• Title/Summary/Keyword: 스핀변환

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Synthesis of Titanium Dioxide Nanoparticles with a High Crystalline Characteristics (높은 결정성을 갖는 이산화티탄 나노입자의 합성)

  • Kim, Ki-Chul
    • Journal of Convergence for Information Technology
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    • v.7 no.5
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    • pp.53-58
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    • 2017
  • In the age of oil exhaustion, low cost, semi-transparent solar cell, the dye-sensitized solar cell (DSC) has attracted significant attention since 1991 of $Gr{\ddot{a}}tzel$ report. To enhance the light-harvest capability of the photoelectric electrode, and efficiency of photoelectric transformation of the DSC, scattering layer of various structure have been proposed to photoelectric electrode materials. The scattering center of scattering layer needs the large titanium dioxide nanoparticles of 250 - 300 nm in diameter. In this study, the large sized $TiO_2$ nanocyrstals of around 300 nm were synthesized using the modified sol-gel process. According to the analysis of XRD and TEM, the synthesized $TiO_2$ nanoparticles exhibit single crystals of anatase phase. The optical transmittance of the synthesized titanium dioxide film prepared by spin coating is around 50% at 550 nm. It is suitable for scattering layer as a scattering center, and expected to enhance the efficiency of photoelectric transformation of the DSC.

The Effects of Precursor on the Formation and Their Properties of Spin-on Dielectric Films Used for Sub-50 nm Technology and Beyond (50 nm 이상의 CMOS 기술에 이용되는 Spin-on Dielectric 박막 형성과 그 특성에 미치는 전구체의 영향)

  • Lee, Wan-Gyu
    • Journal of the Korean Vacuum Society
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    • v.20 no.3
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    • pp.182-188
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    • 2011
  • Polysilazane and polymethylsilazane based precursor films were deposited on Si-substrate by spin-coating, subsequently annealed at $150{\sim}850^{\circ}C$, and characterized. Structural analysis, shrink, compositional change, etch rate, and gap-filling were observed. Annealing the precursor films led to formation of spin-on dielectric films. C-containing precursor films showed that less loss of N, H, and C while less gain of O than that of C-free precursor films at $400^{\circ}C$, but more loss of N, H, and C while more gain of O at $850^{\circ}C$. Thus polysilazane based precursor films exhibited less reduction in thickness of 14.5% than silazane based one of 15.6% at $400^{\circ}C$ but more 37.4% than 19.4% at $850^{\circ}C$. FTIR indicated that C induced smaller amount of Si-O bond, non-uniform property, and lower resistance to chemical etching.

The Study on the Composition of the Encoder for Driving the High Speed Spindle Motor (고속 스핀들 전동기 구동을 위한 자기식 엔코더 구성에 관한 연구)

  • Choi Cheol;Kim Cheol-U;Lee Sang-Hun
    • The Transactions of the Korean Institute of Electrical Engineers B
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    • v.54 no.5
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    • pp.253-259
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    • 2005
  • Magnetic encoder with relatively low pulse per rotation is generally used for detecting speed of the high-speed rotating machine. It is due to the fact of the mechanical problems of vibration and bearing stiffness and also the limit of maximum output pulse of the mounted encoder. The magnetic encoder is divided into two types, that is, toothed gear-wheel method and magnetic wheel method according to the shape of the rotation disk. In case of detecting speed by the tooth gear-wheel, the encoder itself can be acted as the additional inertia where the number of tooth determining the output pulse and the width of the wheel detecting the change of the magnetic flux density are relatively enough large considering the volume of the rotating machine. While the magnetic wheel method has the limit of the magnetizing number of the ring magnet, there is relatively few, if nv, the influence of inertia on the machine. In this paper, it is proposed a simple magnetic wheel encoder suited for the high speed rotating machine and the method of signal processing and the output characteristics are examined through the V/F operation of max 48,000(rpm) and 2.4(KW) spindle motor.

