• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.5
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• pp.473-479
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• 2013

This study focused on a heavy-duty natural gas engine fuelled with HCNG (CNG: 70 vol%, hydrogen: 30 vol%) and CNG. To study the emission characteristics of an HCNG engine with high compression ratio, the exhaust gas of CNG and HCNG fuel were analyzed in relation to the change in the compression ratio at the half load condition. The results showed that the thermal efficiency improved with an increase in the compression ratio. Consequently, $CO_2$ emission decreased. CO emission increased with inefficient oxidation due to the low exhaust gas temperature. $NO_x$ emission with high compression ratio was increased at the same excess air ratio condition. However, $NO_x$ emission was not affected by a compression ratio exceeding ${\lambda}$ = 1.9 because of the same MBT timing.

• Journal of Energy Engineering
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• v.26 no.4
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• pp.1-6
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• 2017

This study evaluated hydrogen effect of metal and non-metallic materials used in the hydrogen blended natural gas vehicle. Hydrogen penetrated concentration of 34Cr-Mo steel(850MPa tensile strength) for winter driving conditions was measured 0.0018ppm and summer driving conditions was 5.3ppm. The critical hydrogen concentration of high strength metal used in this study was measured 1.03ppm by CLT. Therefore, 34CrMo steel cas cause problems in the 30% HCNG(25MPa) environment. In case of the test for non-metallic materials, all materials met the criteria of the gas resistance test, but Fluorocarbon Rubber material had a significant change in the volume. So if it is used, extra care is needed.

• Journal of the Korean Institute of Gas
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• v.13 no.3
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• pp.28-32
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• 2009

There are two hydrogen supply systems which are central and distributed supply. Central supply system may be cost-effective but huge supply infra cost is needed. For cost-effectiveness, hydrogen supply with existing natural gas pipeline has been focused in Europe. From the analysis results in this study, hydrogen supply method with existing natural gas pipeline is the better for environmental availability including green house effect.

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.264-267
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• 2005

수소의 소규모 분산 생산 기술은 본격적 인 수소 인프라가 도입되기 전에 연료전지 자동차의 수소 충 전용이나 분산 발전형 연료전지의 수소 공급을 위해 필요하다. 생산 용량은 수소 기준으로 $10\~100 Nm^3/hr$ 정도로 현재로선 천연가스의 수증기 개질법이 가장 경제적인 공정으로 알려져 있다. 소규모 생산에 따른 열효율 저하를 줄이 기 위해 단위 공정들이 통합된 컴팩트 개질 시스템의 개발이 필요하다. 핵심 기술인 컴팩트 리포머의 국산화 기술 확보를 위하여 $20 Nm^3/hr$용량의 동심관형 리포머를 설계, 제작하였다. 내부구조는 제작의 단순화를 고려하여 중첩된 동심관이 배열되었고 압력 손실과 열웅력 발생을 억제하도록 유로를 배치하였다. 수증기개질 반응에 필요한 반응열은 리포머 본체에 부착된 버너를 이용하여 공급하였다. 성능 측정을 위한 부속 기기로 상온 흡착식 탈황기, 폐열 회수형 수증기 발생기, 반응물 예열을 위한 열교환기, 생성 가스 응축기를 설계 제작하여 전체 리포밍 시스템을 구성하였다. 반응 온도 $680\~720^{\circ}C$, 탄소 대 수중기 비(S/C ratio) $2.7\~3.2$ 조건에서 수증기 개질 반응을 수행하였다. 해당 반응 조건에서 메탄 전환율 $89\%$ 이상, 저위 발열량 기준 개질 열효율 $70\%$ 이상을 달성하였고 개질 생성가스 내 수소의 최대 유량은 $23.4Nm^3/h$였다. 개발된 리포밍 시스템은 고순도 수소 생산이 필요한 경우, 수소 수율 향상을 위한 고온 수성 가스 전화 반응기를 통합 가능하도록 열교환기 구성을 조정할 수 있으며 용융 탄산염 연료전지와 같이 고온형 연료전지의 경우 $550^{\circ}C$ 이상으로 개질 생성 가스를 공급하도록 구성할 수도 있다. 향후 리포머 본체의 개질 효율 향상 및 장치 소형화, 부속 기기의 최적화를 통한 전체 리포밍 시스템 개선, 스케일 업 설계를 위한 엔지니어링 설계 패키지 구성을 계획하고 있다.

