• Title/Summary/Keyword: 수화특성

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The Experimental Study on Hydration Properties of Quaternary Component Blended High Fluidity Concrete with CO2 Reduction (탄소저감형 4성분계 고유동 콘크리트의 수화 특성에 관한 연구)

  • Choi, Yun-Wang;Oh, Sung-Rok;Jo, Jun-Hee;Kang, Hyun-Jin
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.4
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    • pp.403-413
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    • 2017
  • In this paper, to increase the use of industrial byproducts for $CO_2$ reduction and to improve construction performance, it was manufactured that $CO_2$ reduction type quaternary component high fluidity concrete (QC-HFC) with Reduced cement usage by more than 80% and its quality and hydration characteristics were evaluated. QC-HFC was found to satisfy the target performance, and the flow and mechanical properties were similar to those of conventional concrete. The drying shrinkage of QC-HFC decreased about twice compared with the conventional blend, and the hydration heat decreased about 36%. As a result, it can be concluded that the amount of cracks can be reduced by reducing temperature stress due to hydration heat reduction effect and reducing deformation due to relatively small temperature difference between inside and outside. Also, As a result of the simulation of the mass structure, the temperature cracking index of QC-HFC is 1.1 or more, and the cracking probability is reduced by about 35%, so that the crack due to temperature can be reduced.

Hydration of Active-Belite Cement with Gypsum and Slag (석고와 슬래그를 첨가한 Active-Belite Cement의 수화특성)

  • 이성호;박동철;김남호;최상흘
    • Journal of the Korean Ceramic Society
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    • v.35 no.4
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    • pp.330-330
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    • 1998
  • Active belite cement clinkers were synthsized by using natural raw materials with borax and calcium phosphate ({{{{ {Ca }_{3 }( {PO}_{4}) }}2) In both case {{{{alpha ^、 {C }_{2 }S }} were formed but borax was more efficient. The cement syn-thesized with the addition of borax was hydrated with the addition of anhydrite(5 wt%) and slag(30wt%, 40wt% 50wt%) The addition of 50wt% slag with anhydrite was good for strength development in 7days and the compressive strength was developed to twice than no addition of slag at 28 days strength.

A Sign Language Translator using Data Mining in Kinect Environment (키넥트 환경에서 데이터 마이닝을 이용한 수화 번역기)

  • Lee, Sang-Jun;Woo, Tea-Ho;Kim, Jia;Park, Seon-Yeong;Lee, Soo-Won;Kim, Gye-Young
    • Proceedings of the Korea Information Processing Society Conference
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    • 2012.11a
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    • pp.619-622
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    • 2012
  • 본 연구에서는 키넥트(Kinect) 센서를 통해 수화 동작에서 손의 좌표와 이동방향을 추출하여 속성으로 하고, 데이터 마이닝의 분류 기법을 통해 수화를 인식하여 그 결과를 한글 텍스트로 번역해주는 소프트웨어를 개발한다. 제안 방법의 1단계에서는 0.05초 단위로 추출한 손의 좌표만을 속성으로 한다. 2단계에서는 개개인의 특성 및 화면상의 위치와 같은 요소에 따라 좌표 값이 달라지기 때문에, 손의 움직임에서 변위를 추출하여 손이 움직이는 방향을 속성으로 한다. 하지만 비슷한 방향으로 움직이는 수화가 있을 경우 수화의 구분이 어려우므로 3단계에서는 손의 좌표, 방향 두 가지를 분류하는 속성으로 사용한다. 향후 연구 방향은 수화의 중요한 요소인 손의 위치를 속성으로 추가시키고, 데이터 마이닝의 부스팅(Boosting) 기법을 적용하여 인식률을 높이는 것이다.