Calculation of Soil Moisture and Evapotranspiration of KLDAS applying Ground-Observed Meteorological Data (지상관측 기상자료를 적용한 KLDAS(Korea Land Data Assimilation System)의 토양수분·증발산량 산출)

  • Park, Gwangha;Kye, Changwoo;Lee, Kyungtae;Yu, Wansik;Hwang, Eui-ho;Kang, Dohyuk
    • Korean Journal of Remote Sensing
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    • v.37 no.6_1
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    • pp.1611-1623
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    • 2021
  • Thisstudy demonstratessoil moisture and evapotranspiration performance using Korea Land Data Assimilation System (KLDAS) under Korea Land Information System (KLIS). Spin-up was repeated 8 times in 2018. In addition, low-resolution and high-resolution meteorological data were generated using meteorological data observed by Korea Meteorological Administration (KMA), Rural Development Administration (RDA), Korea Rural Community Corporation (KRC), Korea Hydro & Nuclear Power Co.,Ltd. (KHNP), Korea Water Resources Corporation (K-water), and Ministry of Environment (ME), and applied to KLDAS. And, to confirm the degree of accuracy improvement of Korea Low spatial resolution (hereafter, K-Low; 0.125°) and Korea High spatial resolution (hereafter, K-High; 0.01°), soil moisture and evapotranspiration to which Modern-Era Retrospective analysis for Research and Applications, version 2 (MERRA-2) and ASOS-Spatial (ASOS-S) used in the previous study were applied were evaluated together. As a result, optimization of the initial boundary condition requires 2 time (58 point), 3 time (6 point), and 6 time (3 point) spin-up for soil moisture. In the case of evapotranspiration, 1 time (58 point) and 2 time (58 point) spin-ups are required. In the case of soil moisture to which MERRA-2, ASOS-S, K-Low, and K-High were applied, the mean of R2 were 0.615, 0.601, 0.594, and 0.664, respectively, and in the case of evapotranspiration, the mean of R2 were 0.531, 0.495, 0.656, and 0.677, respectively, indicating the accuracy of K-High was rated as the highest. The accuracy of KLDAS can be improved by securing a large number of ground observation data through the results of this study and generating high-resolution grid-type meteorological data. However, if the meteorological condition at each point is not sufficiently taken into account when converting the point data into a grid, the accuracy is rather lowered. For a further study, it is expected that higher quality data can be produced by generating and applying grid-type meteorological data using the parameter setting of IDW or other interpolation techniques.

Synthesis of Aluminum Nitride Powers and Whiskers from a (NH4)[Al(edta)]·2H2O Complex under a Flow of Nitrogen (질소 분위기에서 (NH4)[Al(edta)]·2H2O 착물으로부터 질화알루미늄 분말 및 휘스커의 합성)

  • Jung, Woo-Sik
    • Journal of the Korean Ceramic Society
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    • v.39 no.3
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    • pp.272-277
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    • 2002
  • Aluminum nitride (AlN) powders and whiskers were synthesized by a modified carbothermal reduction and nitridation where a ($NH_4)[Al(ethylenediaminetetraacetate)]{\cdot}2H_2O$ complex is used as precursor. The AlN powders were obtained by calcining the complex without mixing any carbon source under a flow of nitrogen in the temperature range 1200∼1500$^{\circ}$C and then burning out the residual carbon. The nitridation process was investigated by $^{27}Al$ magic-angle spinning (MAS) unclear magnetic resonance, infrared spectroscopy and X-ray diffraction. The complex is pyrolyzed, converted to ${\rho}$- and ${\gamma}$- alumina and then nitridated to AlN without ${\gamma}-{\alpha}$ alumina transition. The morphology of ${\gamma}$-alumina, when it was converted to AlN, was retained, strongly indicating that ${\gamma}$-alumina is converted to AlN through solid-state $AlO_xN_y$, not through gaseous intermediates such as aluminum and aluminaum suboxides. AlN whiskers were obtained, when a (0001) sapphire was used as a catalyst.

Development of a tool to automate finite element analysis of a spindle system of machine tools (공작기계 주축 시스템의 유한요소해석 자동화를 위한 툴 개발)

  • Choi, Jin-Woo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.4
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    • pp.2350-2355
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    • 2015
  • A tool was developed in this research for automation of one-dimensional finite element analysis (1D FEA) for design of a machine tool spindle system composed mainly of a shaft and bearings. As it is based on object-oriented programing, it uses the objects of a CAD system. It requires minimum data to be input to define the spindle system such as shaft cross-sections and bearing stiffness. Then, it automatically generates the geometric model based on the data and then, converts it into the FE model of 1D beams and springs. The graphic user interfaces developed allow a user to interact with the tool. This tool can be applied to identification of a near optimal design of the spindle system in minimum time and efforts by automating the FEA process with numerous design changes.

