• Proceedings of the Korean Society Of Semiconductor Equipment Technology
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• 2004.05a
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• pp.213-216
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• 2004

폐슬러지 실리콘과 흑연의 혼합물에 물을 주입하고 열처리하여, 마이크론 크기의 이산화 실리콘 구형입자를 제조하였다. 제조된 이산화 실리콘의 직경은 균일하고 약 $1.7\mu\textrm{m}$이다. 탄화 실리콘이 이산화 실리콘 구형입자와 함께 존재하였으며, 그 모양은 휘스커와 다면체였다. 폐슬러지 실리콘과 탄소의 혼합물을 고온에서 열처리하면 일산화 실리콘 기체가 생성된다. 물이 산소의 공급원으로 주입되면 일산화 실리콘 기체는 산소와 반응하여 이산화 실리콘 고체가 형성될 수 있다. 실리콘 공급원으로 일산화 실리콘이 반응기 내에 균일하게 분포하고 물을 주입하여 이산화 실리콘이 형성되는 메커니즘은 액상에서 수산화 실리콘 구형입자를 형성하는 메커니즘과 유사하다.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.5
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• pp.482-488
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• 2008

• Journal of Korean Society of Water and Wastewater
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• v.29 no.1
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• pp.57-63
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• 2015

Recently, Korea's municipal wastewater treatment plants generated amount of wastewater sludge per day. However, ocean dumping of sewage sludge has been prohibited since 2012 by the London dumping convention and protocol and thus removal or treatment of wastewater sludge from field sites is an important issue on the ground site. The hydrothermal carbonization is one of attractive thermo-chemical method to upgrade sewage sludge to produce solid fuel with benefit method from the use of no chemical catalytic. Hydrothermal carbonization improved that the upgrading fuel properties and increased materials and energy recovery, which is conducted at temperatures ranging from 200 to $350^{\circ}C$ with a reaction time of 30 min. Hydrothermal carbonization increased the heating value though the increase of the carbon and fixed carbon content of solid fuel due to dehydration and decarboxylation reaction. Therefore, after the hydrothermal carbonization, the H/C and O/C ratios decreased because of the chemical conversion. Energy retention efficiency suggest that the optimum temperature of hydrothermal carbonization to produce more energy-rich solid fuel is approximately $200^{\circ}C$.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2020.11a
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• pp.143-144
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• 2020

For modern people who spend 80% of the day indoors, indoor air quality is an important factor in their lives. Radon and fine dust, which are indoor air quality pollutants, cause various diseases and lung diseases, so a method is needed to reduce them. Therefore, this study intends to utilize the air pollutant adsorption properties of the carbonized sludge by using the carbonized sludge generated through drying and carbonization of the sludge. As a result of the experiment, it was shown that the concentration of radon and fine dust gradually decreased as the replacement ratio of carbonized sludge increased. The reason is that the carbonized sludge has the ability to adsorb fine dust and radon, so it is considered that it gradually decreases as the replacement ratio increases. Also, the compressive strength and flexural strength tend to decrease gradually. The reason for this is that the carbonized sludge has a number of internal voids, and as the replacement ratio increases, the internal voids increase and the strength decreases. If the refinement and strength of the carbonized sludge replacement ratio are supplemented, it is believed that it will be able to replace the existing finishing materials.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.05a
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• pp.189-190
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• 2021

Recently, the spread of intense social distancing and untact culture due to COVID-19 has increased the time spent indoors. In addition, according to the International Cancer Institute, fine dust was classified as a first-class carcinogen, a substance found to be carcinogenic, such as asbestos and benzene. As a result, interest in indoor air quality is increasing, and many studies are underway to reduce air pollutants. This study is a basic experiment of a board made to improve indoor air quality. The basic characteristics of the board, flexural strength and compressive strength, are analyzed and the results of the test are as follows. Experiments have shown that flexural strength and compressive strength tend to decrease as the replacement rate of hydrocarbons increases. It is believed that the strength of the sludge has decreased due to the increase in internal voids due to the increase in non-surface area, volume and diameter of microfiber as it undergoes the carbonation process. In addition, it is believed that the amount of moisture needed for curing during the mixing process was reduced due to the absorption of hydrocarbons.

