• Title/Summary/Keyword: 승온

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Thermal Stability of Furfuryl Alcohol/Graphite Powder Mixtures for Impregnation of Carbonaceous Composite (탄화복합재료 함침을 위한 퍼퓨릴알콜/흑연분말 혼합물의 열안정성)

  • An, Yeong-Seok;Jo, Dong-Hwan
    • Korean Journal of Materials Research
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    • v.8 no.4
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    • pp.299-303
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    • 1998
  • We examined, using thermoanalytical methods, the effects of $2000^{\circ}C$ heat-treated graphite powders and heating rate of cure after impregnation on the thermal stability and carbon yield of furfuryl alcohol, which is frequently used not only as an impregnant but also as a matrix precursor for carbon fiber-reinforced carbon composites. It was founded that the addition of 30wt% graphite powders to furfuryl alcohol and the heating rate of $35^{\circ}C$/min showed the highest thermal stability of furfuryl alcohol/graphite powder mixture. The carbon yield above $1000^{\circ}C$ was enhanced more than 10% in comparison with the absence of graphite powders. It would be expected that this result can contribute to some extent to reduce the repeating number of processing cycle (carbonization-impregnation-cure-re-carbonization) required to densify a carbonaceous composite.

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A study on the Optimization of Sewage Sludge-based Adsorbent Carbonization Condition for Improving Adsorption Capacity of Hydrogen Sulfide (H2S) (황화수소(H2S) 흡착성능 증진을 위한 하수슬러지 기반 흡착제 탄화조건 최적화 연구)

  • Choi, Sung Yeol;Jang, Young Hee;Kim, Sung Su
    • Applied Chemistry for Engineering
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    • v.29 no.6
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    • pp.765-771
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    • 2018
  • In this study, the optimization of carbonization conditions in manufacturing processes was performed to improve the absorption performance of sewage sludge based sorbent used for treating $H_2S$ out of all odorous substances generated by various environmental facilities. Adsorbents applied were manufactured from the sewage treatment plant under different carbonization conditions, such as temperature and heating rate, and the correlation between the adsorption performance and physical properties of the adsorbents was verified. As a result, the adsorption performance of sludge at $900^{\circ}C$ with a heating rate of $10^{\circ}C/min$ was the best, and the SEM and BET analysis revealed that specific surface area and characteristics of pore (size, volume) were major parameters for the adsorption. In addition, the effect of K ions used for improving the adsorption performance of the optimum carbonization condition sorbent was insignificant for the sewage sludge based sorbent.

Downward Influences of Sudden Stratospheric Warming (SSW) in GloSea6: 2018 SSW Case Study (GloSea6 모형에서의 성층권 돌연승온 하층 영향 분석: 2018년 성층권 돌연승온 사례)

  • Dong-Chan Hong;Hyeon-Seon Park;Seok-Woo Son;Joowan Kim;Johan Lee;Yu-Kyung Hyun
    • Atmosphere
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    • v.33 no.5
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    • pp.493-503
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    • 2023
  • This study investigates the downward influences of sudden stratospheric warming (SSW) in February 2018 using a subseasonal-to-seasonal forecast model, Global Seasonal forecasting system version 6 (GloSea6). To quantify the influences of SSW on the tropospheric prediction skills, free-evolving (FREE) forecasts are compared to stratospheric nudging (NUDGED) forecasts where zonal-mean flows in the stratosphere are relaxed to the observation. When the models are initialized on 8 February 2018, both FREE and NUDGED forecasts successfully predicted the SSW and its downward influences. However, FREE forecasts initialized on 25 January 2018 failed to predict the SSW and downward propagation of negative Northern Annular Mode (NAM). NUDGED forecasts with SSW nudging qualitatively well predicted the downward propagation of negative NAM. In quantity, NUDGED forecasts exhibit a higher mean squared skill score of 500 hPa geopotential height than FREE forecasts in late February and early March. The surface air temperature and precipitation are also better predicted. Cold and dry anomalies over the Eurasia are particularly well predicted in NUDGED compared to FREE forecasts. These results suggest that a successful prediction of SSW could improve the surface prediction skills on subseasonal-to-seasonal time scale.

