• Title/Summary/Keyword: 수소 이온 농도

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Treatability of Heavy Metals in the Washing Technology of Marine Sediments Contaminated with Organic Matter (세척기반처리에 의한 해양오염퇴적물에 함유된 유기 오염물질 제거 공정 중 중금속 처리 가능성)

  • Sim, Young Sub;Kim, Kyoung Rean;Kim, Suk Hyun
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.12
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    • pp.851-857
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    • 2014
  • Treatability of heavy metals in marine sediments contaminated with mainly organic matter was investigated on the basis of washing technology using oxidizers and surfactants. Sediment samples were collected at N area which expected for remediation project of contaminated marine sediment. For additives, hydrogen peroxide ($H_2O_2$) and Tween-80 were used at oxidizer and nonionic surfactant, respectively. In experiments, sediments was mixed with sea water at the ratio of 1 : 3 than $H_2O_2$ (1 M, 3 M, 4 M, 5 M) and Tween-80 (0.05%) were added. Samples were gathered at following reaction time (10, 20, 30, 40, 50, 60, 70, 80 min and 24 h). Total Organic Carbon (TOC) was 55.2% at the conditions of 5 M $H_2O_2+0.05%$ Tween-80 24 h. Hence total heavy metals were Cu 29.5%, Zn 42.3%, Cd 73.0% and bioavailable heavy metals were Cu 60.0%, Zn 77.7%, Cd 90.2% at the conditions of 5 M $H_2O_2+0.05%$ Tween-80 10 min. The correlations for between bioavailable metals (Cu, Zn, Cd) and TOC were significant (Cu, Zn, Cd; $r^2=0.94$, 0.85, 0.69, respectively).

Density Dependent Growth and Survival Rates of Atrina pectinata in Duekryang Bay, Korea (득량만 키조개, Atrina pectinata의 양성밀도에 따른 성장과 생존율)

  • Kim, Dae-Hong;Yoon, Ho-Seop;An, Yun-Keun;Lee, Sa-Dong;Choi, Sang-Duk
    • The Korean Journal of Malacology
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    • v.24 no.2
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    • pp.137-142
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    • 2008
  • Growth and survival rates dependent on the density of a pen sell, Atrina pectinata were measured from Duekryang bay in Korea. Annual water temperature and salinity of the study area were ranged from 14.5 to $28.0^{\circ}C$ and from 27.98 to 31.89 psu, respectively. The pH, DO, COD, DIN, Chl-a and SPM in the study area ranged from 7.78-8.35 mg/L, 7.07-7.90 mg/L, 1.20-1.70 mg/L, 2.88-6.02 mg/L, 0.20-0.79 mg/L and 10.8-21.4 mg/L. The IL, COD and AVS in sediments ranged from 4.0-4.6%, 7.28-10.76 mg/L and 0.03-0.05 mg/L respectively. The daily growth rate of shell height and total weight were 0.27%, 0.33%(5 indiv./$m^2$), 0.26, 0.29%(10 indiv./$m^2$) and 0.21, 0.20%(35 indiv./$m^2$). The survival rate also decreased along the density gradient; highest at the lowest density of 5 indiv./$m^2$ and lowest at the maximum density of 35 indiv./$m^2$.

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The Effect of Carbonated Water on Bovine Enamel Erosion and Plaque Adhesion (시판 탄산수에 의한 우치 법랑질 침식과 침착 효과)

