• Journal of the Korean Chemical Society
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• v.55 no.4
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• pp.603-611
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• 2011

Ethoxylacetyl oxime ligands [HL, (1) and $H_2L^1$, (3)] react with copper(II) acetate monohydrate yield octahedral and square planar complexes, respectively. The complexes have been postulated due to elemental analyses, IR, UVVis. spectra, magnetic susceptibility, conductivity and ESR spectra. Molar conductance of the complexes in DMF indicates a non-ionic character. The ESR spectra of [$(L)_2Cu(H_2O)_2$], (2) complex at room temperature and 77K are characteristic of an axial symmetry ($d_{x2-y2}$) with covalent bond character and have a large line width typical of dipolar interactions. However, [$(L^1)Cu$], (4) complex in the solid state showed spectra of marked broadening and loss of hyperfine splitting confirming spinexchange interactions between the copper(II) sites. The spectrum of the doped copper(II) complex at room temperature showed super-hyperfine splitting from coordinated nitrogen atoms and it has an axial type ($d_{x2-y2}$) with covalent bond character and an essentially square-planar arrangement around the copper(II) ion. The spectrum of [$(L^1)Cu$], (4) in frozen methanol at 77K was characteristic of the triplet state of a dimer species and the distance found between the two copper(II) centers was calculated and is equal to 4.8 ${\AA}$.

• Journal of the Korean Chemical Society
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• v.53 no.3
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• pp.302-307
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• 2009

Investigation was conducted to examine whether photochemical reaction of N-(tributylstannyl)- methylphthalimide generates an azomethine ylide intermediate in its excited state as its silyl derivative N-(trimethylsilyl)methylphthalimide which has been observed to form an azomethine ylide. The irradiation of N-(tributylstannyl)methylphthalimide in $D_2O-CH_3$CN generates mono-deuterated N-methylphthalimide as an exclusive product which supports the efficient generation of azomethine ylide intermediate and its trapping by water molecule through a proto-destannylation pathway. However the generated tributylstannyl subsitiuted ylide was not observed to be trapped with a dipolarophile such as methyl acrylate and acrylonitrile present in the reactions which is in contrast with the ylide from N-(trimethylsilyl)methylphthalimide.

• Korean Chemical Engineering Research
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• v.48 no.2
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• pp.224-231
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• 2010

In GvdW EOS, a recently presented paper, shows that the characteristic status for spherical non-linear particle, of which the mutual behavior is known to be vdWf(van der Waals force) only, could be described well enough in the critical region. However, in current papers, analysis has not been done on GvdW about whether it is accurate or not, even for the particles in the linear form or those with the additional mutual behavior such as static-electricity, so there's some argument about the wide use of that. Therefore, in this paper, for the simulation in the critical region of Normal-alkane group(R=methane, ethane, propane, butane) which are the particles that has a linear charateristic and Normal-amine group($RNH_2$, R=methyl-, ethyl-, propyl-amine) where static-electricity is extremely shown, GvdW parameter values about these particles are defined, and based on this simulation, we compared results to the current EOS presented recently, and analyzed them. Through the simulation, it was shown that in case of Normal-alkane group and Normal-amine group molecules, GvdW presents an accurate critical region characteristic which is far more close to the measurement compared to current EOSs. Especially for butane with big amount in molecules, we found out that only GvdW EOS can reach close enough to the critical point.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.22 no.6
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• pp.79-88
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• 2008

In this study electromagnetic fields near electric power lines were derived by dipole antenna theory and electromagnetic fields near 3 phase power lines with vertical configurations were formulated and could be computed easily using these formula. It seems that those formula could be applicable to the consideration of electromagnetic fields during the design of transmission and distribution lines. Those formulated equations on elements of electromagnetic fields were applied to the model of a transmission-line system and were calculated by Matlab programs. The calculation results are follows. For variation of horizontal distance profiles of $E_y$ and $B_z$ are same each other, and also those of $B_y$ and $E_z$ are same each other. This means that coupled elements of E and B are perpendicular each other and have the propagation direction of the right-hand system such as $x{\rightarrow}E_y{\rightarrow}B_z$. Resultant electric field E is dominated by the element $E_y$ and resultant magnetic field B is dominated by the element $B_z$.

• Journal of the Korean Vacuum Society
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• v.12 no.4
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• pp.218-227
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• 2003

Pd/Si/Ti/Pt and Pd/Si/Pd/Ti/Au ohmic contacts to n-type InCaAs were investigated for applications to AlGaAs/GaAs HBT emitter ohmic contacts. In the Pd/Si/Ti/Pt ohmic contact, as-deposited contact showed non-ohmic behavior, and high specific contact resistivity of $5\times10^{-3}\Omega\textrm{cm}^2$ was achieved by rapid thermal annealing at $375^{\circ}C$/10 sec. However, the specific contact resistivity decreased remarkably to $2\times10^{-6}\Omega\textrm{cm}^2$ by annealing at $425^{\circ}C$/10sec. In the Pd/Si/Pd/Ti/Au ohmic contact, minimum specific contact resistivity of $3.9\times10^{-7}\Omega\textrm{cm}^2$ was achieved by annealing at $400^{\circ}C$/20sec. In both ohmic contacts, low contact resistivity and non-spiking planar interface between ohmic materials and InGaAs were maintained. Therefore, these thermally stable ohmic contact systems are promising candidates for compound semiconductor devices. RF performance of the AlGaAs/GaAs HBT was also examined by employing the Pd/Si/Ti/Pt and Pd/Si/Pd/Ti/Au systems as emitter ohmic contacts. Cutoff frequencies were 63.9 ㎓ and 74.4 ㎓, respectively, and maximum oscillation frequencies were 50.1 ㎓ and 52.5 ㎓, respectively. It shows very successful high frequency operations.

