0.5 kN respectively in cases of specimen thicknesses of 35 mm, 45 mm and 55 mm. Two specimens in case of static experiment were selected to verify these analysis results. The maximum reaction forces were shown when the forced displacement proceeded as much as 5 to 6 mm. The maximum reaction forces became 0.22 kN and 0.3 kN respectively in cases of specimen thicknesses of 35 mm and 45 mm. By comparing the derived results, it could be shown that there was not much difference between the data of analyses and experiments. Therefore, It is inferred that the study data can be secured with only analysis by no extra experimental procedure. It is thought that the mechanical properties at the structure bonded of DCB with the type of mode III can be analyzed systematically.