Temperature-Programmed Reduction of Copper Oxide Supported on ${\gamma}-Al_2O_3$ and $SiO_2$ (${\gamma}-Al_2O_3$$SiO_2$에 입혀진 산화 구리의 승온 환원)

  • Hwa-Gyung Lee;Chong-Soo Han;Min-Soo Cho;Kae-Soo Lee;Hakze Chon
    • Journal of the Korean Chemical Society
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    • v.30 no.5
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    • pp.415-422
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    • 1986
  • The metal-support interaction of copper oxide supported on ${\gamma}$-alumina and silica was studied by X-ray diffraction (XRD) and temperature-programmed reduction(TPR). It was found that XRD pattern of CuO can not be observed up to 5.0wt % copper content for CuO/${\gamma}-Al_2O_3$ while CuO/$SiO_2$ sample shows the CuO pattern even at 2.5wt% copper content. $H_2-$TPR of CuO/${\gamma}-Al_2O_3$ system shows four major peaks at 145${\circ}C$, 185${\circ}C$, 210${\circ}C$, and 250${\circ}C$. In the case of CuO/$SiO_2$, a large peak at 250${\circ}C$ was appeared accompanying a small peak at 425${\circ}C$. Comparing the TPR peaks with that of copper aluminate which was prepared from the calcination of CuO/${\gamma}-Al_2O_3$ at 1000${\circ}C$, the peaks at around 145${\circ}C$, 200${\circ}C$ (185${\circ}C$ and 210${\circ}C$), and 250${\circ}C$ were corresponded to $Cu^+$ ion in CuO interacting ${\gamma}-Al_2O_3$, $Cu^+$ ions in defect sites of ${\gamma}-Al_2O_3$ and $Cu^{2+}$ ion in the bulk CuO layer, respectively. From the results, it was concluded that there is considerable metal-support interaction in CuO on ${\gamma}-Al_2O_3$ and the interaction results in a stabilization of $Cu^+$ ion in the system.

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A Study on Co-carbonization Behavior of CoaI Tar and Petroleum Pitch (석유핏치와 석탄타르핏치의 공탄화 거동에 관한 연구)

  • Sim, Hwan-Bo;Lee, Baek-Hyeon;Hong, Seong-Wan;Lee, Bo-Seong
    • Korean Journal of Materials Research
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    • v.6 no.2
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    • pp.138-144
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    • 1996
  • 탄소재료 결합모재의 전구체로 핏치류가 많이 이용된다. 본 연구에서는 탄화거동에서 차이를 보이고 있은 석유계와 석탄계 핏치의 첨가량을 10-70wt%까지 배합하여 400-50$0^{\circ}C$ 온도범위에서 열처리하는 동안에 나타나는 흐름거동, 용해도 정도 등을 관찰함으로서 모재로서의 가능성을 평가하였다. 질소분위기에서 열처리속도 2.5$^{\circ}C$/min로 43$0^{\circ}C$까지 승온하여 30분 동안 처리한 결과 석유계 핏치의 첨가량이 50%가 될 때 까지는 핏치의 유동성과 점결력을 좌우하는 것으로 알려질 $\beta$-resin의 양이 45wt%이상으로 나타났으며, 이렇게 혼합된 핏치는 탄화수율도 같은 조건으로 처리된 원료 핏치에 비해 73-100%까지 높은 값을 보임으로서 모재로서의 가능성이 있음을 보였다.

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Sintering process and properties of anode support for SOFC

  • Lee, Dae-Jin;Ji, Mi-Jeong;Lee, Mi-Jae;Jo, Nam-Hui;Park, Seong-Tae;Choe, Byeong-Hyeon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.261-261
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    • 2009
  • Anode 지지형 SOFC의 Anode 지지층 제조에 있어 Ni의 입성장이 일어나면 전극의 반응면적이 줄어들어 전기전도도가 감소되므로 소결체의 제조공정이 매우 중요하다. 기공형성제의 함량이 증가할수록 기공율도 증가하였고 기공체의 함량이 20%를 넘어가면서 기공율은 오히려 줄고 밀도도 감소하였다. Anode 지지체는 $1200^{\circ}C$ 이상에서 열처리하여야 입자간 소결이 이루어지며 승온 속도를 $2.5^{\circ}C$ 유지하여 20% 수준의 기공률을 형성하였다. 소결한 음극지지체를 환원하였을 때 35%수준의 개기공을 형성하였고 전해질과의 접착성도 우수하였다.