• Geophysics and Geophysical Exploration
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• v.1 no.1
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• pp.57-63
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• 1998

The electrical resistivity method, one of old and widely used geophysical prospecting methods, has extended its scope to civil & environmental engineering areas. The electrical resistivity imaging technique was performed at the waste disposal site located in Junju to verify the applicability to the environmental engineering area. The dipole-dipole array, with the dipole spacing of 10 m, was applied along eight survey lines. The field data were obtained under the control of automatic acquisition softwares and topographic effects were corrected during processing stage. The processed resistivity images show that very low resistivity develops inside the disposal site and the distribution of low resistivity is exactly in accord with the boundary of the site except the river side. The depth of low resistivity zones is deeper toward the river side, which is interpreted that there is a high possibility for contaminants to be scattered to the river. From resistivity images, it was feasible to deduce the depth of waste disposal as well as the horizontal/vertical distribution of the contaminated zone, which proved the applicability of the electrical resistivity imaging technique to the environmental engineering area.

• Applied Chemistry for Engineering
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• v.30 no.2
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• pp.160-166
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• 2019

In this study, oxygen functional groups were introduced on activated carbon fibers (ACFs) by oxygen plasma treatment to improve the adsorption performance on an acetic acid which is a sick house syndrome induced gas. The active species was generated more as the flow rate of the oxygen gas increased during the plasma treatment. For this reason, the specific surface area (SSA) of the ACFs decreased with much more physical and chemical etching. In particular, the SSA of the sample (A-O60) injected with an oxygen gas flow rate of 60 sccm was reduced to about $1.198m^2/g$, which was about 6.95% lower than that of the untreated samples. On the other hand, the oxygen content introduced into the surface of ACFs increased up to 35.87%. Also, the adsorption performance on the acetic acid gas of the oxygen plasma-treated ACFs was improved by up to 43% compared to that of using the untreated ACFs. It is attributed to the formation of the hydrogen bonding due to the dipole moments between acetic acid molecules and oxygen functional groups such as O=C-O introduced by the oxygen plasma treatment.

• Journal of the Korean Geotechnical Society
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• v.38 no.10
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• pp.49-60
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• 2022

Underground urbanization appears to be a promising solution in response to the shortage of construction sites in the above-ground space. In this context, an accurate evaluation of a construction site ensures the long-term performance of geosystems. This study characterizes potential sites for complex plants built in underground space using geophysical methods (i.e., seismic refraction exploration and electrical resistivity survey) and in situ tests (i.e., standard penetration tests (SPTs) and downhole tests). SPTs are conducted in nine boreholes BH-1-BH-9 to estimate the groundwater level and vertical distribution of geological structures. The seismic refraction method enables us to obtain the elastic wave velocity and thickness of each soil layer for each cross-sectional area. An electrical resistivity survey conducted using the dipole array method provides the electrical resistivity profiles of the cross-sectional area. Data obtained using geophysical techniques are used to assess the classification of the soil layer and bedrock, particularly the fracture zone. This study suggests that geotechnical information using in situ tests and geophysical methods are useful references to design an underground complex plant construction.

• Journal of Space Technology and Applications
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• v.2 no.1
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• pp.41-51
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• 2022

CubeSat is a satellite platform that is widely used not only for earth observation but also for space exploration. CubeSat is also used in magnetic field investigation missions to observe space physics phenomena with various shape configurations of magnetometer instrument unit. In case of magnetic field measurement, the magnetometer instrument should be far away from the satellite body to minimize the magnetic disturbances from satellites. But the accommodation setting of the magnetometer instrument is limited due to the volume constraint of small satellites like a CubeSat. In this paper, we investigated that the magnetic field interference generated by the cube satellite was analyzed how much it can affect the reliability of magnetic field measurement. For this analysis, we used a reaction wheel and Torque rods which have relatively high-power consumption as major noise sources. The magnetic dipole moment of these parts was derived by the data sheet of the manufacturer. We have been confirmed that the effect of the residual moment of the magnetic torque located in the middle of the 3U cube satellite can reach 36,000 nT from the outermost end of the body of the CubeSat in a space without an external magnetic field. In the case of accurate magnetic field measurements of less than 1 nT, we found that the magnetometer should be at least 0.6 m away from the CubeSat body. We expect that this analysis method will be an important role of a magnetic cleanliness analysis when designing a CubeSat to carry out a magnetic field measurement.

• The Journal of the Acoustical Society of Korea
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• v.41 no.3
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• pp.268-277
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• 2022

In this study, each component of flow noise source of underwater propeller installed to the scale model of the KVLCC2 is investigated and the effect of each noise source on underwater-radiated noise is quantitatively analyzed. The computation domain is set to be the same as the test section of the large cavitation tunnel in the Korea Research Institute of Ship and Ocean Engineering. First, for the high-resolution computation of flow field which is noise source region, the incompressible multiphase Delayed Detached Eddy Simulation is performed. Based on flow simulation results, the Ffowcs Williams and Hawkings integral equation is used to predict underwater-radiated noise and its validity is confirmed through the comparison with the tunnel experiment result. For the quantitative comparison on the contribution of each noise source, the spectral levels of sound pressure and power levels predicted using propeller tip-vortex cavitation, blade surface and rudder surface as the integral region of noise sources are investigated. It is confirmed that the cavitation which is monopole noise source significantly contributed to the underwater-radiated noise than propeller blades and rudder which is dipole noise source, and the rudder have more contribution than propeller blades due to the influence of the propeller wake.