• Fire Science and Engineering
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• v.28 no.4
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• pp.8-13
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• 2014

In order to improve safety for hydrogen network infrastructure, the ignition temperature by hot wire was investigated for different hydrogen compositions in pipelines. The result shows that minimum temperature for ignition decreased with decreasing hydrogen composition. The minimum temperature was confirmed at a hydrogen composition of approximately 10 vol.%. The one of the reasons is supposed that buoyancy force should generate the convection of gas mixture. It was also found that humidity had a little effect on ignition temperature, flame temperature.

• Fire Science and Engineering
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• v.22 no.3
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• pp.234-238
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• 2008

Autoignition suppression of hydrogen/air premixed mixtures by $CF_3CHFCF_3(HFP)$ was investigated computationally. Numerical simulation was performed in isobaric and homogeneous system to evaluate the induction times. The detailed chemistry of 93 species and 817 reaction mechanism was introduced for hydrogen/air/HFP mixtures. The result of pure hydrogen/air mixture show that the resulting value of induction time depends relatively weakly on the definition used event though there are various criteria for defining the induction time such as the inflection of temperature, OH and $O_2$ concentrations generally. Also, the autoignition temperature of $H_2/air$ mixture is estimated to about 850K, which is corresponds to the literature value. In the case of HFP addition in $H_2/air$ mixture, the results shows that there are several inflection points of radical concentration, and hence it might be to use the temperature for defining ignition delay. When HFP is added to stoichiometric $H_2/air$ mixture, the effect of ignition delay is outstanding above 10% HFP concentration. As HFP concentration increases, both dilution and chemical effects contribute to delay the ignition. Also, the chemical effect on the ignition delay is more considerable with the higher HFP concentration.

• Journal of the Korea Organic Resources Recycling Association
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• v.27 no.4
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• pp.51-59
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• 2019

In this study, the influence of anaerobic digested sludge and 50 mM PBS (phosphate buffer solution) mixing ratio (1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7) on hydrogen production and inoculation period were examined. MECs were operated in fed-batch mode with an applied voltage of 0.9 V. As a result, in the 1:1 mixing ratio reactor, 9.8-20.9 mL of hydrogen was produced with the highest hydrogen content of 66.8-79.6%. Hydrogen gas production and power density increased from after 12 days of inoculation for the 1:1 mixing ratio reactor. In case of 1:2, 1:3 and 1:4 mixing ratio reactor, the hydrogen gas production was 3.7-7.1 mL and the hydrogen gas content was 5.8-65.8%. The hydrogen gas yield in 1:5, 1:6 and 1:7 ratio reactors, was 0.50-0.69 mL and hydrogen content range was 1.8-7.1%. The mixing ratio was found to be suitable for hydrogen production and inoculation period by mixing ratio up to 1:4.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.37 no.4
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• pp.383-391
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• 2009

The detonation wave characteristics of JP-7 and oxygen mixture is investigated by one-step induction parameter model (IPM) obtained from a detailed chemistry mechanism. A general procedure of obtaining reliable one-step kinetics IPM for hydrocarbon mixture from the fully detailed chemistry is described in this study. The IPM is obtained by the reconstruction of the induction time database obtained from a detailed kinetics library. The IPM was confirmed by the comparison of the induction time calculations with that from detailed kinetics. The IPM is later implemented to a fluid dynamics code and applied for the numerical simulation of detonation wave propagation. The numerical results show the detailed characteristics of the detonation wave propagation in JP-7 and oxygen mixture at affordable computing time, which is not be possible by the direct application of the detailed chemical kinetics mechanism of hydrocarbon fuel combustion.

• Journal of Energy Engineering
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• v.12 no.2
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• pp.124-130
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• 2003

In the present study, the combustion characteristics of methane and hydrogen-supplemented methane as alternative fuels for automotive vehicles were investigated at various hydrogen substitution rate, ignition position and ignition methods in a CVCC. As a result, it is possible to decrease the total burning time and to obtain the reduction of NO concentration by using MSCDI device under the lean mixture conditions without deteriorating combustion characteristics such as combustion efficiency, maximum combustion pressure etc.. And by mixing hydrogen into methane, it was found that the reduction of the total burning time was obtained, in comparison with the use of methane only ; and at the same time, the combustion promotion rate was improved remarkably in comparison with the use of methane only.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 1998.10a
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• pp.15-15
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• 1998

마하 수 6 이상인 극초음속 비행에는 스크램제트(SCRamjet : Supersonic Combustion Ramjet) 엔진이 가장 적합한 엔진으로 알려져 있고 현재 미국을 중심으로 이 엔진의 개발에 많은 노력을 기울이고 있다. 스크램제트 엔진의 성공적인 개발을 위해서는 초음속 공기 내에서 연료의 분사를 통한 가장 효율적인 연소를 유도할 수 있어야 한다. 초음속 상태의 공기와 연료의 혼합을 증대시키고 연소안정성을 향상시키는 방법으로 연소기 내에 인위적으로 경사충격파를 발생시키는 방안이 Marble 등에 의해 최초로 도입되었다. 본 연구에서는 스크램제트엔진 내의 연소기를 모델링하여 마하수 2.5의 초음속공기 유동 중앙에 수소 제트를 분사하여 초음속 수소-공기 화염을 만들고 연소기의 측면에 동일한 모양과 크기의 쐐기를 각각 부착시켜 평면 경사충격파를 발생시켰다 본 실험은 충격파가 초음속 화염에 미치는 영향을 연구한 최초의 실험연구이다.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2003.11a
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• pp.45-49
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• 2003

