• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.11 no.2
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• pp.270-280
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• 1999

A performance analysis simulation program that can be applied to a hermetic reciprocating compressor with various refrigerants has been developed. For the numerical analysis, the passage of refrigerant in compressor is subdivided into control volumes. Instead of the ideal gas assumption, CSD equation of state is applied to calculate the thermodynamic properties of refrigerants. To verify the validity of developed program, the result has been compared with the experimental data served by the compressor supplier. The performance of each refrigerant and the possibility of direct application are estimated by applying R12, 134a, R290, R600a and R290/R600a mixture to an existing compressor. Also, parametric study for various crank rotating speeds and the mole fractions of refrigerant has been performed.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 1997.11a
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• pp.17-17
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• 1997

극초음속 여객기와 군사용 항공기에 대한 수요가 증가함에 따라서 새로운 개념의 다양한 추진기관이 연구가 진행되고 개발되어 왔다. 초음속 항공기의 속도 영역은 마하 10-20 정도가 되는데 이 속도 한계를 극복하기 위하여 초음속 연소 램제트 엔진(SCRamjet; Supersonic Combustion Ramjet)이 제안되었다. 스크램 제트를 개발하기 위해서는 연료와 산화제의 혼합 효율 문제, 화염의 안정화 문제, 벽면의 냉각에 관한 문제 등 몇 가지 기본적인 문제들을 해결해야 한다. Univ of Michigan에서 실험한 연소기를 모델로 본 연구에서는 연료와 공기의 혼합에 관한 수치 연구를 수행하였다. 다원 혼합기체에 관한 축대칭 Navier-Stokes 방정식을 지배 방정식을 이용하였고 비평형 화학반응식을 고려하였다. 공간 차분에는 유한 체적법을 이용하였다. 대류 플럭스 항은 Roe의 Upwind FDS 기법을 사용하여 차분하였고 점성항에는 중심 차분법을 이용하였다. 시간 적분법으로는 근사 자코비안과 LU분할 기법을 이용한 완전 내재적 방법이 쓰였다. 난류 모델로는 Mentor에 의해 제안된 2 방정식 k-$\varepsilon$/k-$\omega$ 혼합모델을 사용하였다. 유동장이 실험에서의 찍은 사진과 유사한 모습의 충격파 간섭을 수치 모사하였고 수소가 확산되는 모습과 함께 노즐 lip 주위의 재순환 영역에 대해서 살펴볼 수 있었다.

• Transactions of the Korean hydrogen and new energy society
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• v.4 no.2
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• pp.5-15
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• 1993

Hydrogen production in visible light with the following semiconductor systems, $CdS-WO_3$, $CdS-TiO_2$, have been investigated in the presence of redox catalyst (Pt, $RuO_2$). MeOH, EtOH, isopropanol, sulfide/sulfite mixture, lactic acid were used as sacrifical reagents. The optimal condition for $H_2$ evolution was found to be in qgueous lactic acid media for $CdS-WO_3/RuO_2$. The photochemical efficiency for this system was 1.05 % and the $H_2$ evolution rate was 26.5ml/min. at $6.07{\times}10^{-5}$ einstein/sec photon rate

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.11 no.2
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• pp.262-269
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• 1999

The application of hydrocarbon refrigerant mixtures in a hermetic reciprocating compressor for dehumidifier is investigated. The selected refrigerants are R12, R134a, HC-Blend (R290/R600a), CX(R152a/R600a) and OS-l2a. Both theoretical and experimental investigations have been performed for the selected refrigerants. The test results of hydrocarbon refrigerants have been compared to traditional refrigerant(R12) and R134a. The results show that hydrocarbon refrigerant mixtures(HC-Blend, CX and OS-l2a) are very good alternatives in the refrigeration system for R12 and R134a.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.628-631
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• 2017

An experimental study of the combustion characteristics according to the equivalence ratio of hydrocarbon fuel/air premixture excited by ultrasonic standing wave are presented. The image of the propagating flame was acquired using a high-speed camera, and the combustion characteristics of each fuel were closely observed through image processing. it was conformed that ultrasonic standing wave has been found to stimulate the combustion reaction in the stoichiometric ratio.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.832-835
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• 2009

