• Title/Summary/Keyword: 안티몬

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Analysis of Heavy Metals in Dyes and Pigments Used in Make up Tattoo (화장용 문신으로 사용되는 염료 및 색소의 중금속 분석)

  • Jeong, Mi-Ra;Lee, Hui-Seong;LEE, Ji-Young;Lee, Sun-Hwa
    • Journal of the Korea Convergence Society
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    • v.9 no.4
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    • pp.321-329
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    • 2018
  • This study was attempted to provide data for establishing appropriate guidelines and control standards for accurate information and production of dyes and pigments through the analysis of representative heavy metals and other metals used in cosmetic tattoos. A total of 30 tattoo products for cosmetics were selected from among the representative heavy metals such as arsenic, antimony, cobalt, cadmium, copper, lead, zinc, barium, tin, selenium, chromium and magnesium, manganese(15kinds) were analyzed. As a result of examining the contents of heavy metals in dyes and pigments used in cosmetic tattoo products, it was found that the total of 20products(66.7%) exceeded the reference value and found to be unsuitable for safety standards. It is suggested that the guidance of the specialized agency for safe procedures, appropriate control controls and standards for the dyes and pigments used, and the potential risks of heavy metals are needed.

A Study on the Shielding Element Using Monte Carlo Simulation (몬테카를로 시뮬레이션을 이용한 차폐체 원소 평가)

  • Kim, Ki-Jeong;Shim, Jae-Goo
    • Journal of radiological science and technology
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    • v.40 no.2
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    • pp.269-274
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    • 2017
  • In this research, we simulated the elementary star shielding ability using Monte Carlo simulation to apply medical radiation shielding sheet which can replace existing lead. In the selection of elements, mainly elements and metal elements having a large atomic number, which are known to have high shielding performance, recently, various composite materials have improved shielding performance, so that weight reduction, processability, In consideration of activity etc., 21 elements were selected. The simulation tools were utilized Monte Carlo method. As a result of simulating the shielding performance by each element, it was estimated that the shielding ratio is the highest at 98.82% and 98.44% for tungsten and gold.

A study on the removal of As, Sb, Bi from the copper sulfate solutions by Ion exchange resin containing Aminophosphosphonic acid as a functional group (황산동용액(黃酸銅溶液)에서 Aminophosphosphonic acid 관능기를 가진 이온교환수지에 의한 As, Sb, Bi 제거(除去)에 관한 연구(硏究))

  • Ahn, Jae-Woo;Seo, Jae-Seong
    • Resources Recycling
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    • v.21 no.5
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    • pp.50-57
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    • 2012
  • A comparative study has been carried out on the removal of impurities such As, Sb, Bi from the copper sulfate solution by ion exchange resin containing aminophosphosphonic acid as functional group. The various parameters which affect the removal of impurities; such as the reaction temperature, the reaction time, the amount of ion-exchange resins, the concentration of sulfuric acid in electrolyte, were studied. The basic experimental results showed that about 88% of Sb & 94% of Bi can be adsorbed in these chelate resins and removed from the copper sulfate solutions but As was removed below 10% from the solutions. And the selective elution of Bi and Sb from the adsorbed ion exchange resin also can be achieved by $H_2SO_4$ or HCl solutions. The results also showed that 98.1% of Sb and 96.6% of Bi can be adsorbed from the copper sulfate solutions after 2 Bed-volume of continuous ion exchange column test.

Provenance Study on Lead Isotope of the Bronze Using a Korea Peninsula Lead Isotope Data - Focused on Bronze Relics Excavated from Cheonghaejin - (한반도 납광산의 납동위원소비를 이용한 청동 원료의 산지추정 - 청해진 출토 청동기를 중심으로 -)

  • Hwang, Jin Ju;Kim, So Jin;Han, Woo Rim;Han, Min Su
    • Journal of the Mineralogical Society of Korea
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    • v.27 no.4
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    • pp.263-270
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    • 2014
  • This paper was researched that provenance of the raw material for bronze relics excavated Cheonghaejin using the distribution of lead isotope ratio based on galena ores of South Korea. Also we want to make sure that the trace elements appearing as a by-product can be used as a secondary indicator for provenance research. In the case of the galena map of the East-North Asia (Mabuchi, 1985), data are plotted in China area. Therefore it is estimated that most bronzes were produced with lead ore from China. On the other hand, the same data are plotted in the Okcheon Metamorphic Belt and Yeongnam Massif of the galena map of South Korea (KOPLID, 2012). Also the contents of Ag and Sb are available as indicator due to separate ores from similar zone in lead isotope ratio.

