• Title/Summary/Keyword: 쉘 두께

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Optical Properties of Ag@Fe3O4 Core-Shell Nanoparticles (Ag@Fe3O4 코어-쉘 나노입자의 광학적 특성)

  • Song, Younseong;Koh, Kwangnak;Kim, Kyujung;Lee, Jaebeom
    • Korean Journal of Optics and Photonics
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    • v.28 no.3
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    • pp.97-102
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    • 2017
  • In this paper, we investigate the optical properties of $Ag@Fe_3O_4$ nanoparticles (NPs) composed of a plasmonic core and a magnetic shell. As the $Fe_3O_4$ shell with high refractive index (~2.42) is formed on the surface of the silver NPs having diameter of 60 nm, the wavelength of the localized surface-plasmon resonance (LSPR) is shifted from 420 nm to 650 nm, a so-called "redshift". Furthermore, through the use of three simulation models ($Ag@Fe_3O_4$ NP, $Fe_3O_4$ shell NP, and silver NP), the peak at 410 nm is seen to be the result of scattering by the $Fe_3O_4$ shell with 60 nm thickness, which would be useful in comprehending the complex optics in various nanoscale assemblies using similar NPs.

Statistical Behavior of RC Cooling Tower Shell due to Shape Imperfection (철근콘크리트 냉각탑의 형상불완전에 의한 확률론적 거동)

  • 최창근;노혁천
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.13 no.1
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    • pp.147-158
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    • 2000
  • For the large scale reinforced concrete cooling tower shells, the shape imperfection can be introduced due not only to mistakes in the process of construction but also to the long term behavior of concrete. The shape imperfection evokes the additional responses such as displacements and stresses in addition to the design values. In this study, the statistical behavior of the RC cooling tower shell due to the shape imperfection is investigated using the Monte Carlo simulation. The radius of cooling tower and the shell thickness are adopted as the parameters which cause the shape imperfection. The shape imperfection is modeled as a stochastic field rather than the local one of axisymmetric or bulge type of imperfection. The randomness in the radius is shown to be more affecting the structural responses than the randomness in the shell thickness. In addition to the geometrical randomness, the effect of randomness in the modulus of elasticity on the structural response is also investigated and compared with that of the geometrical ones.

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Nonlinear analysis of containment structure under thermal and pressure load (원자로 격납건물의 열응력해석연구)

  • 오병환;이명규
    • Proceedings of the Korea Concrete Institute Conference
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    • 1993.04a
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    • pp.219-224
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    • 1993
  • 본 연구는 철근콘크리트 격납구조물에서 가상의 냉각제 유출사고에 의한 온도하중과 압력에 따른 거동을 알아보기 위한 비선형 해석을 수행하였다. 시간에 따른 온도하중을 결정하기 위하여 과도온도해석을 통해 격납구조물 단면내의 온도분포를 구하였다. 구조물은 기하학적 비선형성과 재료비선형성을 고려한 판 및 쉘요소로 이상화되며, 쉘요소는 두께방향에 따라 변하는 응력을 고려하기 위해 몇 개의 층으로 이루어진 모델을 사용하였다. 열응력은 인접한 두시간 단계에서의 온도차를 하나의 하중증가로 고려하여 초기변형 문제로 변환하여 결정되었다. 본연구에서의 수치실험에 의하여 과도온도해석에 근거한 비선형온도경사를 고려할 때의 변위가 고려하지 않을 때의 변위에 비해 크게 나타남을 알 수 있다.

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Hygrothermal Bending Analysis of Laminated Composite Plates and Shells Considering a Higher-order Shear Deformation (고차전단변형을 고려한 적층복합판 및 쉘의 열-습윤 휨해석)

  • 한성천;윤석호
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.12 no.1
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    • pp.37-44
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    • 1999
  • 비등방성으로 적층된 복합판 및 쉘구조물에서 온도와 습도의 급격한 변화는 구조물의 강도와 성능을 저하시키는 중요한 원인이 된다. 더욱이 하중에 의한 역학적 변위와 조합될 때에는 좌굴, 대변형 혹은 고응력 상태를 유발하게 된다. 본 연구에서는 이중 퓨리에급수를 이용하여 3차의 전단변형함수로 가정된 평형방정석을 전개하고 폭-두께비, 형상비의 변화 그리고 재료의 성질에 따른 결과에 대하여 고찰하였다.

