• Title/Summary/Keyword: 시료 전처리

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Manufacture of Biodegradable Polymer with Wastepaper(I) - Pretreatment and Analysis of Chemical Components On Wastepaper - (폐지를 이용한 생분해성 고분자의 제조(I) - 폐지의 화학적 조성 분석 및 전처리 -)

  • Kwon, Ki-Hun;Lim, Bu-Kug;Yang, Jae-Kyung;Chang, Jun-Pok;Lee, Jong-Yoon
    • Journal of the Korean Wood Science and Technology
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    • v.28 no.3
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    • pp.34-41
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    • 2000
  • Recently many scientists have tried to synthesize biodegradable polymers due to durable and non-biodegradable products of conventional synthetic plastics when these were wasted in nature. So to reuse the wastepapers for biodegradable polymer resources, ONP (old newsprint), OCC (old corrugated containerbpard) were carried out by the pretreatment of chlorinite, hypochlorite and oxygen-alkali treatment conditions. For manufacturing of biodegradable polymer with wastepaper, this study performed to investigate change of chemical components and optimal pretreatment condition. The summarized results in this study were as follows: Lignin content in ONP and OCC was was higher than in MOW and ash content was the highest in MOW. More amount of ash components were reduced by wet defiberation than by dry defiberation. Wet defiberation fiber are better than dry defiberated fiber in chemical pretreatment condition for wastepapers, and the best result was obtained in the condition of sodium chlorite at $70^{\circ}C$, because it has high delignification ratio, ${\alpha}$-cellulose contents and degree of polymerization in this treatment condition. Oxygen-alkali treatment condition is the worst method because of low yield, low degree of polymerization in this pretreatments.

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Development of Surface Modified Tencel fabrics through the Control of Fibrillation(III) -Effect of DP Finishing Method and NaOH Pretreatment- (피브릴화 조절을 통한 다양한 감성의 텐셀소재 개발(제3보) -DP가공 방법 및 NaOH 전처리가 미치는 효과-)

  • Shin, Younsook;Son, Kyounghee
    • Journal of the Korean Society of Clothing and Textiles
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    • v.26 no.12
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    • pp.1749-1755
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    • 2002
  • 본연구의 목적은DP가공에 의한 가교화를 통해 텐셀의 피브릴화를 조절할 때 DP가공 방법 및 NaOH전처리 효과를 물성, 표면형태, 역학적 성질 및 태의 변화의 관점에서 고찰하는데 있다. SEM 분석결과DP가공에 의해 피브릴 발생 정도는 감소하였다. DP가공 방법에 있어 서 WF법과 PDC법에 따른 물성의 차이는 나타나지 않았다. 역학적특성의 경우 DP가공은 DP가공 방법에 상관없이 효소처리한 직물의 인장선형성에는 큰 영 향을 주지 않았으나 인장에 너지, 굽힘 강성, 압축선형성, 압축 레질리언스, 기하학적 거칠기는 감소시켰고 인장 레질리언스, 굽힘이력, 압축에너지는 증가시켰다. 전단특성은 WF법에서는 증가한 반면, PDC법에서는 감소하여 DP가공 방법에 따른 차이를 나타내었다. WF법이 PDC법보다 더 높은 Koshi, Numeri, Fukurami 값을 보였으며, 종합태 값은 비슷하게 나타났다. NaOH 전처 리에 의해 수지부착량은 감소하였으나 감량률은 증가하였으며, DP성/물성은 더 낮게 나타났다. NaOH 전처리에 의해 인장선형성, 인장에너지, 압축 레질리언스, 전단 및 굽힘특성은 증가하였으나 인장레질리언스와 압축선형성, 압축에너지, 표면특성은 감소하였다. NaOH 전처리한 경우 Koshi는 증가하였고, Numrei와 Fukuramil는 감소하였으며, 종합태 값은 가장 낮았다. 처리한 시료들은 각각 다른 감성과 촉감을 나타냈다.