Study on the safety review and management system of Hazardous substances in nail products (네일 제품의 유해물질 안전성 검토 및 관리제도 개선 연구)

  • Yun, Cho-Hee;Lee, Seung-Hee
    • Journal of the Korea Convergence Society
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    • v.8 no.11
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    • pp.439-445
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    • 2017
  • This study compares the safety of nail products by reviewing domestic and foreign literature for preparing a safety management plan for reduction of human body exposure to hazardous substances that occur in nail products. We analyzed the cases of exceeding the limit value of hazardous substances. In domestic artificial nail adhesive and nail tip, toluene content was 40.3 times higher than the standard value, chloroform was 22.8 times, and antimony was 15.4 times. In developed countries, it is obligatory to provide material safety data and workplace ventilation equipment through various policy researches. However, there is no safety standard in Korea. Therefore, if the regulations for safety management should be established with each characteristic of nail product, work environment, workers, and consumers, and the awareness of hazardous substance cosmetics should be improved through development and dissemination of various educational programs, it can contribute to disease prevention and health promotion.

A Study on the Acid Digestion Bomb Pretreatment Method of Fire Retardant Chemicals (DBDPE-$Sb_2O_3$) for the Determination of Antimony (DBDPE-$Sb_2O_3$ 중 Sb를 분석하기 위한 가압 산분해 전처리 연구)

  • Choi, Jong-Keum;Park, Je-An;Park, Kyung-Su;Kim, Sun-Tae;Kim, Young-Sang
    • Analytical Science and Technology
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    • v.13 no.6
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    • pp.731-735
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    • 2000
  • The acid digestion bomb pretreatment method for the determination of antimony in a commercial fire retardant material sample (DBDPE-$Sb_2O_3$) was studied. DBDPE-$Sb_2O_3$ sample was digested with $H_2SO_4:HCl$(1:2) mixture in digestion bomb at $220^{\circ}C$ for 2 hrs. and antimony was determined by atomic absorption spectrophotometry. Recovery of 99.6-99.8% and C.V. of 0.94-1.07% for Sb was obtained for spiked real samples. In the present method, the analytical results obtained for antimony were 40.3 and 36.3% (w/w), respectively.

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Monitoring of Lead and Antimony in Metallic Kitchenware (국내 유통 금속제 주방기구 중 납 및 안티몬 모니터링)

  • Lee, Sun-Hee;Jung, Kyu-Jin;Lee, Yoong-Kook;Sung, Jun-Hyun;Eom, Mi-Ok;Lee, Yong-Ja;Lim, Joung-Gyoon
    • Journal of Food Hygiene and Safety
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    • v.22 no.1
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    • pp.52-56
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    • 2007
  • In order to offer monitoring data about standard and specification of metallic kitchenware, we carried out the material test and migration test of lead and antimony in 71 kinds of kitchenwares. As a result of this study, Pb was detected less than 0.06% at the material test and Sb was not defected in 71 kinds of kitchenwares. Pb was also detected less than 0.41 mg/L at the migration test. Currently according to the Food Code of Korea, Pb and Sb in metal product shall not exceed 10% and 5%, respectively and Pb migrated from metal product shall not exceed 1.0 mg/L. Therefore, our all data are not exceeding the standard and specification of metal product and show that all the kitchenwares in domestic circulation may be safe.