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Magneto-impedance and Magnetic Relaxation in Electrodeposited Cu/Ni80Fe20 Core/Shell Composite Wire (전기도금 된 Cu/Ni80Fe20 코어/쉘 복합 와이어에서 자기임피던스 및 자기완화)

  • Yoon, Seok Soo;Cho, Seong Eon;Kim, Dong Young
    • Journal of the Korean Magnetics Society
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    • v.25 no.1
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    • pp.10-15
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    • 2015
  • The model for the magneto-impedance of composite wires composed of highly conductive nonmagnetic metal core and soft magnetic shell was derived based on the Maxwell's equations. The Cu($100{\mu}m$ diameter)/$Ni_{80}Fe_{20}$($15{\mu}m$ thickness) core/shell composite wire was fabricated by electrodeposition. The impedance spectra for the $Cu/Ni_{80}Fe_{20}$ core/shell composite wire were measured in the frequency range of 10 kHz~10 MHz under longitudinal dc magnetic field in 0 Oe~200 Oe. The spectra of complex permeability in circumferential direction were extracted from the impedance spectra by using the derived model. The extracted spectra of complex permeability showed relaxation-type dispersion which is well curve-fitted with Debye equation with single relaxation frequency. By analyzing the magnetic field dependence of the complex permeability spectra, it has been verified that the composite wire has magnetic anisotropy in longitudinal direction and the origin of the single relaxation process is the magnetization rotation in circumferential direction.

Comparison of Pipeline and Clamshell Capping Technologies for the Remediation of Contaminated Marine Sediments (해양 오염퇴적물 정화를 위한 원통관과 클램쉘을 이용한 피복 기술의 비교)

  • Kang, Ku;Hong, Seong-Gu;Kim, Young-Kee;Park, Seong-Jik
    • Journal of Navigation and Port Research
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    • v.41 no.4
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    • pp.195-206
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    • 2017
  • In situ capping technology for marine sediment pollution control has never been applied in South Korea. In this study a pilot project for the capping was carried out in Busan N Harbor. Pipeline and clamshell capping technologies were implemented for the pollution control. Changes of capping shapes, sediment contamination, and the time and costs required for the two constructions were compared. Both the pipeline and clamshell technologies were found to satisfy the target thickness of 50 cm on average. However, the pipeline method did not operate sensitively in terms of change of the sea floor topography, resulting in an uneven shape and a thickness. Organic carbon and ignition loss quite decreased after the pipeline or the clamshell capping while pH showed no significant change. Organic and residual fraction of Cd, Ni, and Zn in the sediments appeared to decrease after all cappings. The pipeline method took a construction time four times as much as the clamshell method. The clamshell method was demonstrated to reduce the construction cost by about 40% compared with the pipeline method. However, a monitoring for all the parameters needs to be conducted at least two years in order to better evaluate an efficiency of the pollution control by these capping constructions.

Pipe Wall-Thinning Inspection using Vibration Modes of Pipes with Circumferentially Varying Thickness (원주 방향 두께가 불균일한 배관의 진동 모드 특성을 이용한 배관 감육 검사 기법 연구)

  • Han, Soon-Woo;Seo, Jeong-Seok;Park, Jin-Ho
    • Journal of the Korean Institute of Gas
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    • v.21 no.1
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    • pp.18-26
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    • 2017
  • This work proposes an alternative pipe wall-thinning inspection method based on change of eigenfrequencies of shell vibration modes in wall-thinned pipes. It takes much time to detect wall-thinning of pipes using ultrasonic thickness gauge and only a limited number of pipes are under regular inspection. In a pipe with locally decreased thickness, stiffness varies along circumferential direction and natural frequencies of shell vibration modes of the pipe change or frequencies of same modes bifurcate into two different values. Therefore, one can monitor pipe wall-thinning by measuring change of natural frequencies or estimate wall-thinning shape qualitatively. The feasibility of the proposed method was studied by FE vibration analysis for wall-thinned pipes. Modal testing was also carried out for the pipes with artificial wall-thinned section to verify the working performance of the suggested technique.

