• Title/Summary/Keyword: 시멘트 수화

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Geochemical Modelling of the Effect of Calcite and Gypsum on the Hydration of Cements (방해석 및 석고가 시멘트 수화과정에 미치는 영향에 대한 지구화학 모델링 연구)

  • Ryu, Ji-Hun;Kim, Geon-Young;Koh, Yong-Kwon;Choi, Jong-Won
    • Journal of the Mineralogical Society of Korea
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    • v.23 no.2
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    • pp.151-159
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    • 2010
  • The effect of calcite and gypsum on the hydration of Portland cement was investigated using GEM-PSI, a geochemical model. Addition of calcite and gypsum up to 5 wt% of total cement clinker into Portland cement was found to influence the hydrate assemblage of the hydrated cement in different ways. The results of geochemical modelling showed that the fraction of calcium monocarbonate increased by the hydration of cement with the increase of calcite addition. The results of modelling also indicated that gypsum increased the fraction of ettringite in the assemblage of hydrated cement as the amount of gypsum added increases. This study showed that porosity generated by the hydration of cement had a significant relation with the amount of calcite and gypsum added. The porosity of hydrated cement was lower when calcite added up to 3 wt% of cement clinker compared to the hydrated cement with the same amount of gypsum addition. However, when calcite added more than 3% of cement clinker, the porosity of hydrated cement were higher than that of hydrated cement with the same amount of gypsum addition.

Development activator for physical properties of slag Cement (슬래그 시멘트의 물성제어를 위한 활성화제 개발)

  • Park, Nam-Kyu;Lee, Jong-Kyu;Chu, Yong-Sik;Song, Hun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.545-548
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    • 2008
  • In this study aluminium sulfate, Ca(OH)$_2$, K-R Slag and $Na_2SO_4$ were used as active admixtures and their concentration 1, 3, 5, 7 weight percent in cement. The physical properties of active admixtures cement mortar were investigated by flow test and compressive strength. It was found that the resulting active admixtures exhibited the higher compressive strength than OPC mortar up. From the test results, cement mortars added active admixture have a good fundamental property.

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Hydration Characteristics of Cement Containing Zeolite (제올라이트가 함유된 시멘트의 수화 특성)

  • Lee, Chang-Yong;Kim, Youn Cheol;Lee, Jong-Jib
    • Applied Chemistry for Engineering
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    • v.22 no.4
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    • pp.423-428
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    • 2011
  • Hydration characteristics of cement containing zeolite mined at Daepo in Gyeongbuk province were studied for use as a mineral admixture. The cement paste containing zeolite was characterized by the measurement of heat evolution, XRD, EDS, nitrogen adsorption and mercury intrusion porosimetry. The cement paste containing zeolite exhibited tendencies toward acceleration of paste setting and promotion of cement hydration with the increase of zeolite content. The flow of mortar containing zeolite strongly reduced with increase of zeolite content. Compressive strength of the mortar containing zeolite increased very rapidly at an early age in comparison with plain mortar. These results would be related to aluminum species escaped from zeolite particles during the alkali dealumination of zeolite by the hydration process of cement.

The Degree of Hydration and Mechanical Properties of High Volume Fly Ash Cement (하이볼륨 플라이애시 시멘트의 수화도 및 역학적 특성)

  • Cha, Soo-Won;Choi, Young-Cheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.5
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    • pp.95-102
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    • 2022
  • Recently, there has been a growing interest in reducing greenhouse gases in all industrial fields. In the construction industry, studies have been conducted for the use of high-volume fly ash concrete to replace cement with fly ash. Quantitative measurements of cement hydration and fly ash reactivity enable a clear understanding of the strength development mechanism of high-volume fly ash concrete. It is very difficult to describe the reactivity in a simple way because the hydration and pozzolanic reactions of cement paste containing fly ash are very complex and the composition of the hydration product cannot be accurately determined. This study investigated the hydration and mechanical properties of high volume fly ash (HVFA) cement according to the substitution rate of fly ash (FA). The hydration degree of cement and the reactivity of FA were evaluated through the selective dissolution method and the non-evaporable water content of the paste according to age. In addition, compressive strength was measured using HVFA mortar specimens according to age. As a result of the experiment, as the substitution rate of fly ash increased, the hydration degree of cement increased, but the reactivity of FA decreased.

Effects of the Organic Fatty Acid Salts on the Watertightness Properties of the Cementitious Materials (시멘트 재료의 수밀특성에 미치는 유기 지방산 염의 영향)

  • Na, Seung-Hyun;Kang, Hyun-Ju;Ahn, Kwang-Hoon;Song, Myong-Shin
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.529-532
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    • 2008
  • The durability of concrete and the water-tightness properties of cementitous material are closely relation. So, water-tightness materials as natural minerals, organic fatty acid, organic fatty salts inorganic materials use for improvement of concrete durability. But these materials are somehow different in water-tightness mechanism. In this study, we studied on hydration properties and water-tightness properties of cementitous materials with zinc-stearate, a kind of organic fatty acid salts.

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