• Proceedings of the Materials Research Society of Korea Conference
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• 2009.05a
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• pp.26.1-26.1
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• 2009

최근 반도체 세정에 있어서 지난 40년 동안 지속적으로 사용되고 있는 알칼라인 기반의 RCA 세정법은 많은 초순수 및 화학액 소모량과 세정시 불필요한 박막의 손실, 환경적인 문제로 인하여 이를 대체하고자 하는 새로운 새정액 및 세정 방법에 대한 연구가 활발하게 이루어지고 있다. 특히 초순수에 가스를 혼합하여 메가소닉을 이용한 기능수 세정은 기존 RCA 세정액의 문제점들을 해결하기 위한 세정액으로 최근 반도체 제조 공정 뿐만 아니라 Photo mask, FPD 세정 공정에서 널리 이용되고 있다. 하지만 기능수에 대한 기초적인 특성 연구와 메가소닉에 의한 세정력 변화에 대한 연구는 부족한 상태이다. 본 연구에서는 고순도의 수소가스(99.999%)를 가스 접촉기, pHasorII (Entigris, USA) 와 순환 속도의 조절이 가능한 펌프, BPS-3 (Levitronix, USA) 를 이용하여 지속적으로 초순수와 수소가스를 혼합하는 방법으로 수소수를 제조하였으며, 용존 수소 농도계, DHDI-1 (TOA-DKK, Japan)으로 수소수의 농도를 확인하였다. 0.1 MPa 압력과, 3 LPM의 수소가스 유출속도에서 최대 2.0 ppm의 수소수를 얻을 수 있었으며, 수소수의 기초 특성을 평가하기 위하여 수소 농도 변화에 따른 pH, 표면 에너지를 측정하였다. 또한 압력 변화에 따른 반감기를 측정하여 bath형태의 세정기에서 적용 가능성을 평가하였다. 수소수의 세정력은 $Si_3N_4$ 입자가 임의로 오염된 실리콘 웨이퍼를 이용하여 bath 및 매엽식 세정기에서 수소수 농도와 메가소닉 형태 및 첨가제 변화에 따른 세정효율을 기존의 SC-1 세정액과 각각 비교 평가하였다. 기능수 발생장치에서 압력이 제거된 상태에서는 평균 20분의 반감기를 갖는 것이 관찰되었고, 압력이 유지된 상태에서는 수소수의 농도가 유지되는 것을 확인하였으며, pH의 경우 수소수의 농도가 점차 증가함에 따라 감소하여 2.0 ppm의 농도에서 pH 5.3정도의 값을 나타내었다. 표면 장력은 초순수와 비교했을 때 큰 변화가 없음을 확인할 수 있었다. Bath 형태의 세정기에서 메가소닉을 인가하여 수소수의 세정효율을 측정한 결과, 같은 조건에서 실험한 초순수와는 비슷하며, SC-1보다는 낮은 세정효율이 측정되었다. 반면 매엽식 세정기에서 동등한 조건의 실험을 실시한 결과, 수소수 세정에서 첨가제에 의한 영향으로 SC-1을 대체할 수 있는 높은 입자 제거효율을 가짐을 확인할 수 있었다.

• Journal of Korea Soil Environment Society
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• v.2 no.3
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• pp.23-30
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• 1997

The purpose of this study was to evaluate effects of solids content and mixing speed in treatment of petroleum hydrocarbon contaminated soils using a slurry-phase bioreactor. Performance results on slurry-phase bioremediation of diesel fuel contaminated soil were generated at the bench-scale level. The fate of TPH(Total Petroleum Hydrocarbon) was evaluated in combination with biological treatment. Abiotic and biotic fate of the TPH were determined using soil not previously exposed to compounds in diesel fuel. The reactor volume for given throughput can be reduced by maximizing the solids content. Applications of 50% and 20% solids content(dry weight basis) were showed a little difference(57.5% : 61.6%) in biological TPH removal rate each other. Mixing and particle suspension are critical to desorption and biological degradation. In this standpoint, this study was performed using two mixing speed. When the reactor was operated at 70rpm, it had a better result in the particle suspension and TPH removal rate than the reactor with mixer rotated at 20rpm. In the reactor applied 20rpm, it was resulted in failure of particle suspension.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.48 no.8
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• pp.589-595
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• 2020

Large eddy simulation (LES) of a partially premixed gas turbine combustor is conducted. Four different hydrogen compositions are considered to investigate the fuel composition effects on the flow field inside the combustor. The comparison with the experimental flame structure and velocity profile is conducted to verify the LES results, revealing that the partially premixed flame structure is altered when hydrogen composition is changed. The flame structure becomes shorter and thicker as the hydrogen composition is increased, and therefore, the flame effect in the rigid wall is minimized. The change in the recirculation zone at the combustor wall with hydrogen addition is further investigated. Overall, the LES with combustion model is quite promising for accurately predicting the reactive flow characteristics in connection with the fuel composition.