• Geotechnical Engineering
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• v.14 no.6
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• pp.113-125
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• 1998

At the end of 1997 about 3 million tons of coal ash was produced as byproducts from the coal fired electrical power plants in Korea. Only about 27% of that byproducts was utilized as the admixtures of cement and concrete industry. But the large quantity of coal fired fly-ash has been used as the soil improvement materials in other countries. So the aim of this study is the estimation of the applicability of the coal fired fly-ash as microfine grouting materials by admixing the superfine particles which were separated from the coal fired fly-ash for the higher values. The 6 types of specimens were manufactured in the laboratory for the purpose of estimating the chemical and physical properties of cement and grouts. These specimens consisted of 2 specific surfaces of 6, 000 and 8, 000$cm^2$/g in Elaine method. And these specimens are devide into 3 ratios (30%, 50%, 70%) of fly-ash by weight. From the estimated properties of the coal fired fly-ash microflne cements and grouts, 50% fly-ash is the most suitable ratio for grouting materials. However, further study of durability is necessary for using fly-ash grouts practically at the field projects. The higher content of the unburned carbon of fly-ash increases the thinner layer of carbon on the surface of solution of grouts, and requires more quantity of surface active agent. As a results of this study, it is found that the microfine fly-ash is very useful as a good grouting material if 50% of fly-ash is added with the microfine portland cement. So, in the near future, if the coal fired fly-ash is able to be used as grouting material in Korea, the demand of fly-ash will increase rapidly.

• Journal of the Korea Concrete Institute
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• v.28 no.2
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• pp.205-212
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• 2016

This research investigates the influence of ground granulated blast furnace slag (GGBFS) composition on the alkali-activated slag cement (AASC). Aluminum oxide ($Al_2O_3$) was added to GGBFS binder between 2% and 16% by weight. The alkaline activators KOH (potassium hydroxide) was used and the water to binder ratio of 0.50. The strength development results indicate that increasing the amount of $Al_2O_3$ enhanced hydration. The 2M KOH + 16% $Al_2O_3$ and 4M KOH + 16% $Al_2O_3$ specimens had the highest strength, with an average of 30.8 MPa and 45.2 MPa, after curing for 28days. The strength at 28days of 2M KOH + 16% $Al_2O_3$ was 46% higher than that of 2M KOH (without $Al_2O_3$). Also, the strength at 28days of 4M KOH + 16% $Al_2O_3$ was 44% higher than that of 4M KOH (without $Al_2O_3$). Increase the $Al_2O_3$ contents of the binder results in the strength development at all curing ages. The incorporation of AASC tended to increases the ultrasonic pulse velocity (UPV) due to the similar effects of strength, but increasing the amount of $Al_2O_3$ adversely decreases the water absorption and porosity. Higher addition of $Al_2O_3$ in the specimens increases the Al/Ca and Al/Si in the hydrated products. SEM and EDX analyses show that the formation of much denser microstructures with $Al_2O_3$ addition.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.473-476
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• 2008

Due to the pursuit of high function and international price increase in the field of construction, the application of the secondary product using cement is on the increase gradually in the construction industry in the pursuit of economic cost reduction by the shortening of the construction time like Expediting and the dry construction method at the same time. However, it is in very urgent situation of measures to improve the structural performance or durable performance because it is limited for use in terms of panel in interior exterior building or functional repair reinforce as yet. Accordingly, this study is to investigate applicability of permanent Formwork like mould with the structural performance or excellent durable performance in the field of construction, and to derive optimum mixture in the performance and quality of manufacture. As a result of analysis comparison with the dynamic and durable properties of vacuum extrusion molding high toughness cement panel according to the mixture of four conditions, this study has found that the test body of mixing ECC-DP3 using small filler and large granulated blast furnace slag and powder flame retardant had excellent relative hardness and bending stress strain. The durable performance has shown excellent tendency by the decrease of porosity and enhancement of water-tightness.