Evaluating Spectral Preprocessing Methods for Visible and Near Infrared Reflectance Spectroscopy to Predict Soil Carbon and Nitrogen in Mountainous Areas (산지토양의 탄소와 질소 예측을 위한 가시 근적외선 분광반사특성 분석의 전처리 방법 비교)

  • Jeong, Gwanyong
    • Journal of the Korean Geographical Society
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    • v.51 no.4
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    • pp.509-523
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    • 2016
  • The soil prediction can provide quantitative soil information for sustainable mountainous ecosystem management. Visible near infrared spectroscopy, one of soil prediction methods, has been applied to predict several soil properties with effective costs, rapid and nondesctructive analysis, and satisfactory accuracy. Spectral preprocessing is a essential procedure to correct noisy spectra for visible near infrared spectroscopy. However, there are no attempts to evaluate various spectral preprocessing methods. We tested 5 different pretreatments, namely continuum removal, Savitzky-Golay filter, discrete wavelet transform, 1st derivative, and 2nd derivative to predict soil carbon(C) and nitrogen(N). Partial least squares regression was used for the prediction method. The total of 153 soil samples was split into 122 samples for calibration and 31 samples for validation. In the all range, absorption was increased with increasing C contents. Specifically, the visible region (650nm and 700nm) showed high values of the correlation coefficient with soil C and N contents. For spectral preprocessing methods, continuum removal had the highest prediction accuracy(Root Mean Square Error) for C(9.53mg/g) and N(0.79mg/g). Therefore, continuum removal was selected as the best preprocessing method. Additionally, there were no distinct differences between Savitzky-Golay filter and discrete wavelet transform for visual assessment and the methods showed similar validation results. According to the results, we also recommended Savitzky-Golay filter that is a simple pre-treatment with continuum removal.

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Blanching Effect on Quality Characteristics and Antioxidant Activities in Yacon Soaked in Doenjang Sauce (데침에 따른 야콘 된장절임의 항산화 활성 및 품질 변화)

  • Kim, Gi-Chang;Kim, Hye-Sun;Jo, In-Hee;Kim, Kyung-Mi;Kim, Jin-Sook
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.41 no.7
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    • pp.921-926
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    • 2012
  • The objective of this study was to investigate the quality characteristics of blanched and non-blanched yacon (Smallanthus sonchifolius) soaked in Doenjang sauce. The yacon was treated by blanching ($100^{\circ}C$, 4 min), then soaked in Doenjang sauce at $20^{\circ}C$. The pH and total acidity of blanched yacon were not changed significantly after 42 days of soaking. But, the pH and total acidity of non-blanched yacon were rapidly increased and decreased, respectively. The salinity of blanched yacon was higher than that of non-blanched yacon until 35 days. Also, the $Brix^{\circ}$ of blanched yacon was higher than that of non-blanched yacon from 7 days to 35 days. Textural properties of both non-blanched and blanched yacon showed that hardness increased until 21 days but decreased afterwards. The total polyphenol contents of non-blanched yacon decreased after 14 days, but blanched yacon remained constant. The DPPH radical scavenging activity of both blanched and non-blanched yacon decreased gradually as aging continued in the Doenjang sauce. There were no significant differences in sensory characteristics between blanched and non-blanched yacon soaked in Doenjang sauce.

Optimization the Xylose Fractionation Conditions of Pepper Stem with Dilute Sulfuric Acid (농업부산물 고추대 (Pepper Stem)을 이용한 묽은 황산 자일로즈 분별공정의 최적화)

  • Won, Kyung-Yoen;Oh, Kyeong-Keun
    • KSBB Journal
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    • v.24 no.4
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    • pp.361-366
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    • 2009
  • Response surface methodology (RSM) was used for optimization the fraction conditions of xylose from pepper stem with dilute sulfuric acid. The independent variables were acid concentration in the range of 1.134 to 2.866%, reaction temperatures in the range of 142.68 to $177.32^{\circ}C$, and hydrolysis time in the range of 6.34 to 23.66 min. were studied. The dependent variables were xylose yield from pepper stem, and the production of by-products, for example, furfural, acetic aicd, HMF etc. Experimental results had a good match with statistical result. The maximum xylose yield obtained in this experiment was 71% concentration.