  • Lim, Do-Seon;Ban, Yu-Hee;Min, Young-Eyn;Park, Jin-Joo;Yu, Ye-Jin;In, So-Ra;Ju, Hyun-Ji;Jung, Sun-Young;Hwang, Young Sun
    • Journal of dental hygiene science
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    • v.15 no.4
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    • pp.437-444
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    • 2015
  • Due to the attractive benefits with regard to bone health, digestion, and hydration, carbonated water consumption have rapidly grown over the past few years. However, the acidic drink has latent potential for enamel erosion. The most experimental studies about the enamel erosion have focused on the carbonated beverages with sugar and artificial sweeteners. Here, we determined the enamel erosion potential by commercially available carbonated waters with bovine teeth. The erosion was verified by pH value, calcium concentration, and scanning electron microscope. Then plaque accumulation by bacterial adhesion was determined on the enamel erosion surface to measure roughness. In the present study, we observed that the increased calcium content after being immersed in carbonated waters result from the overall enamel erosion. There were no significant differences between general carbonated waters and mineral waters for erosive capacity. Therefore, commercially available carbonated waters are potentially erosive. In addition, oral bacteria strongly adhered to the erosive enamel surfaces thereby facilitating the development of dental plaque. Thus, it is urgently necessary to provide food safety information on the carbonated water as acidic drink to prevent the enamel erosion.

Experimental Evaluation and Resident's Assessment of Zero Food Waste System in Multi-family Housing Estates (공동주택단지의 음식물쓰레기 제로하우스 시스템 실용화를 위한 현장 시험운영 및 거주자 평가)

  • Oh, Jeongik;Lee, Hyunjeong
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.12
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    • pp.674-681
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    • 2015
  • This research conducts both experimental evaluation and resident's assessment of zero food waste system (ZFWS) in multifamily housing estates in order to explore the feasibility of ZFWS embedded in fermentation and extinction technology utilizing wood chips turned into fertilizer. Having been established in a multifamily housing estate, ZEFWS was proved to be functional and effective. During the 3-month experimental period, the weight between infused food waste and its reactor was reduced significantly enough, and the chemical analysis showed that the concentration of organic compounds went from 87.9% to 75.8%, $H_2O$ decreased from 69.7% to 45.5%, NaCl rose from 0.2% to 0.5%, pH increased from 4.6 to 7.8, and ATP escalated from 505.3 nmol/L to 723.5 nmol/L. Also, the chemical analysis of the output in the experimentation indicated adequacy of the organic fertilizer. In the self-administered questionnaire survey for residents participating in the field project, almost all the respondents viewed that ZFWS can compete with conventional food waste disposal methods and an idealistic way to upcycling food waste into fertilizer.

Case Studies of Geophysical Mapping of Hazard and Contaminated Zones in Abandoned Mine Lands (폐광 부지의 재해 및 오염대 조사관련 물리탐사자료의 고찰)

  • Sim, Min-Sub;Ju, Hyeon-Tae;Kim, Kwan-Soo;Kim, Ji-Soo
    • The Journal of Engineering Geology
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    • v.24 no.4
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    • pp.525-534
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    • 2014
  • Environmental problems typically occurring in abandoned mine lands (AML) include: contaminated and acidic surface water and groundwater; stockpiled waste rock and mill tailings; and ground subsidences due to mining operations. This study examines the effectiveness of various geophysical techniques for mapping potential hazard and contaminated zones. Four AML sites with sedimentation contamination problems, acid mine drainage (AMD) channels, ground subsidence, manmade liner leakage, and buried mine tailings, were selected to examine the applicability of various geophysical methods to the identification of the different types of mine hazards. Geophysical results were correlated to borehole data (core samples, well logs, tomographic profiles, etc.) and water sample data (pH, electrical conductivity (EC), and heavy metal contents). Zones of low electrical resistivity (ER) corresponded to areas contaminated by heavy metals, especially contamination by Cu, Pb, and Zn. The main pathways of AMD leachate were successfully mapped using ER methods (low anomaly peaks), self-potential (SP) curves (negative peaks), and ground penetrating radar (GPR) at shallow penetration depths. Mine cavities were well located based on composite interpretations of ER, seismic tomography, and well-log records; mine cavity locations were also observed in drill core data and using borehole image processing systems (BIPS). Damaged zones in buried manmade liners (used to block descending leachate) were precisely detected by ER mapping, and buried rock waste and tailings piles were characterized by low-velocity zones in seismic refraction data and high-resistivity zones in the ER data.