폐기물의 감량화 및 자원화 기술 중 가장 대표적인 기술로 폐기물의 가스화 용융 기술을 들 수 있다. 폐기물 가스화 용융 기술은 폐기물 내의 탄소 및 수소 성분은 가스화 하여 CO, $H_2$가 주성분인 합성가스(synthesis gas, syngas)로 전환하고, 불연물은 용융하여 환경적으로 무해한 슬래그 또는 금속으로 회수하는 기술이다. 본 연구에서는 고발열량폐기물과 탈수슬러지 혼합가스화를 통하여 생산된 합성가스를 합성가스 압축기를 통하여 유용한 원료물질을 제조하는 공정인 수성가스 전환 반응(water gas shift reaction)과 가스화 반응기의 보조연료로 투입하기 위한 합성가스 압축, 이송 시스템의 운전 특성을 고찰하였다. 그 결과 고발열량폐기물과 탈수슬러지 혼합가스화에서 합성가스는 안정적으로 발생하였으며, 합성가스 압축, 이송시스템을 위한 정제설비에서의 분진제거는 99.07 %의 효율을 얻었고, 또한 합성가스 재순환 장치의 성능시험을 통하여 대기 중의 산소가 유입이 안 되는 기밀성을 확인하였다. 합성가스 압축, 이송 공급 유량 제어 실험 결과로는 합성가스 압축기 기동 시 합성가스 압축압력과 공급유량은 비례적으로 증감하는 것을 알 수 있었다.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2006.11a
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• pp.150-153
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• 2006

Gas generator should be adopted either fuel rich or oxidizer rich combustion because of the temperature restriction to avoid any possible thermal damages to turbine blade. This study focuses to model the non-equilibrium chemical reaction of kerosene/LOx with detailed kinetics developed by Dagaut using Perfectly stirred reactor(PSR) assumption. To predict more reliable species fraction and other gas properties, Frenklach's soot model was added to Dagaut's detailed kinetics.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.11a
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• pp.349-352
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• 2010

This is conceptual study of vitiated air heater(VAH), the necessary ground test facility, for characteristics studies of scramjet combustion and development of scramjet engines. The VAH is one of various types which provided hot air to an intake or a combustion chamber of scramjet and it must use suitable fuel to get hot combustion gas and more similar mixture gas(vitiated air) to real air. In the study, foreign VAHs being capable of providing very high temperature were researched, and injectors for VAH using LNG(CH4) or hydrogen were designed conceptually to develop scramjet vehicle.

• Korean Chemical Engineering Research
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• v.43 no.6
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• pp.728-739
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• 2005

An experiment and simulation were performed for hydrogen separation of mixtures by PSA (pressure swing adsorption) process on activated carbon. The binary ($H_2/Ar$; 80％/ 20％) and ternary ($H_2/Ar/CH_4$; 60％/ 20％/ 20％) mixtures were used to study the effects of feed composition. The cyclic performances such as purity, recovery, and productivity of 2bed-6step PSA process were experimentally and theoretically compared under non-isothermal and non-adiabatic conditions. The develped process produced the hydrogen with 99％ purity and 75％ recovery from both processes. Therefore, optimal separation condition was referred multicomponent gas mixtures.

• Journal of the Korean Chemical Society
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• v.29 no.1
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• pp.45-51
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• 1985

Rate constants and activation parameters for the methanolysis of t-butyl halide (t-BuCl, t-BuBr, t-BuI) in various MeOH-DMSO mixtures were measured by conductometric method. Taft's solvatochromic parameters, such as polarity-polarizability(SPP's), ${\pi}^{\ast}$, hydrogen bond donor (HBD) acidity, ${\alpha}$, and hydrogen bond acceptor (HBA) basicity, ${\beta}$ of the solvents, were determined by the so called solvatochromic method using five indicators. The variation of methanolysis rate with the solvent composition was discussed on the basis of the activation parameters and the correlation of the rates with the solvatochromic parameters. It is concluded that the polarity-polarizability, HBD acidity and HBA basicity of the mixtures had an effect on the ionization of t-butyl halide cooperatively, also that the specific interaction between the leaving groups and the solvents, such as ion-dipole and hydrogen bond acceptor-donor interaction, is the most important factor of solvent effects on the stabilization of transition states.