• Journal of the Korean Ceramic Society
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• v.42 no.3 s.274
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• pp.182-187
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• 2005

There are many kinds of polycarboxylate superplasticizer as a functional classification which are introduced to domestic; Water Reducer, Retention, Ultra High Strength Superplasicizer. These are showed different physical behaviors because of the difference in the chemical system and the manners after cement mixing. In the case of water reducer, when $1.2\% of cement weight used, water reducing which is over $30\% is observed, but it take with segregation and the reduction of slump flow shows over 30 cm after 45 min of concrete produce. In the case of retention, when the same quantity used, water reducing which is about $25\% is observed and slump flow which is up to 45 min shows under 15 cm. And in the case of ultra high strength, when $1.2\% of cement weight used, water reducing which is over $30\% is observed, and slump flow which is up to 45 min recorded fewer than 15 cm. Compressive strength of ultra high strength superplasticizer has take effect of early age strength, and in the condition of specific mixing, 18 h-compressive strength is insured for more than $60\;Kgf/cm^2$ and 24 h-compressive strength is insured for more than $80\;Kgf/cm^2$.

• Journal of the Korean Ceramic Society
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• v.40 no.8
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• pp.804-810
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• 2003

The fine powder produced by heating and grinding of the waste concrete in the waste construction was investigated whether utilize as substitution raw material of SiO$_2$, CaO, and Al$_2$O$_3$ source for OPC clinker manufacture is possible or not. In order to synthesize OPC clinker, limestone, shale, converter slag and fly ash were used as main raw materials, and modulus was fixed LSF 91.0, SM 2.60, IM 1.60. The synthesized clinkers were characterized. The Main products of synthesized clinker were C$_3$S, ${\beta}$-C$_2$S, C$_3$A, C$_4$AF as OPC clinker at 1,43$^{\circ}C$. As a result of TG-DTA and burnability index(B.U) analysis of each raw mixtures, the formation temperature of clinker phases was similar and B.I was showed easy burning as 48.6∼51.4.

• Journal of the Society of Disaster Information
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• v.10 no.3
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• pp.432-441
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• 2014

The purpose of this research is to investigate characteristics of lathe scrap for manufacturing fiber reinforced cementitious composites(FRCCs) to use lathe scrap as a alternative materials of steel fiber. It should be noted that the use of the lathe scrap for making FRCCs raised friendly environmental effect as well as economy because the lathe scrap was a by-product of steel manufactures. For this purpose, various steel scraps were collected from processing plants of metal and then their physical properties were evaluated. Also, steel scraps were classified and analyzed according to the KS D 2101 and then of these scraps, lathe scrap as a alternative materials of steel fiber was suggested. In addition, FRCCs containing lathe scraps were made according to their total volume fractions of 0.0, 0.5, 1.0, 1.5, and 2.0% for water-binder ratios of 30%, 40%, respectively, and then characteristics, such as the workability, compressive strength, and flexural strength of those were evaluated. It was observed from the test result that the compressive strengths at 7 and 28 days of FRCCs containing lathe scrap were slightly small but the flexural strengths at 28 days of those increased by 10% compared with plain concrete.

• Journal of the Korea Concrete Institute
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• v.29 no.1
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• pp.65-75
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• 2017

