• Journal of the Korea Institute of Building Construction
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• v.20 no.1
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• pp.1-9
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• 2020

Chloride ion, which penetrates into the cement composites from the outside, generally diffuses by the concentration gradient. Chloride ions are adsorbed by the chemical reaction with cement hydrates. Recent studies have shown that anion exchange resin (AER) powder can effectively adsorb the chloride ion in the cement composites, and thus, the cement composites containing AER have a high chloride adsorption capacity and a good resistance for chloride penetration. In this study, the chloride adsorption ability of the AER powder was investigated under the conditions of distilled water and calcium hydroxide saturated solution to determine if the AER powder is less effective to increase the chloride adsorption ability after grinding process. The chloride adsorption ability of AER powder was compared with the previous research about the chloride adsorption of AER bead. In addition, the compressive strength, chloride diffusion coefficient (using NT Build 492 method), and the chloride profile of cement mortar substituted with AER powder were investigated. There was no decrease in the chloride adsorption capacity of AER powder but increase in the kinetic property for chloride adsorption after the grinding process. The AER powder could absorb the chloride ion in the mortar quickly, and showed better chloride ion adsorption ability than the cement hydrates.

• Polymer(Korea)
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• v.36 no.2
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• pp.216-222
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• 2012

We synthesized microcapsule absorbent with crosslinked poly(styrene-$alt$-maleic anhydride) (PSMA) as a core and PSMA as a shell by a precipitation polymerization method for the delayed absorption of excess water in cement mortar. cPSMA-PSMAs with core-shell structure were synthesized with ratios of 1/1, 1/2 and 1/3 as core monomer mass to shell monomer mass to control shell thickness. We observed the hydrolysis of PSMA in cement-saturated aqueous solution by a FTIR spectrometer. We observed good core-shell structure microcapsules for 1/2(cPSMA #3), but observed incomplete core-shell structure for 1/1(cPSMA #2) and 1/3(cPSMA #4) of core/shell monomer ratios. The swelling ratio of cPSMA #3 in cement-saturated aqueous solution was increased until 20 min. After that it was decreased until 2 hrs swelling time, and they started to increase again. The viscosities of cement paste with cPSMA #3 microcapsules were very slowly increased until 1 hr and increased fast after 1.5 hrs. Cement mortar with 0.5 wt% cPSMA #1 having only core part showed about 5% increase in compressive strength compared to that of plain cement mortar. cPSMA #3 added cement mortar showed the highest compressive strength with 7% increase.

• Journal of the Korean Recycled Construction Resources Institute
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• v.3 no.2
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• pp.132-139
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• 2015

In this study, the different unit cement content by the ratio of water absorption and water-cement ratio are applied to examine the properties of the concrete used the aggregate recycled by the crushing treatment. According to the experimental results, in the mix of low strength and high water-cement ratio, both of the compressive strength is almost equal in the concrete using the recycled aggregate by the crushing treatment and the concrete using broken stones. It means that the recycled aggregate has the low effect of the amount of bonded mortar. But, in the mix of high strength and low water-cement ratio, the concrete using the recycled aggregate by the crushing treatment has 40% less of the compressive strength than that using broken stones by the effect of the amount of bonded mortar. On the other hand, after 8 weeks, the dry shrinkage of the recycled aggregate with 7% of the ratio of water absorption doubles that of the broken stones with 1% ($-350{\times}10^{-6}$), in other words $-700{\times}10^{-6}$. Thus, the dry shrinkage should be prior to any other conditions in recycling waste concrete for the aggregate for concrete. When the recycled aggregate with 3% of the ratio of water absorption is used, the compressive strength of the rich mix concrete ($450kg/m^3$ of the unit cement content) is equivalent to that of the concrete using broken stones, while in using the recycled aggregate with 7% of the ratio of water absorption, the rich mix concrete has 7% lower compressive strength than the concrete using broken stones. But, the compressive strength of the ordinary mix concrete ($350kg/m^3$ of the unit cement content) is far lower than that using broken stones.

• Journal of the Korea Institute of Building Construction
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• v.17 no.3
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• pp.227-234
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• 2017

This research analyzes the properties of mortar following the rise in water-cement ratio and applicability as an eco-friendly construction supply by using the mudflats of a dredged arena as a substitute for aggregate. The results of a experiment of the flow showed that the flow value decreases as the amount of mudflats increases. A test for chloride content showed that the chloride content increases with the amount of mudflats. In the compression of specimen mixed with mudflat and the testing of tensile strength, the strength weakened as the addition ratio of mudflats rose. However, with 14-day strength as the standard, most specimen showed more strength than the plain, and 14-day strength was higher than 28-day strength. It appears to be experimental error in the mixing process from the viscosity and cohesion of mudflats, and it is considered that there will be a need for an experiment on mixing methods of mudflats in the future. The compressive strength of this research was the strongest with 70% in water-cement ratio, and the tensile strength was strongest with 80% in water-cement ratio. In the evaluation of surface analysis, 70% water-cement ratio, which is finest in strength, mixing, and compactness, was selected to analyze the roughness of the surface, and the results showed that the surface became smoother as the addition ratio of mudflats increases. In conclusion, it appears that 70% water-cement ratio is the optimal mixing ratio for mortar and 10 to 30% addition ratio of mudflats the optimal ratio. It also appears that the application of interior finishing material like bricks and tiles and interior plastering material using the mudflats are possible.

