• Korean Journal of Materials Research
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• v.5 no.4
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• pp.405-411
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• 1995

급냉응고된 Al-3.51wt%Li-0.34wt%Zr 합금의 시효거동을 시차주사열량계(DSC)에 의한 열분석 방법으로 조사하였다. DSC에 의한 비열측정 결과 $\delta$’의 석출에 의한 발열반응과 $\delta$, $\beta$ 및 복합석출상의 석출에 의한 발열반응을 확인하였으며 $\delta$’ 및 $\delta$의 재고용에 의한 2개의 흡열반응을 확인하였다. 7$0^{\circ}C$ 저온시효시 $\delta$’의 석출에 의한 발열반응 이전에 흡열반응이 나타났으며 이것은 $\delta$’ 석출 이전에 $\delta$’ 전구생성물이 형성되었음을 의미한다. DSC 곡선상에 나타난 발열과 흡열곡선을 해석하여 얻은 $\delta$’상 석출과 재고용의 활성화에너지값은 각각 83KJ/mol과 98KJ/mol로서 Al-Li 2원계 및 Al-Li-Mg에 비해 높은 값을 나타내엇으며, 시효에 의한 강화가 일어나 DSC에 의한 비열변화 조사결과 나타난 $\delta$’상 석출 완료 시효조건점 (21$0^{\circ}C$, 1시간)에서 최고경도값(Hv 160)을 나타내었다.

• Journal of the Society of Disaster Information
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• v.10 no.1
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• pp.71-83
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• 2014

This study carried out an experiment in order to compare thermal characteristics after collecting dust generated in the process of disposing of waste tire, plywood flour in the process of manufacturing plywood, salicylic acid dust in the process of manufacturing functional soap, and dust in the process of manufacturing wheat powder, which has potential fire and explosion hazard. According to the results of experiment, the analysis showed that all samples subject to the experiment were in the condition where heat flux decreased and temperature decreased as the quantity of added talc was increased. This shows that decomposition rate decreased, and hazard decreased. However, in all of samples subject to the experiment, as heating rate increased, endothermic onset temperature moved to the low-temperature part, and the amount of absorbed heat was largely increased. This showed that the decomposition hazard of sample increased as heating rate increased, according to the analysis. Besides, TGA experiment results showed that thermal stability was secured because total weight loss decreased as the amount of talc was increased for all samples subject to the experiment regarding the ratio of weight loss. It is expected that the continuous research and supplementation of dust explosion mechanism in the future will contribute to the establishment of measures for the effective dust explosion prevention.

• Applied Biological Chemistry
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• v.20 no.1
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• pp.117-122
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• 1977

Development of new burning additives against nitrate salts used in past tobacco industry examined to reduce harmful nitrogenous compounds in smoke. Among several additives treated, the best effect by means of elevation of combustibility and reduction of tar and nicotin contents in smoke was observed by adding sodium citrate from 0.6 to 1% in tabacco. The following results were obtained through investigating combustibility, chemical composition, and differential thermal analysis of the tabacco treated with the buring additives. 1) The close relation was observed between the levels of the smoke components and combustibility of the treated tabacco. 2) Differential thermal analysis (D.T.A.) of citrate-treated tobacco shows an increase in H. Value and a decrease in L. Value as compared with other tobacco sample. 3) The D.T.A. of sodium-nitrate and sodium-citrate shows that sodium-nitrate gives endothermal reaction at $270^{\circ}$ and $310^{\circ}$ and sodium citrate gives exothermal reaction at $290^{\circ}$ with endothermal reaction at $170^{\circ}\;and\;310^{\circ}$. 4) $Na_3-citrate-treated$ tobacco shows an increase in smoke generation between room temperature and $350^{\circ}$ (Zone A) and a decrease in smoke generation between $350^{\circ}$ and $900^{\circ}$ (Zone B) compared with untreated tobacco. The smoke from these tobacco also contains lower levels of Tar, Nicotine, Phenols, Nitrogen oxides and Benzpyrene, and elevation of static Burning rate.

• Applied Chemistry for Engineering
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• v.20 no.3
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• pp.266-272
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• 2009

Physical and chemical properties of waste LCD glass were investigated to test the feasibility of feed materials for the production of foamed glass. For this study, chemical analysis, thermal analysis, rheological consideration with the viscosity change under high temperature and thermal expansion coefficient were carried out and the trial production of foamed glass as; in spherical and block type also attempted. All results showed waste LCD glass would be a good feed material for the production of foamed glass and foaming technology of LCD glass would be an effective recycling alternative.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.7 no.3
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• pp.400-405
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• 1997

Lead scandium niobate powders were prepared by a molten salt synthesis method using KCl as a flux. Variations in phase formation and particle morphology were investigated for the temperature range $700^{\circ}C$ to $850^{\circ}C$. Pure $Pb(Sc_{1/2}Nb_{1/2})O_3$ perovskite phase was formed at $850^{\circ}C$ after 2hrs and the average particle size of powder was below 0.5 $\mu\textrm{m}$. The results are discussed with respect to DTA, X-ray diffraction, and microstructural characterization data.