Effect of Internal Curing by Super-Absorbent Polymer (SAP) on Hydration, Autogenous Shrinkage, Durability and Mechanical Characteristics of Ultra-High Performance Concrete (UHPC) (고흡수성 수지(SAP)를 이용한 내부양생이 초고성능 콘크리트(UHPC)의 수화반응, 자기수축, 내구성 및 역학적 특성에 미치는 영향)

  • Kang, Sung-Hoon;Moon, Juhyuk;Hong, Sung-Gul
    • Journal of the Korea Concrete Institute
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    • v.28 no.3
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    • pp.317-328
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    • 2016
  • This research intends to understand the impact of super-absorbent polymer (SAP) as an internal curing agent in Ultra-High Performance Concrete (UHPC). Two different types of SAPs of acrylic acid (SAP_AA) and acrylic acid-co-acrylamide (SAP_AM) were examined with UHPC formulation. Isothermal calorimetry and x-ray diffraction experiments revealed the impact of polymers with the different chemical bonds on cement hydration. To test its feasibility as a shrinkage reducing admixture for UHPC, a series of experiments including flowability, compressive strength, rapid chloride permeability and autogenous shrinkage profile was performed. While both SAPs showed a reduction in autogenous shrinkage, it has been concluded that the SAP size and chemical form significantly affect the performance as an internal curing agent in UHPC by controlling cement hydration and porosity modification. Between the tested SAPs, SAP_AM which absorbs more water in UHPC than SAP_AA, shows better mechanical and durability performance.

Evaluation of Hydration Characteristics and NOx-removal Performances of Cement Paste Containing Refined TiO2 Obtained from Waste Sludge (폐수 슬러지에서 정제된 TiO2를 혼입한 시멘트 페이스트의 수화특성 및 질소산화물 제거 성능 평가)

  • Yoon, Hyunno;Seo, Joonho;Kim, Seonhyeok;Bae, Jinho;Kil, Taegeon;Lee, Haeng-Ki
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.41 no.4
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    • pp.357-364
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    • 2021
  • The present study investigated the hydration properties and NOx-removal performances of the cement pastes containing three different types of TiO2. Two commercially available TiO2 (P-25 and NP-400) and refined TiO2 (GST) obtained from waste sludge were incorporated to cement paste at levels of 0, 5, 10, and 20 wt%. Isothermal calorimetry test results indicated that the TiO2 incorporation induced a notable influence on the reaction kinetics of cement paste, showing the highest cumulative heat release in the samples containing P-25, followed by NP-400 and GST. Quantitative X-ray diffractometry as calculated by the Rietveld method identified that the incorporated TiO2 promoted the formation of C-S-H, ultimately leading to the enhancement in the 28 day-compressive strength of cement pastes. As revealed by SEM/EDS analysis, the content of distributed Ti elements on the surface of the samples was in the order of P-25, GST, and NP-400. Regardless, the NOx-removal performance was the highest in the sample containing P-25, followed by NP-400 and GST.

Effect of Blast Furnace Slag and Desulfurized Gypsum on Hardening of CFBC Boiler Coal Ash (CFBC 보일러 석탄회의 경화에 대한 고로슬래그, 탈황석고의 영향)

  • Lee, Woong-Geol;Kim, Jin-Ho;Kim, Kyung-Nam;Song, Myong-Shin
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.443-450
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    • 2021
  • The effects of blast furnace slag(BFS) and desulfurized gypsum(FDG) on the compressive strength of CFBA, and self-hydration of CFBA were studied. CFBA has self-hydrating and hardening properties, and it can be seen that the compressive strength of CFBA can be improved by using appropriate amounts of BFS and FDG. In addition, the self-hardening properties of CFBA are similar to the hydration reaction of 4CaO·Al2O3·Fe2O3 (C4AF), a cement clinker mineral, and when free-CaO, CaSO4 and CaCO3 coexist, Compressive strength of CFBA is expressed by the formation of calcium carbo compounds and hydrates of ettringite, calcium silicate, and calcium aluminate.