The Contamination of Groundwater by Acid Mine Drainage in the Vicinity of the Hanchang Coal Mine and the Efficiency of the Passive Treatment System (산성광산배수에 의한 한창탄광 부근 지하수의 오염과 자연정화처리시설 효율에 관한 연구)

  • 지상우;김선준
    • Journal of Soil and Groundwater Environment
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    • v.8 no.2
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    • pp.9-18
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    • 2003
  • Sampling of waters from each stage of treatment system (Successive Alkalinity Producing System; SAPS), tailings seepage, and spring near the Hanchang coal mine of Kangwon Province were carried out seasonally and analyzed to evaluate the source and possible path of groundwater contamination by acid mine drainage (AM). Sulfur isotope compositions were measured to identify the origin of groundwater contaminations and the sulfate reduction processes in the SAPS. Low pH and high metal concentration of spring water indicates possibility of the groundwater contamination by AMD. Removal efficiency of acidity of the SAPS was 18.17 g/$\textrm{m}^2$/day on an average and the metal removal efficiency was almost 100%, which was higher than those of other treatment systems. However, no appreciable decrease of sulfur content and almost similar sulfur isotope compositions of water from each stage of the treatment system may suggest incomplete or very poor sulfate reduction by sulfate reducing bacteria. Chemical and sulfur isotope compositions showed that spring water was contaminated by seepage from mine tailings. And seepage of stonewall, a part of treatment system was affected by both tailings seepage and mine adit drainage. In this study site, the treatment system was constructed for the only AMD from mine adit not for tailings seepages, which resulted in the groundwater contamination from tailing seepages. Similar situation is expected in other abandoned coal mine areas.

A Change of Surface Properties of Carbon Black by Surface Treatment (표면처리에 의한 Carbon Black의 표면물성변화)

  • Lee, Chang-Woo;Lee, Chang-Il;Hong, Young-Ho;Hong, In-Kwon;Jang, Yun-Ho;Hahm, Yeong-Min
    • Applied Chemistry for Engineering
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    • v.7 no.4
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    • pp.768-776
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    • 1996
  • Carbon Black has various advantageous properties such as reinforcement, tinting, weathering, chemical resistance, electrical resistance, etc., but it has poor affinity in the solution. The purpose of this study is to enhance dispersion in the aqueous solution by altering the surface characteristics. Two different treatments were applied for both channel black and furnace black respectively. Channel black was treated in alkaline solution to replace hydrogen of the carboxyl group with alkaline metal, Li, Na, K. Furnace black has few functional groups, and it was treated with $HNO_3$ to increase the number of functional group on carbon black. It was seen that the substitution of alkaline metal on the surface of channel black enhances the degree of dispersion. Also the higher the acid concentration and reaction temperature, the more the number of some functional groups on the furnace black. Reaction time was not seen to be effective.

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Summary on the Dinoflagellate Cyst Assemblages of Modern Sediments from Korean Coastal Waters and Adjoining Sea (한국연안해역 와편모조류 시스트 연구에 관한 고찰)