Fabrication of compact surface structure by molar concentration on Sb-doped SnO2 transparent conducting films (안티몬 도핑된 주석 산화물 투명전도막의 몰 농도에 따른 치밀한 표면 구조 제조)

  • Bae, Ju-Won;Koo, Bon-Ryul;Ahn, Hyo-Jin
    • Journal of Powder Materials
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    • v.25 no.1
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    • pp.54-59
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    • 2018
  • Sb-doped $SnO_2$ (ATO) transparent conducting films are fabricated using horizontal ultrasonic spray pyrolysis deposition (HUSPD) to form uniform and compact film structures with homogeneously supplied precursor solution. To optimize the molar concentration and transparent conducting performance of the ATO films using HUSPD, we use precursor solutions of 0.15, 0.20, 0.25, and 0.30 M. As the molar concentration increases, the resultant ATO films exhibit more compact surface structures because of the larger crystallite sizes and higher ATO crystallinity because of the greater thickness from the accelerated growth of ATO. Thus, the ATO films prepared at 0.25 M have the best transparent conducting performance ($12.60{\pm}0.21{\Omega}/{\square}$ sheet resistance and 80.83% optical transmittance) and the highest figure-of-merit value ($9.44{\pm}0.17{\times}10^{-3}{\Omega}^{-1}$). The improvement in transparent conducting performance is attributed to the enhanced carrier concentration by the improved ATO crystallinity and Hall mobility with the compact surface structure and preferred (211) orientation, ascribed to the accelerated growth of ATO at the optimized molar concentration. Therefore, ATO films fabricated using HUSPD are transparent conducting film candidates for optoelectronic devices.

Effect of Various Supports on the Catalytic Performance of V-Sb Oxides in the Oxidative Dehydrogenation of sobutane (이소부탄의 산화탈수소반응에 대한 여러 담지체에 따른 V-Sb 산화물 촉매 성능 효과)

  • Shamilov, N.T.;Vislovskiy, V.P.
    • Journal of the Korean Chemical Society
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    • v.55 no.1
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    • pp.81-85
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    • 2011
  • $V_{0.9}Sb_{0.1}O_x$ systems, bulk and deposited on different supports (five types of $\gamma$-aluminas, $\alpha$-alumina, silica-alumina, silica gel, magnesium oxide), have been tested in the oxidative dehydrogenation (ODH) of iso-butane. Catalytic performance of VSb oxides has shown to be highly dependent on the support and the nature of the support decreasing in a series: $\gamma$-$Al_2O_3$ > $\alpha$-$Al_2O_3$ > Si-Al-O > $SiO_2$ $\approx$ MgO $\gg$ unsupported. Variation of the V-Sb-O-loading in the studied range of coverage (0.5-2 theoretical monolayer) only slightly influences the catalysts' activity and selectivity. The best catalytic performance of $\gamma$-alumina-supported $V_{0.9}Sb_{0.1}O_x$ systems can be explained by the optimal surface interaction between support and supported components resulting in the formation of well-spread amorphous active $VO_x$-component with vanadium in a high oxidation state.

Exploration for the Carlin-type Gold Deposits and Its Potential to Korea (칼린형 금광상 탐사와 국내 적용성 연구)

  • Park Maeng-Eon;Sung Kyu-Youl;Baek Seung-Gyun;Kim Pil-Geun;Kang Heung-Suk;Moon Young-Hwan
    • Economic and Environmental Geology
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    • v.38 no.4 s.173
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    • pp.421-434
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    • 2005
  • Abstract Based onthe characteristics of Carlin-type gold deposit in Nevada district, a potential in Korea is evaluated to the Yemi area where is structurally controlled by folds and trust fault. The fault of high angles are combined with a more permeable rocks such as the Yemi breccia and laminated silty limestone. The pattern of enrichment factors for Tl, Sb, As, Ag, Pb, Zn, Cu, Mo and W of limestones in the southern area are geochemically similar with those reported from the Carlin-type Bold deposit. Moreover, the oxygen and carbon isotopes show a hydrothermal alteration is widely developed in this area. According to the result of geophysical interpretation, stable isotope, alteration mineralogy, geochemical study, and geological structure, this mineralized zone may be extended to the M direction, so a detailed systematic exploration is required to identify this alteration zone.