The Experimental Study on the Heat Hydration Properties of Concrete According to Binder Conditions (결합재 조건에 따른 콘크리트의 수화발열 특성에 관한 연구)

  • Choi, Sung-Woo;Jo, Hyun-Tae;Ryu, Deuk-Hyun
    • Journal of the Korea Concrete Institute
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    • v.18 no.6 s.96
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    • pp.769-776
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    • 2006
  • Recently, owing to the development of industry and the improvement of building techniques, concrete structures are becoming larger and higher. In hardening of these large connote structures, the heat of hydration gives rise to considerable thermal stress depending on the size and environmental condition of concrete, which might cause thermal cracking. Especially, the crack may cause severe damage to the safety and the durability of concrete structure. This study investigates the thermal properties of concrete according to several binder conditions, such as OPC, Belite rich cement(BRC), slag cement(SC), blast furnace slag(B) added cement fly ash(F) added cement and blast-furnace-slag and fly ash added cement. As a result of this study, the properly of concrete is most better BRC than others, and fly ash(25%) added cement and BFS(35%)-fly ash(15%) added cement gets superior effect in the control of heat hydration. But synthetically considered properties of concrete, workablity, strength heat hydration, etc, it is more effective to use mineral admixture. Especially, to be used Blast Furnace slag is more effective.

Water-repellency and Bonding Characteristics of the Cement Hydrate-Organic Acid Compound (시멘트 수화물-유기산의 결합특성과 그 Compound의 발수성)

  • Rho, Jae-Seong;Cho, Heon-Young;Hong, Seong-Soo;Choi, Jeong-Bong
    • Applied Chemistry for Engineering
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    • v.3 no.4
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    • pp.639-648
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    • 1992
  • For recycling cement hydrate(CH) as waterproofers for mortar and concrete or a filler for rubber & plastics, the cement hydrates were treated with stearic acid(SA). And the bonding characteristics and the water repellency of the CH-SA compounds were investigated by using FT-IR, TGA, SEM, XRD, and contact angle measuring apparatus. Water tightness of the remitars used CH-SA compounds was also tested. The results are summarized as follows : 1) If the cement hydrates are treated with over 2.0% of stearic acid, the CH-SA compounds show very strong water repellency. 2) The stearic acids are solidified on the surfaces of cement hydrate in calcium stearate and aluminium stearate. 3) If CH-SA compounds which is cement hydrate treated with 5~10% of stearic acid are used 3%~6% in remitar, water absorption ratio and water permeatility ratio of remitar are decreased in below 30% of those of the ordinary remitar.

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Hydration Properties of Low Carbon type Low Heat Blended Cement (무기질 자극제를 사용한 탄소배출 저감형 저발열형 혼합시멘트의 수화특성에 관한 연구)

  • Choi, Sung-Woo;Ryu, Deuk-Hyun;Kim, Hun-Sang;Kim, Gyu-Yong
    • Journal of the Korea Institute of Building Construction
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    • v.13 no.3
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    • pp.218-226
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    • 2013
  • Of construction materials, cement and steel are the representative material that carbon dioxide. to reduce carbon emissions in the use of these materials The purpose of this study is low heat type blended cement, which is manufactured using a amount of cement than ordinary low heat blended cement. Low heat blended cement, mixing ratio of 10%, was investigated hydration properties and adiabatic temperature of concrete. The study in order to activate the reaction mineral admixture, a separate source of CaO and $SO_3$ areneeded. gypsum and lime, it expected amount of cement, low-carbon low-heat blended cement could reduce the hydration heat concrete than currentlyused low heat blended cement.

Differential Scanning Calorimetry of Skin Collagen (피부조직 콜라겐의 DSC 특성)

  • Kim, Young-Ho;Hong, Sang-Pill;Yang, Ryung
    • Korean Journal of Food Science and Technology
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    • v.27 no.4
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    • pp.571-575
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    • 1995
  • Transition temperature$(T_m)$ and $enthalpy({\Delta}H)$ were examined by means of DSC to obtain basic information on heat stability of skin tissue collagen. From DSC properties of insoluble collagen on hydration time and moisture content, it was found that moisture content had more effect on structural stability of collagen than hydration time. As moisture content increased, $({\Delta}H)$ increased while $(T_m)$ decreased. DSC properties of acetone dried skin on the variation of age and sex showed higher heat stability in case of male rat and heat stability seemed to be connected with age, as $(T_m)$ and $({\Delta}H)$increased with age. Meanwhile, DSC properties of salt soluble collagen showed higher values in female rat than in male rat, and the $(T_m)$ and $({\Delta}H)$ decreased significantly with age in female rat. These results seemed to suggest indirectly that collagen structure varied with age or sex in the same tissue.

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