• 한국신재생에너지학회:학술대회논문집
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• 2007.11a
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• pp.75-78
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• 2007

천연가스의 수증기 및 이산화탄소 복합 개질은 탄화수소화합물과 이산화탄소를 원료로 사용하여 수소를 생산하는 공정으로, 온실가스로 지목되고 있는 주요 화합물을 수소와 일산화탄소 혼합 가스로 전환시켜 합성 반응 또는 연료전지에 사용할 수 있도록 해준다. 본 연구에서는 $MgAl_2O_4$를 지지체로 하는 니켈계 촉매를 제조하여 수증기 및 이산화탄소 복합 개질 반응에 사용하였으며, 기존의 수증기 개질촉매 적용 시 문제가 되었던 탄소 침적에 의한 촉매 비활성화를 피할 수 있었다. 개발된 촉매 레시피를 바탕으로 펠릿 촉매를 제조하여 0.1 bpd규모의 Fischer-Tropsch 합성 반응에 적용 가능한 튜브형 반응기에 적용하여 수증기 및 이산화탄소 복합 개질 반응을 실시하였으며, 반응기의 온도 구배, 가스 조성 변화를 관찰하였다. 반응 조건에 따른 촉매 및 반응기의 성능 최적화를 실시하여 최적 촉매 및 반응기 성능을 모색하고자 하였다.

• Journal of the Korean Institute of Gas
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• v.15 no.2
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• pp.1-8
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• 2011

In this research, the safety trends and technologies of HCNG, a mixture of hydrogen and natural gas, are analyzed. This is an attracting alternative fuels to meet the strengthened automotive exhaust gas emission standards. HCNG is very important opportunities and challenges in that it is available the existing CNG infrastructures, meets the strengthened emission standards, and the technical, social bridge of the coming era of hydrogen. It is essential for the commercialization of HCNG that hydrogen - compressed natural gas blended fuel for use in preparation of various safety considerations included accidents scenario, safety distance, hydrogen attack, ignition sources and fire detectors are examined. Risk assessments also are suggested as one of permission procedure for HCNG filling station.

• Economic and Environmental Geology
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• v.48 no.1
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• pp.89-101
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• 2015

The sour gas is natural gas containing components such as hydrogen sulphide and carbon dioxide that form acids when mixed with water. Element sulfur precipitates from sour gas when reservoir pressure and temperature decrease. According to the International Energy Agency, about 43% of the world's natural gas reserves(2,580 tcf or 73.057 tcm), excluding North America, are sour. The sour gas is often derived from the Germanic word 'sauer or acidic' and the etymology referred to as 'sour'. Sour gas requires special handling and infrastructure because it contains significant amounts of hydrogen sulphide, making it highly corrosive, flammable and explosive, and there fore more costly and dangerous to process. So the business of sour gas is affected by two important factors: the economic value of the gas, and the methods used in its production. According to be analyzed in the academic literature to sour gas(2000~2014) by the program of 'web of science', the research activities 145 papers in sour gas.

• Journal of the Korean Professional Engineers Association
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• v.12 no.4
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• pp.26-31
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• 1979

The Natural Gas and petroleum have the same Origin, Namely, Ocean bottom deposits of the marine plant, plankton which are subdued to the biological action of the bacterium under the anaerobic circumstance, and changed to the hydrocarbon gas and oils. and such resources are appeared in the aqueous sedimentary rocks in the tertiary. There are three types of gas field, which are oil well gas field, structural gas field and water soluble gas field.

• Korean Chemical Engineering Research
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• v.53 no.4
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• pp.496-502
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• 2015

Hydrocarbon dew point(HCDP), a property which is the most generally used for describing natural gas condensation, is a very important parameter of natural gas quality specifications. HCDP is strongly influenced by the concentration of the heavier hydrocarbon components, especially $C_6+$, so, along with compliance with gas quality specifications, build up of procedures for obtaining accurate HCDP is essential for gas transmission company, because hydrocarbon condensation present may cause serious operational and safety problems. This study has been carried out in an attempt to measure HCDP accurately by the automatic hydrocarbon dew point meter under the actual field conditions. Measured HCDP also has been compared with calculated HCDP using the composition determined by gas chromatograph and industry accepted equation of state at multiple pressures, along with the cricondentherm. The test results are 1) the automatic hydrocarbon dew point meter was able to measure stable HCDP continuously 2) the automatic hydrocarbon dew point meter has been performed reference measurement by pure propane with a known dew point from literature, and 3) A meaningful differences was observed when comparing the automatic hydrocarbon dew point meter and gas chromatograph results for synthetic standard gas mixtures and real gas mixtures.

• Journal of Welding and Joining
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• v.22 no.2
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• pp.8-12
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• 2004

지하로부터 채굴되는 천연가스의 황화수소(H$_2$S)가스 농도가 일정 수준 이상이면 이를 사우어가스(sour gas)분위기라고 하는데, 이러한 부식성 분위기에 강재가 노출되면 강재 내부에 수소유기균열(hydrogen induced cracking)이 발생할 위험성이 높아진다.(중략)