• Resources Recycling
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• v.19 no.4
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• pp.41-50
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• 2010

A fundamental study was carried out to develop a process for recycling tungsten and cobalt from WC-Co hardmetal sludge generated in the manufacturing process of hardmetal tools. The complete extraction of cobalt and simultaneous formation of tungstic was achieved by treating the sludge using aqua regia. The effect of aqua regia concentration, reaction temperature and time, pulp density on cobalt leaching and tungstic acid formation was investigated. The complete leaching of cobalt was attained at the optimum conditions: 100 vol.% aqua regia concentration, $100^{\circ}C$ temperature, 60 min. reaction time and 400 g/L pulp density. A complete conversion of tungsten carbide of the sludge to tungstic acid was however, obtained at the pulp densities lower than 150 g/L under the above condition. The progress of reaction during the aqua regia treatment of the sludge was monitored through the XRD phase identification of the residue. The metallic impurities in the tungstic acid so produced could be further removed as insoluble residues by dissolving the tungsten values in ammonia solution. The ammonium paratungstate($(NH_4)_{10}{\cdot}H_2W_{12}O_{42}{\cdot}4H_2O$) of 99.85% purity was prepared from the ammonium polytungstate solution by the evaporation crystallization method.

• Korean Chemical Engineering Research
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• v.50 no.4
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• pp.718-722
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• 2012

$H_2S$ adsorption characteristics of adsorbent made by sewage sludge were investigated. For analyses of the manufactured adsorbent, various methods such as Iodine adsorptivity, scanning electron microscope (SEM), and measurements of BET surface area and pore volume were adopted. As the major adsorption characteristic, breakthrough curve was measured by using a continuous fixed bed adsorption column for operating variables such as adsorption temperature ($25{\sim}45^{\circ}C$), aspect ratio (L/D)(3~9), gas flow rate (0.1~2.0 liter/min) and $H_2S$ gas concentration (50~200 ppm). The experimental result showed that the carbonization and activation of sewage sludge are very important for the improvement in $H_2S$ adsorption capacity.

• Journal of the Korea Organic Resources Recycling Association
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• v.24 no.2
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• pp.3-13
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• 2016

This study investigated the environmental and economical assessment for sewage sludge treatment options including biogasification, incineration, carbonization, drying, and solidification. Additionally it is also investigated the economical feasibility of the current guidelines (Digestion efficiency for organic waste = 45 %, Moisture content of sludge = 95 and 93 %) and it aimed to suggest the scientific informations for a policy-making. For the economical feasibility the 30 plants with anaerobic digestion treatment and the 17 plants without anaerobic digestion treatment were investigated. The result of the comparison of sewage sludge treatment options showed that anaerobic digestion+incineration was the most economically feasible considering incineration and drying. For smaller treatment capacity, solidification was the most economically feasible considering carbonization and solidification and anaerobic digestion+carbonization was the most economically feasible considering carbonization and solidification.

• Journal of the Korea Organic Resources Recycling Association
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• v.24 no.2
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• pp.15-29
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• 2016

This study investigated the environmental and economical assessment for sewage sludge treatment options including biogasification, incineration, carbonization, drying, and solidification. Considering B/C ratio for an anaerobic digestion treatment, for $270,000m^3/d$ (over $1,150m^3/day$), B/C was 1, as the moisture content increased to 95 %, B/C was 1 for $100000m^3/d$ (capacity of $400m^3/day$). Anaerobic digestion+solidification was the most economically feasible, then Anaerobic digestion+incineration and anaerobic digestion+drying were the next economically feasible and then anaerobic digestion+carbonization was the least economically feasible. If anaerobic digestion efficiency was improved to 45%, the treatment costs for anaerobic digestion+carbonization, anaerobic digestion+incineration and anaerobic digestion+drying were decreased to 3,000~5,000 won/t and the costs for anaerobic digestion+solidification was decreased to 2,000~3,000 won/t due to increasing of the beneficial cost of the biogas production.

• Journal of the Korea Organic Resources Recycling Association
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• v.24 no.3
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• pp.5-13
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• 2016

This study investigated the environmental and economical assessment for sewage sludge treatment options including biogasification, incineration, carbonization, drying, and solidification. For the economical feasibility the 30 plants with anaerobic digestion treatment and the 17 plants without anaerobic digestion treatment were investigated. In regarding to the environmental assessment, the air emission pollutants (SOx, NOx, etc) from incineration and carbonization plants were assessed and 1~34 % of emission limits was emitted. Drying and solidification plants emitted about 30 % of odour limits. And the rest of the pollutants were emitted either at not-detectable level or at below the limits. When the by-products from the solidification treatment was used as landfill cover materials, the unconfined compression strength could be below the limit and it could cause an unsafe condition for those passing vehicles and the possibility of the ground subsidence. There has been a maintenance difficulty due to frequent blockage and operational failure. The result of the comparison of sewage sludge treatment options showed that anaerobic digestion+incineration was the most economically feasible considering incineration and drying. For smaller treatment capacity, solidification was the most economically feasible considering carbonization and solidification and anaerobic digestion+carbonization was the most economically feasible considering carbonization and solidification.