C-S-H phase is the most abundant reaction product, occupying about 50~60% of cement paste volume. The phase is also responsible for most of engineering properties of cement paste. This is not because it is intrinsically strong or stable, but because it forms a continuous layer that binds together the original cement particles into a cohesive whole. The binding ability of C-S-H phase arises from its nanometer-level structure. In terms of chloride penetration in concrete, C-S-H phase is known to adsorb chloride ions, however, its mechanism is very complicated and still not clear. The purpose of this study is to examine the interaction between chloride ions and C-S-H phase with various Ca/Si ratios and identify the adsorption mechanism. C-S-H phase can absorb chloride ions with 3 steps. In the C-S-H phase with low Ca/Si ratios, momentary physical adsorption could not be expected. Physical adsorption is strongly dependent on electro-kinetic interaction between surface area of C-S-H phase and chloride ions. For C-S-H phase with high Ca/Si ratio, electrical kinetic interaction was strongly activated and the amount of surface complexation increased. However, chemical adsorption could not be activated for C-S-H phase with high Ca/Si ratio. The reason can be explained in such a speculation that chloride ions cannot be penetrated and adsorbed chemically. Thus, the maximum chloride adsorption capacity was obtained from the C-S-H phase with a 1.50 Ca/Si ratio.

• Journal of the Korea Concrete Institute
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• v.17 no.2 s.86
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• pp.263-271
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• 2005

HPFRCC(High Performance Fiber Reinforced Cementitious Composite) is a class of FRCCs(Fiber Reinforced Cementitious Composites) that exhibit multiple cracking. Multiple cracking leads to improvement in properties such as ductility, toughness, fracture energy, strain hardening, strain capacity, and deformation capacity under tension, compression, and bending. These improved properties of HPFRCCs have triggered unique and versatile structural applications, including damage reduction, damage tolerance, energy absorption, crack distribution, deformation compatibility, and delamination resistance. These mechanical properties of HPFRCCs become different from the kinds and shapes of used fiber, and it is known that the effective size of fiber in macro crack is different from that in micro crack. This paper reports an experimental findings on the mechanical properties of HPFRCCs reinforced with the micro fiber(PP50, PVA100 and PVA200) and macro fiber(PVA660, SF500). Uniaxial compressive tests and three point bending tests are carried out in order to compare with the mechanical properties of HPFRCCs reinforced with micro fibers or hybrid fibers such as compressive strength, ultimate bending stress, toughness, deformation capacity and crack pattern under bending, etc.,

• Journal of the Korean Recycled Construction Resources Institute
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• v.8 no.2
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• pp.235-244
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• 2020

This study conducted a series of studies to offer a novel method of using CBS-dust that produced as by-product in the manufacture of cement. Four different contents of BS and CBS-dust were adopted for test parameters of this study. Mortar with 50% of W/B was fabricated. First, in the case of the fresh mortar, the flow decreased as the CBS-dust replacement rate increased, but the binder composition ratio BS 45% and 65% showed higher fl ow than Pl ain when repl acing CBS-dust 5%. In the case of air content, overall, the tendency was proportional to the CBS-dust replacement rate, and chloride tended to exceed the reference value at all replacement rates except for the CBS-dust 0% replacement. The compressive strength of the hardened mortar shows the resul t that the strength is improved when the CBS-dust is repl aced by 5% to 10%, and the CSH gel and structure formation is confirmed by microstructure analysis through the hydration reaction when the CBS-dust is replaced. Therefore, for a given condition CBS-dust is used as a early-strength admixture in a concrete secondary product that uses a large amount of admixture without reinforcing bars it can be an effective method for enhancing the strength of concrete as an alkali activator.

• Journal of the Korea institute for structural maintenance and inspection
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• v.14 no.5
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• pp.144-152
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• 2010

In this study, cement-based filler is used as an adhesive instead of organic adhesive, epoxy because there were problems under wet condition. First, the bond strength of cement-based filler was measured and the result was satisfied with KS F 4716. However, in case of wet condition, bond strength of epoxy adhesive decreased $0.73N/mm^2$ in 7 days and $0.84N/mm^2$ in 14 days from pilot test. This implies that there would be a problem on reinforced concrete structure in wet condition, such as tunnel and sewage box. In the second experiment, the flexural strength of RC beams with GFRP using different thickness of cement-based filler was investigated, and the result was indicated 113%, 66%, 75% increase in 10mm, 20mm, 30mm thickness, respectively. From the result, it was known that 10mm filler thickness produces stable bond performance.