Performance of SOFC According to Thickness of Shell with Ni-YSZ Core-shell (Ni-YSZ Core-shell에서 Shell의 두께에 따른 SOFC의 출력특성)

  • CHOI, BYUNG-HYUN;HONG, SUN-KI;JI, MI-JUNG
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.6
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    • pp.663-668
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    • 2017
  • SOFC anode fabricated core-shell using machano-fusion method using core with submicron size Ni, nano size YSZ for shell. Using prepared core-shell, depending on the thickness of the shell, we studied how the characteristics of sintering and SOFC cell change by sintering the anode. The Ni-YSZ core-shell has a Ni core of 0.5 to $1.2{\mu}m$ over 2 to 7 YSZ of 15 to 20 nm is, and as the high speed mixing time increases, the YSZ number increases and the shell thickness becomes uniform increased. When the fuel electrode is manufactured with core-shell, it has superior sintering property, has grain of uniform size compared with the one synthesized by general mixing, the falling path is short, the conductors (electrons and ions) connection is excellent, the electrical conductivity has become excellent. The thicker the shell, the lower the electrical conductivity. When the thickness of shell ranged from 46 to 139 nm and 61 to 81 nm, the performance was the highest and the ASR was the smallest.

코어/쉘 나노입자를 포함한 고분자 박막을 저항 변화층으로 사용한 전기적 안정성을 가진 메모리 소자의 메커니즘 동작

  • Eo, Sang-Su;Yun, Dong-Yeol;Kim, Tae-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.233-233
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    • 2013
  • 유기물/무기물 나노복합체를 이용하여 제작한 비휘발성 메모리 소자는 간단한 공정과 플렉서블 기기 응용 가능성 때문에 많은 연구가 진행되고 있다. 다양한 나노입자를 포함한 고분자 박막에 대한 연구는 많이 진행되었지만, 비휘발성 메모리소자에서 CdSe/InP 나노입자를 사용한 나노복합체의 전기적 안정성과 동작 메커니즘에 대한연구는 미흡하다. 본 연구는 CdSe/InP 코어/쉘 나노입자가 poly (N-vinylcarbazole) (PVK) 박막에 분산되어 있는 나노복합체를 이용하여 메모리 소자를 제작하여 전기적 특성과 안정성을 관찰 하였다. 소자 제작을 위해PVK 고분자를 용매인 클로로벤젠에 용해한 후, 헥산에 안정화 되어있는 CdSe/InP 나노입자를 초음파 교반기를 사용하여 고르게 섞었다. Indium-tin-oxide (ITO)가 증착한 유리 기판을 화학물질로 세척한 후 기판 위에 CdSe/InP 나노입자와 절연성 고분자인 PVK가 혼합된 용액을 스핀코팅 방법으로 도포하여 나노입자가 포함된 고분자 박막층을 형성하여 저항 변화층으로 사용하였다. 형성된 박막 위에 마스크를 사용하여 Al 상부전극을 고진공에서 열 증착하여 비휘발성 메모리 소자를 제작하였다. 제작된 소자의 전류-전압(I-V) 특성을 측정한 결과 동일전압에서 전도도가 좋은 상태 (ON)와 좋지 않은 상태 (OFF)인 두 개의 상태상 존재한다는 것을 확인하였고, CdSe/InP인 나노입자가 포함된 소자와 포함되지 않은 소자의 전기적 특성을 비교 분석하였다. 두 상태의 안정성을 ON 또는OFF 상태의 스트레스를 측정하여 두 상태의 안정성을 확인하였고, 실험결과를 바탕으로 메모리 소자의 동작 메커니즘을 기술하였다.

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Nonlinear Dynamic Analysis of Reinforced Concrete Shells Using Layered Elements with Drilling DOF (회전자유도를 갖는 층상화 요소를 이용한 철근콘크리트 쉘구조의 비선형 동적해석)

  • 김태훈;이상국;신현목
    • Journal of the Earthquake Engineering Society of Korea
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    • v.5 no.6
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    • pp.21-27
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    • 2001
  • In this paper, a nonlinear finite element procedure is presented for the dynamic analysis of reinforced concrete shells. A computer program, named RCAHEST(reinforced concrete analysis in higher evaluation system technology), for the analysis of reinforced concrete structures was used. A 4-node flat shell element will drilling rotational stiffness is used for spatial discretization. The layered approach is used to discretize behavior of concrete and reinforcement through the thickness. Material nonlinearity is taken into account by comprising tensile, compressive and shear models of cracked concrete and a model of reinforcing steel. The smeared crack approach is incorporated. Solution of the equations of motion is obtained by numerical integration using Hilber-Hughes-Taylor(HHT) algorithm. The proposed numerical method for the nonlinear dynamic analysis of reinforced concrete shells is verified by comparison with reliable analytical results.

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