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A Study on Aerodynamic Reduced Order Model Using Proper Orthogonal Decomposition (Proper Orthogonal Decomposition을 이용한 공력축소모델 연구)

  • Jun, Sang-Ook;Park, Kyung-Hyun;Kang, Seung-On;Lee, Dong-Ho
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2009.04a
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    • pp.151-154
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    • 2009
  • 본 연구에서는 Proper Orthogonal Decomposition (POD)를 이용하여 공력축소모델을 구축하였다. 일반적으로 Euler equations과 같은 높은 정확도를 가지는 공력해석을 수행할 경우 많은 계산 비용이 발생하게 된다. 특히 공탄성 해석과 같이 수차례의 공력해석이 필요한 경우 그 비용은 더 증가하게 된다. 이러한 문제를 줄이기 위해서 축소모델(Reduced Order Model; ROM)의 개발은 반드시 필요하다. 공력축소모델을 구하는 방법 중 하나인 POD는 snapshot 데이터로부터 기저벡터를 구하고, 이들의 선형결합을 통하여 축소된 공간에서 해를 찾는 방법이다. 본 연구에서는 POD 기저벡터를 이용한 공력축소모델을 구축하고, 이를 전투기 날개문제에 적용하여 구하여진 정상상태 해와 Euler 해석 결과를 비교해 보았다. 또한 진동하는 익형문제에 적용하여 봄으로써 공탄성 해석에 적용 가능성 여부를 확인하였다.

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A Study on Behavior of Steel Surface Oxidation with Characteristics of the Combustion (연소 특성에 따른 강판 표면 산화거동에 관한 연구)

  • KIM, SEULGI;KANG, KIJOONG;LEE, KEEMAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.4
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    • pp.392-400
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    • 2017
  • An experimental study was conducted to investigate behavior of steel surface oxidation with characteristics of the combustion. The excess entalphy combustion in porous media system was applied to implement the direct radiation heating system. The surface oxidation thickness (SOT) of fuel-lean was thicker than the SOT of fuel-rich. Also, the SOT was increased by increasing residence time. Detailed explanations were given by SEM and EDS analysis.

Development of Helicopter Design and Analysis Program for Helicopter Conceptual Design (헬리콥터 개념설계를 위한 설계 및 분석 프로그램 개발)

  • Ko, Kang-Myung;Kang, Seung-On;Kim, Sang-Hun;Lee, Dong-Ho;Chang, Yong-Jin;Choi, Won;Hwang, Yu-Sang;Kim, Cheol-Ho
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.1595-1600
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    • 2007
  • It is necessary a simple helicopter design and performance analysis program for a stage of helicopter conceptual design. To meet that needs, we have developed a program which is simply used to estimate helicopter configuration and performance. The program developed by this study is composed of Requirement, Mission profile Analysis, Size, Aerodynamic, Trim, Propulsion, Weight, and Performance modules, and each modules carry out operations for a given flight condition. In this study, we validate this analysis program in 9,500 1bs and 22,000 1bs helicopters and estimate design configuration and performance of 16,000 1b helicopter. And We can use this program to optimization process for Helicopter MDO framework.

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Residual Stress Effect in Ferroeletric Ceramics (강유전 요업체에서의 잔류응력 영향)

  • 정훈택;김호기
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.2 no.1
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    • pp.70-75
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    • 1992
  • A model for a microstructural residual stress in a ferroelectric material is proposed. Based on this model, two facts are estimated. One of them is that the residual stress on a grain boundary is larger than that on a domain boundary. Another one is that the microstructural residual stress decrease with increasing grain size. These facts are confirmed by the microcrack morphology and the dependence of dielectric constant hysteresis between heating and cooling on grain size in $PbZr_{0.4}Ti_{0.6}O_3$ ceramics.

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