  • Yoon, Yang Ho;Shin, Hyeon Ho
    • Korean Journal of Environmental Biology
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    • v.31 no.4
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    • pp.243-274
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    • 2013
  • To investigate the research state and characteristics of dinoflagellate cyst along the Korean coastal waters, this work analyzed 45 studies conducted in the Korean coasts and basin, the south of Jeju, East China Sea including some part of the Yellow Sea. It was found that the research on dinoflagellate cyst began in the later half of the 1980s in Korea, and that the research areas focused on eutrophied regions where a red tide occurred or on the seas where coastal development occurred. In other words, no research on the East Sea was found. In terms of research contents, there were various studies on analysis of cyst assemblage, tracking of the changes in marine environment like process of eutrophication, roles as a seed population in occurrence of a red tide, creation of cyst by use of sediment trip and tracking of its changes, morphological changes by the change of pH concentration in the hypoxia zone of eutrophied region, germination of a specific species, and other international-level studies. Species composition and cell density also varied in the Korean coastal waters. However, much research on dinoflagellate cyst in Korea is not systematic, and is fragmentary and individual and hencesuffers from great limitations. The research results so far have focused only on specific regions, and sporadic research had been conducted by specific research groups. Dinoflagellate cyst of surface sediments represents the accumulation index of pelagic environment in the sea and is a useful index to understand the marine environment efficiently. In conclusion, Korea requires organized human resources and collaborative research on dinoflagellate cyst which in turn should be considered as a component of marine ecosystem and as an essential aspect of marine biology.

Studies on the Mucilage of the Root of Abelmoschus Manihot, Medic -[Part VI] The Influence of Microorganism for the Viscosity- (황촉규근(黃蜀葵根) 점액(粘液)에 관한 연구(硏究) -[제육보(第六報)] 황촉규근(黃蜀葵根) 점액(粘液)의 점도변화(粘度變化)에 미치는 미생물(微生物)의 영향(影響)-)

  • On, Doo-Heayn;Kim, Jeong-Myeon;Im, Zei-Bin
    • Applied Biological Chemistry
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    • v.22 no.2
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    • pp.101-108
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    • 1979
  • The viscosity of mucilage of Abelmoschus Manihot, Medic root decreased by the influence of various mechanical, physical and chemical conditions. It was experimented by viscosity decrease of mucilage connected with hydrogen ion concentration, bacterial multiplication, disinfection with 70% ethanol, some antibiotics, such as streptomycin, penicillin, ganamycin and chloramphenicol and mucilage derived from autoclaved Abelmoschus Manihot, Medic root. The results obtained were as follows: 1. It was clear that the viscosify of mucilage decreased notably under the influence of infected bacteria and bacterial multiplication. 2. By the inoculation of Bacillus subtilis ATCC 6633 and Escherichia coli ML 1410 to the mucilage the viscosify decrease fast but the viscosity of mucilage derived from autoclaved, Abelmoschus Manihot, Medic root. 3. The small quantity of reducing sugar in the mucilage was detected. 4. Hydrogan ion concentration in the mucilage remained $6.5{\sim}8.0$ in spite of the viscosity decrease.

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Analytical Method of Multi-Preservatives in Cosmetics using High Performance Liquid Chromatography (HPLC 를 이용한 화장품 중 살균보존제 다성분 동시분석법 연구)

  • Min-Jeong, Lee;Seong-Soo, Kim;Yun-Jeong, Lee;Byeong-Chul, Lee
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.48 no.4
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    • pp.321-330
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    • 2022
  • This study attempted to establish an optimal multi-compound simultaneous analysis method that can secure reliable results for 15 - preservatives, 2 - sun screens and 1 - antioxidants of cosmetics using HPLC-PDA. Since the potential of hydrogen (pH) in the mobile phase affects the acid dissociation constant (pKa) of the preservatives, and the peak retention time shift and area change were observed. The peak separation condition was established by adjusting the pH to 0.1% H3PO4 addition (mL) when preparing the mobile phase. As a results of method validation, the linearity correlation coefficient (R2) of above 0.999 were obtained, and accuracy 87.9 ~ 101.1%, 0.1 ~ 7.6% precision for two types of cosmetics (cream and shampoo). It was found that the limit of detection (LOD) was 0.1 ~ 0.2 mg/kg and the limit of quantitation (LOQ) was 2.0 ~ 4.0 mg/kg. In addition, it was possible to simultaneously separate p-anisic acid, a natural compound that was difficult to separate in HPLC due to the small difference from methylparaben, a synthetic preservatives. Through this study, it will be effectively used to secure quality control and safety for compound that need restrictions on use cosmetics.