High Energy Photon Dosimetry by ESR Spectroscopy in Radiotherapy (ESR Spectroscopy에 의한 치료용 고에너지 광자선의 선량측정)

  • Chu, Sung-Sil
    • Progress in Medical Physics
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    • v.1 no.1
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    • pp.31-42
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    • 1990
  • The finding of long lived free radicals produced by ionizing radiation in organic crystals and the quantification of this effect by electron spin resonance(ESR) spactroscopy has proven excellent dosimetric applicability. The tissue equivalent alanine dosimeter also appear appropriate for radiation therapy level dosimetry. The dose measurement was performed in a Rando phantom using high energy photons as produced by high energy medical linear accelerator and cobalt-60 teletherapy unit. The absorbed dose range of the ESR/alanine dosimetry system could be extended down to 0.1 Gy. The response of the alanine dosimeters was determined for photons at different therapeutic dose levels from less than 0.1 Gy to 100 Gy and the depth dose measurements were carried out for photon energies of 1.25MeV, 6 and 10 MV with alanine dosimeters in Rando phantom. Comparisons between ESR/alanine in a Rando phantom and ion chamber in a water phantom were made performing depth dose measurements to examine the agreement of both methods under field conditions.

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Synthesis of Porous $TiO_2$ Thin Films Using PVC-g-PSSA Graft Copolymer and Their Use in Dye-sensitized Solar Cells (PVC-g-PSSA 가지형 공중합체를 이용한 다공성 $TiO_2$ 박막의 합성 및 염료감응 태양전지 응용)

  • Byun, Su-Jin;Seo, Jin-Ah;Chi, Won-Seok;Shul, Yong-Gun;Kim, Jong-Hak
    • Membrane Journal
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    • v.21 no.2
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    • pp.193-200
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    • 2011
  • An amphiphilic graft copolymer comprising a poly(vinyl chloride) (PVC) backbone and poly (styrene sulfonic acid) (PSSA) side chains (PVC-g-PSSA) was synthesized via atom transfer radical polymerization (ATRP). Mesoporous titanium dioxide $(TiO_2)$ films with crystalline anatase phase were synthesized via a sol-gel process by templating PVC-g-PSSA graft copolymer. Titanium isopropoxide (TTIP), a $TiO_2$ precursor was selectively incorporated into the hydrophilic PSSA domains of the graft copolymer and grew to form mesoporous $TiO_2$ films, as confirmed by scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis. The performances of dye-sensitized solar cell (DSSC) were systematically investigated by varying spin coating times and the amounts of P25 nanoparticies. The energy conversion efficiency reached up to 2.7% at 100 mW/$cm^2$ upon using quasi-solid-state polymer electrolyte.

Effects of Organic Passivation Films on Properties of Polymer Solar Cells with P3HT:PC61BM Active Layers (유기 패시베이션 박막이 P3HT:PC61BM 활성층을 갖는 고분자 태양전지의 특성에 미치는 영향)

  • Lee, Sang Hee;Park, Byung Min;Cho, Yang Keun;Chang, Ho Jung;Jung, Jae Jin;Pyee, Jaeho
    • Journal of the Microelectronics and Packaging Society
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    • v.21 no.4
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    • pp.105-110
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    • 2014
  • It is required to improve the efficiency and the reliability of the polymer solar cells (PSCs) as the energy saving optical device for the future application of the smart farm facilities. In this study, we fabricated the bulk hetero junction PSCs with organic passivation film layer for the reliability improvement of the devices. The effects of the passivation layer on the electrical properties of the PSCs were studied. The materials of passivation layer are composed of poly vinyl alcohol (PVA) and ammonium dichromate, and the passivation films were fabricated by the spin coating method on the P3HT:$PC_{61}BM$/LiF/Al substrate. The prepared structure of the device is the glass/ITO/PEDOT:PSS/P3HT:$PC_{61}BM$/LiF/Al/passivation layer. The performances of the PSCs with the organic passivation film showed better electrical properties compared with the PSCs without passivation layers. The power conversion efficiency (PCE) values of passivated PSCs decreased from 3.0 to 1.3% after air exposure for 140 hrs. In contrast, the PCE values for the devices without passivation decreased sharply from 3.5 to 0.1% under the same exposure condition.