• Electrical & Electronic Materials
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• v.8 no.1
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• pp.95-101
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• 1995

Crystallizable glasses with precipitation of celsian, anorthite, wollastonite and gahnite were prepared for the purpose of insulating dielectric layers in devices such as integrated circuit substrates. The starting glasses were prepared by melting the batches for 1 hour at 1450.deg. C and then Quenching to a distilled water. And crystallization behavior of these glasses were studied by DTA, TMA, XRD analysis and by the measurement of dielectric properties. The overall composition of the glass-ceramic consists in weight percent of 30-35% A1$_{2}$O$_{3}$, 13-26% BaO, 5-21% CaO, 10-24% ZnO, 4.5-9.0% TiO$_{2}$ and 4-8% B$_{2}$O$_{3}$. As a result, in barium-rich glasses only celsian phase was developed in the range of 850-900.deg. C. Also, the thermal expansion coefficient, dielectric constant and quality factor of these glass-ceramics were 68*10$^{-7}$ /.deg. C, about 9 and more than 1000, respectively.

• Journal of the Mineralogical Society of Korea
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• v.4 no.1
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• pp.1-10
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• 1991

Tosudite from the Sungsan mine, Korea is an alteration product of rhyolitic tuff in the cretaceous Hwangsan Formation. It is associated with illite, dickite, nacrite or quartz and also found in the cavities of black claystone. X-ray diffraction and chemical analyses show that the Sungsan tosudite is a lithium-bearing aluminous 1:1 regularly interstratified mineral of di, dioctahedral chlorite and smectite. Its structural formula is $(K_{0.73}Na_{0.02}Ca_{0.07})(Si1_{13.23}Al_{2.77})(Li_{0.52}Mg_{0.08}Mn_{0.01)Fe^{3+}_{0.07}Al_{12.33})O_{40}(OH)_{20}$ and it suggests that Sungsan tosudite consists of regularly interstratified Li-donbassite and beidellite. DTA and TG curves as well as IR absorption data also support such a result. Temperature of formation of tosudite is inferred to be between $110{\circ}$ and $270{\circ}C$.

• Korean Journal of Mineralogy and Petrology
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• v.35 no.2
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• pp.141-151
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• 2022

The 16 natural zeolites collected from Mongolia (6 types), the United States (1 type), and Korea (9 types) were characterized by XRD, XRF, TGA, DTA, and CEC analysis. All 16 samples are composite minerals. Two or more mineral phases co-exist and consist primarily of minerals such as clinoptilolite, heulandite, mordenite, and chabazite. In certain samples, minerals like illite and quartz were present as impurities. The XRF analysis showed that the 16 natural zeolites contain SiO₂, Al₂O₃, K₂O, CaO, Na₂O, MgO, and Fe₂O₃ oxides. The cation exchange capacity of the U-1 sample was 223.3 meg/100 g, which is higher than the rest of the samples. M-6 sample in Mongolian natural zeolite and K-1 sample in Korean natural zeolite showed the highest cation exchange capacity at 166.6 meg/100 g. As a result of thermal differential and thermos gravimetric analysis, all 16 samples showed excellent thermal stability up to 600℃.

• Journal of the Korean Ceramic Society
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• v.35 no.6
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• pp.640-646
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• 1998

Nucleation and crystallzation of a quaternary glass system for lead titanate glass-ceramics were in-vestigated using DTA(differential thermal analysis ) with variation of nucleation temperature and crystal growth time. Glass samples containing 60mol% of PbO-{{{{ { TiO}_{2 } }} were prepared from melts by the conventional normal cooling method in a cylindrical brass mould. The glass sample was nucleated between 40$0^{\circ}C$ and 50$0^{\circ}C$ for a given time and showed the maximum nucleation rate at 46$0^{\circ}C$ The DTA crystallization peak temperature decreased with increasing nucleating time and decreasing heating rate during DTA runs which indicated an increase of the number of nuclei produced in the system.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.3 no.2
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• pp.176-184
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• 1993

The glasses, which the $\beta$-spodumene as the principal crystalline phase could be precipitated, were melted by adding >, $P_2O_5, TiO_2, ZrO_2 in the Li_2O-Al_2O_3-SiO_2$ system. In order to achieve the glass-ceramic body of near-theoritical density by sintering method, the optimum condition of heat treatment, the effect of glass powder size and the properties were investigated by DTA, XRD, bulk density, thermal expansion and SEM. Addition of $P_20_5$ imProved the tendency of sintering and the sample with 9wt% $P_20_5$ content was the most dense OOdy by sintering method. The optimum condition of heat treatmemt was sintered for densitification at $740^{\circ}C$ and crystallized at $950^{\circ}C$. In the optimum condition, the relative density was above 90% and the thermal expansion was negative about $-1{\times}10^{-7}/^{\circ}C$.