Development of a pretreatment method for determination of levels of perfluorinated compounds in foods according to fat and protein contents (지방과 단백질 함량에 따른 식품의 과불화화합물 분석을 위한 전처리 방법 확립)

  • Bang, Sunah;Park, Na-youn;Hwang, Youngrim;Kang, Gil Jin;Kim, Hye-Jeong;Kang, Young-Woon;Kho, Younglim;Kim, Jung Hoan
    • Korean Journal of Food Science and Technology
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    • v.50 no.1
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    • pp.14-20
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    • 2018
  • Perfluorinated compounds (PFCs) have recently been recognized as global environmental pollutants. This study was performed to develop an analytical method for determination of levels of PFCs in food by LC-MS/MS. One hundred and nine food products were divided into two groups based on their fat and protein contents (high and low), following which samples containing high fat and protein contents were pooled and subjected to pretreatment consisting of enzymatic degradation and hexane extraction. The limit of detection of 17 PFCs in the samples were in the range of 0.013-0.145 ng/g. The degrees of precision of detection for group 1 (samples with low fat and protein contents) and group 2 (samples with high fat and protein contents) were 0.8-21.1 and 1.7-28.2%, respectively, with an accuracy of 78.8-109.8% for group 1 and 80-114.5% for group 2. This study indicated that pretreatment of high fat and protein foods with enzymatic degradation and hexane extraction would improve the detection of PFCs in food.

Antimicrobial and Antioxidant Activity of Protamine Prepared from Salmon Sperm (연어정자로부터 제조된 프로타민의 항균성 및 항산화성)

  • Joo, Dong-Sik;Cho, Soon-Yeong;Kang, Hyun-Joo;Jin, Deok-Hee;Lee, Chang-Ho
    • Korean Journal of Food Science and Technology
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    • v.32 no.4
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    • pp.902-907
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    • 2000
  • Protamine-strong basic protein was prepared from salmon(chum salmon, Oncorhynchus keta) sperm by several pretreatment method. And there were determined yield, amino acid composition, antimicrobial and antioxidant activity of protamine on each pretreatment condition. The yield of protamine was different according to pretreatment, and ultrasonicating, homogenizing and microwaving pretreatment were about 16.0%, 15.5% and 10%, respectively. The main amino acid of P60(microwaving pretreatment for 10 min at $80^{\circ}C$) and UU6(ultrasonicating pretreatment for 60 min at $20^{\circ}C$) were arginine, proline and tryptophan, and arginine content of P60 and UU6 were 61%, 53%, respectively. On the other hand, main amino acid of M(homogenizing pretreatment by mixer) were methionine, proline and arginine, the content were 34%, 28% and 11%, respectively. Also MC(homogenizing pretreatment with $H_{2}SO_{4}$ soln. by mixer) was very different with P60, UU6 and M, the content of MC were proline 44.8% and arginine 39.7%. Prepared protamines showed antimicrobial activity to several gram(+) and gram(-) strain. In particular, the UU6 and P60 protamine has strong antimicrobial activity to Bacillus subtilis and Escherichia coli, and the activity was increased with concentration increasing. Regardless of pretreatment method, all protamine showed antioxidant activity and the $EDA_{50}$ of P60, UU6, M and MC were $101\;{\mu}g/mL$, $410\;{\mu}g/mL$, $523\;{\mu}g/mL$ and $490\;{\mu}g/mL$, respectively.

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Determination of Total Saponin in Ginseng Jellies and Candies (인삼추출물(人蔘抽出物) 함유과자류(含有菓子類)의 Total Saponin 의 정량(定量))

  • Kim, Hyong-Soo;Lee, Hee-Ja
    • Korean Journal of Food Science and Technology
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    • v.10 no.3
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    • pp.356-360
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    • 1978
  • To determine the total saponin extracted by Shibata method, of Ginseng jellies and candies, $vanillin-H_2SO_4$ coloring method, direct drying method and thinchrographic method were compared after samples were treated with methanol to remove sugars. Thinchrographic method was the more reproducible than direct drying method and $vanillin-H_2SO_4$ coloring method was interfered significantly by sugars.

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