• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.1
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• pp.1-8
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• 2023

In this study, to reduce CO₂ emission in the cement manufacturing process, we evaluated the limestone that is used as a raw material for cement, substituted with steel slag by the various substituted levels. Based on the chemical composition of each raw materials including limestone, and blast furnace slow cooling slag, converter slag, and KR slag as an alternative raw material, we simulated the optimal cement raw mixture by the substitution levels of limestone. Test results indicated that the steel slags contain a certain level of CaO that can be used as alternative decarbonated raw materials, and it has enough to partially reduce the amount of limestonem. And we estimated the maximum usable levels of each raw material. In particular, it was confirmed that by using a mixture of these raw materials rather than using them one by one, the effect of reducing limestone was increased and CO₂ emission from the cement manufacturing process could be reduced.

• Ceramist
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• v.20 no.1
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• pp.103-118
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• 2017

1. 2014년도 우리나라 전체 폐기물 발생량은 146,607천 톤이며, 건설폐기물이 46.2%(67,644천 톤), 사업장 일반폐기물이 38.1%(55,914천 톤), 생활폐기물이 12.4%(18,219천 톤), 사업장 지정페기물이 3.3%(48,810천 톤)을 나타내고 있다. 2. 건설폐기물의 97.9%, 배출시설계 폐기물의 77.3%, 생활폐기물의 67.0%, 지정폐기물의 57.3%가 재활용되고 있다. 3. 2015년도 우리나라 시멘트산업에서 18,801천 톤의 순환자원을 재활용하였다. 폐기물이 6,136천 톤이고, 부산물이 12,665천 톤이다. 부산물은 11,000천톤이 제철슬래그이고, 1,600천 톤이 폐석고(탈황석고 중화석고)로 추정된다. 그리고 폐기물 6,136천 톤은 사업장 일반폐기물의 약 11.0%에 해당된다. 4. 시멘트 톤당 순환자원 사용량(재활용 원단위)은 일본이 400kg/톤 이상이고 우리나라는 300kg/톤 대를 나타내고 있다. 일본이 우리나라보다 재활용량/톤이 많은 이유를 다음에서 찾을 수 있다. (1) 고품위 석회석 원료 (2) 법 제도(지원금 포함) 5. 원료 대체율의 산출은 다음 두 산출방법으로 나타낼수 있다. (1) 이론적인 원료 상한 대체량에 대한 실제 원료 대체량 (2) 이론적인 원료 조합량에 대한 실제 원료 대체량 2015년도 우리날 전체 원료 대체량(17,770천 톤)은 (1)에 의한 대체율 : 71% (2)에 의한 대체율 : 27% 6. 자동차 슈레더 더스트(ASR)를 시멘트산업에서 자원화 하게끔 ASR처리의 보완 및 법적지원(지원금 포함)이 요망된다. 7. 부산물 및 폐기물의 자원화는 시멘트산업에서의 이용이 가장 우수한 장점을 갖추고 있다. 그러므로 시멘트산업에서 폐기물의 자원화를 적극 추진하게끔 제도의 보완 및 시설지원 등 정부의 대책수립이 간절하다.

• Cement Symposium
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• s.33
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• pp.131-140
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• 2006

• Cement Symposium
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• s.49
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• pp.27-28
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• 2022

The cement industry emits a large amount of CO₂, and 60~65% of the CO₂ is generated from calcination of raw materials. So, the CO₂ from cement industry can be reduced by substituting decarbonated materials for limestone. In this study, the chemical composition and grindability of three types of steel slag were evaluated and the application of those materials will be examined for the production of low heat portland cement.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.549-552
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• 2008

The cement is accomplished with CaO, SiO2, Al2O3 and Fe2O3, etc. After pulverizing materials of the limestone, the sand and the clay(shale), iron ore, the cement becomes clinker materials sintering from the rotary kiln of oxidizing atmosphere. The part in the materials of the clinker is substituted with slag, sludge etc. and it is used. because The chromium which is to be included in the clinker materials, in sintering process hexavalent chromium is converted with the chrome. Consequently it changed the type and a content of clinker materials and test hexavalent chromium of the clinkers which is manufactured.

• Clean Technology
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• v.6 no.1
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• pp.61-69
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• 2000

In this study, generation process and properties of inorganic industrial waste which can be used in cement industry were investigated. The scheme of recycling to use the selected waste as raw materials, mineralizer and flux, admixture and raw materials for special cement was decided and then various experiments were carried out. The experimental results were as follows ; In the use of industrial waste as raw materials, ferrous materials could be substituted by Cu-slag, Zn-slag, electric arc furnace or convertor furnace slag etc., and a siliceous material could be substituted by sand from cast-iron industry. By-products from sugar or fertilizer industry, which has $CaF_2$ as the main component, and jarosite from Zn refinery enabled clinker phases to be formed at lower temperature by $100{\sim}150^{\circ}C$. Adding Cu slag and STS sludge in proper proportion to cement improved properties of cement. Fly ash and limestone powder as admixture had the same effect on cement. As a raw material for special cement, aluminium waste sludge could be used in making ultra early strength cement, which had the compressive strength of $300kg/cm^2$ within 2hours. And two different ashes from municipal incinerator could be raw materials of the cement which was mainly composed of $C_3S$ and $C_{11}A_7{\cdot}CaCl_2$ as clinker phases.

• Cement Symposium
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• s.49
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• pp.25-26
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• 2022

Coal ash generated from thermal power plants has been used as alternative raw material for cement production. But when using buried coal ash, careful attention is needed because it contains some amount of moisture and chlorides which can cause problems in production process. In this project, cement production process and quality control technology for using buried coal ash as cement raw material has been being developed.

• Cement
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• s.44
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• pp.39-52
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• 1971

• Cement Symposium
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• no.4
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• pp.46-52
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• 1976

• Cement
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• s.59
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• pp.39-49
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• 1975