• Journal of the Korea institute for structural maintenance and inspection
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• v.22 no.4
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• pp.10-18
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• 2018

The primary purposes of this study are to understand a fundamental aspect of current uniformity around a reinforcing bar (rebar) in cement mortar, and to develop an accurate monitoring method in a wet-dry cycling process with the alternative current (AC) impedance method. Three cement mortar specimens with two embedded rebars were prepared in the laboratory. As a main variable, the distance between two rebars was designed to be 10, 20 and 30 mm with the same thickness of 20 mm. To simulate the corrosion of rebars in concrete structures in a marine environment, three cement mortar specimens were exposed to 15 wet-drying cycles (24-hour-immersion in seawater and 48-hour-drying in a room temperature) in the laboratory. It was observed that the potential level shifted to a noble value during corrosion potential monitoring, which is attributed to acceleration of dissolved oxygen diffusion at the drying process. AC impedance was measured in a frequency range from 100 kHz to 1 mHz on a wet-drying process. A theoretical model was proposed to explain the interface condition between the rebars and cement mortar by using the equivalent circuit consisting of a solution resistance, a charge transfer resistance and a CPE (constant phase element). It was observed that the diffusion impedance appeared in a low frequency range as corrosion of rebars progresses. At the drying stage of the wet-drying cycles, the currents line for monitoring tended to be non-uniform at the interface of rebar/mortar, being phase shift, ${\theta}$, close to $-45^{\circ}$.

• 한국석유지질학회:학술대회논문집
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• autumn
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• pp.30-30
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• 2000

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.613-616
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• 2008

Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. Instead, the source of material such as fly ash and blast slag, that are rich in Silicon(Si) and Aluminium(Al), are activated by alkaline liquids to produce the binder. Hence concrete with no cement is effect reduction of CO$_2$ gas. In this study, we investigated the influence of the workability and compressive strength of mortar on water reducing agent, alkaline activator and curing method in oder to develop cementless blast slag based alkali-activated mortar. In view of the results, we found out that the flowability of mortar was lowered as increasing to mole concentration of NaOH, but not large the loss of flowability to 9M NaOH, most of water reducing agent was not effect. The compressive strength was improved as increasing to mole concentration of NaOH, was the most effect in 9M NaOH. The curing temperature and curing conditions on compressive strength of blast slag based alkali-activated mortar didn't influence.

• Magazine of the Korea Concrete Institute
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• v.8 no.4
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• pp.161-169
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• 1996

Styrene-maleic anhydride copolymers with different composition (1:1SMA. 5:1SMA) were synthesized and further reacted with sulfuric acid to obtain water soluble copolymers (1:1SSMA, 5:1SSM.4). In the flow experiments of cement mortar mixed with copolymers, 5:1SSMA showed higher fluidity than 1:1SSMA. The cement mortar mixed with 1% 5:1SSMA maintained 95% of original flow after 60 min. On the other hand, the compressive strength of the hardened cement mortars containing 0.5% copolymers after 28 days curing was also examined. The compressive strength of hardened cement mortar containing 5:1SSMA was increased up to 41% compared to the plain while 1:1SSMA was increased up to 29%. As the results, the 5:1SSMA used in this study are greatly expected as a new high range water reducers for the concrete.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.4
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• pp.421-426
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• 2017

In this paper, the effect of freezing-thawing action on the dynamic modulus and porosity was examined by ultrasonic pulse velocity (UPV) measurement. UPV was measured every 30 cycles during the freezing-thawing test, and dynamic modulus and porosity of cement mortar were calculated by relationship among UPV, porosity and dynamic modulus. Porosity analysis was also performed to compare with calculated porosity by mercury intrusion porosimetry (MIP). From the test, it was found that dynamic modulus of cement mortar was decreased 13% after 300 cycles. The calculated porosity was increased about 30% compared with the initial porosity before freezing-thawing action. The calculated porosity showed similar increase tendency with the porosity measured by MIP. So, it can be concluded that the porosity change of cementitious materials by freezing-thawing action can be predicted by UPV measurement.

• Journal of the Korea Institute of Building Construction
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• v.11 no.6
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• pp.547-556
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• 2011

The primary factors affecting concrete sulfate resistance are the chemical composition of the Portland cement, and the chemistry and quantity of mineral admixtures. To investigate the effect of those on the sulfate attack, the testing program involved several different mortar mixes using the standardized test, ASTM C1012. Four different cements were evaluated, including one Type I cement, two Type I-II cements, and one Type V cement. Mortar mixes were also made with mineral admixtures, as each cement was combined with three different types of mineral admixtures. One Class F fly ash, one Class C fly ash, and one ground granulated blast furnace slag (GGBFS) were added in various percent volumetric replacement levels. Expansion measurements were taken and investigated with the expansion criteria recommended by ASTM.