• Title/Summary/Keyword: 속도 상수

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2차항에 의한 전력조류계산의 개선에 관한 연구

  • Seo, Ui-Seok
    • ETRI Journal
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    • v.5 no.3
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    • pp.26-29
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    • 1983
  • 본 연구에서는 2진수를 사용하여 기억용량의 감소와 테일러 급수의 2차항에 의한 정확하고계산속도가 빠른 전력조류계산방법을 나타낸다. 이 방법은 쟈코비안이 상수이며 2차항의 간단한 계산에 의해 계산속도가 빠르고, 행렬의 비영요소의 위치를 2진수로 나타내어 기억용량을 대폭 감소시킨다. 그리고 정확한 전력조류계산에 의해 신뢰성이 높아 R/X가 큰 송전선의 시스템에도 적절한 방법이다.

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A New Method for Determination of Enzyme Reaction and Activity of Lysozyme with UV-Spectrophotometer (UV-분광광도계를 이용한 새로운 Lysozyme의 효소반응 및 활성측정법 연구)

  • Kim, Woon-Soo;Kim, Yong-Wook;Kim, Woo-Sik
    • Applied Chemistry for Engineering
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    • v.9 no.6
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    • pp.857-863
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    • 1998
  • A simple and new experimental method for determination of lysozyme-M. lysodeikticus cell lysis reaction and lysozyme activity was suggested using Beer's law. The UV transmittance of the solution changed with the concentration of M. lysodeikticus and the relationship between the UV transmittance and M. lysodeikticus cell concentration followed Beer's Law. In addition, it was experimentally proven that the UV transmittance of the solution was not influenced by the lysozyme concentration and product of the lysis reaction. During the lysozyme-M. lysodeikticus cell lysis reaction, thus, M. lysodeikticus cell concentration in the solution could be measured in-situ by UV-spectrophotometer. By using these experimental data, kinetic Parameters of the Michaelis-Menten equation for the lysozyme-M. lysodeikticus cell 1ysis reaction was simply determined The maximum reaction rate constant ($k_3$) and Michaelis-Menten constants were $0.1734sec^{-1}$ and $9.83{\times}10^{-6}M$ respectively. The activity of the lysozyme could also be obtained with this experiment because the lysis reaction rate of the 1ysozyme depended on its activity.

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A Study of New Quick Tool-Life Testing Method (II) - The Developement a New Testing Method of Step-Cutting - (새로운 急速 工具壽命 試驗法에 관한 硏究 II)

  • 오양균;정동윤
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.11 no.1
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    • pp.154-159
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    • 1987
  • In the previously reported Part I, the behavior of the flank wear for carbide tool was studied as a preceeding step to present a simple method for Quick Tool-Life Testing, and the following general equation was obtained $W_{f}$ =(a+bt) $V^{m}$ . In this study the following step-cutting formula for the constants a, b and m in the above general model is derived by using step-cutting data [a numerical formula] To check the validity of the above formula, the comparison is made between the tool-life equation inferred in this method and that inferred in the conventional tool-life testing method, when the wear criterion is 0.3mm. The equation obtained in the present method is V(T')$^{0.57}$=1763 whereas the equation obtained in the conventional tool-life testing method is V(T)$^{0.56}$=1605 The results of the above two formula are satisfactory and also verify the validity of the present research.earch.

The Effect of Pressure on the Iododestannylation between Tetramethyltin and Iodine (Tetramethyltin과 Iodine 사이의 Iododestannylation에 대한 압력의 영향)

  • Kwun, Oh Cheun;Lee, Young Hoon;Jeun, In Seung
    • Journal of the Korean Chemical Society
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    • v.39 no.5
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    • pp.350-355
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    • 1995
  • UV spectrophotometric investigation has been carried out on the system of charge-transfer (CT) complex with iodine and tetramethyltin in carbon tetrachloride solvent. The transient CT absorption spectrum can be observed in ${\lambda}_{max}=270nm$ and the subsequent disappearance of CT absorption spectrum was accompained by the cleavage of tetramethyltin with iodine (iododestannylation). From there, the rate constants for the iododestannylation were determined at 10, 20 and $35^{\circ}C$ up to 1200 bar and the reaction rates were increased with increasing temperature and pressure. From these rate constants, the values of the activation parameters (${\Delta}V^{\neq},\;{\Delta}{\beta}^{\neq},\;{\Delta}H^{\neq}\;and\;{\Delta}S^{\neq}$) were obtained and from these values discussed in terms of solvent structure variation of transition state and mechanism. From these results, it was found that the reaction is followed with $S_F2$ mechanism and weakened $S_F2$ mechanism nature by increasing pressure.

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Kinetics Study of the Reaction of Bromine with Phenylhydrazine in Sulfuric Acid Media (페닐히드라진과 브롬의 반응메카니즘에 관한 연구)

  • Park Byoung Bin;Park Il H.;Kong Young Kun;Choi Q. Won
    • Journal of the Korean Chemical Society
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    • v.21 no.4
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    • pp.227-234
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    • 1977
  • The reaction of phenylhydrazine with bromine in sulfuric acid solution has been studied kinetically. The pseudo-second-order rate constant is approximately inversely proportional to hydrogen-ion concentration when the concentration of sulfuric acid is lower than 1M. arom the study of the effect of potassium bromide concentration on the rate constant, it is concluded that both neutral bromine and tribromide ion participate in the reaction, the rate constants in 0.01M $H_2SO_4$ being $5{\times}10^5M^{-1},sec^{-1}\;and\;0. 7{\times}10^5M^{-1},sec^{-1}$, respectively at $20^{\circ}C$. The pseudo-second-order rate constant of 2.4-dinitrophenylhydrazine-bromine reaction is independent of hydrogen ion concentration. From the KBr addition experiment, the rate constants for $Br_2\;and\;Br_3^-$ were obtained as $1.2{\times}10^5M^{-1},sec^{-1}\;and\;2.0{\times}10^4M^{-1},sec^{-1}$, respectively.

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The Characteristics of the Dehydration Reaction and the Durability for the Thermal Decomposition in Na2B4O7·10H2O/Na2B4O7·5H2O System (Na2B4O7·10H2O/Na2B4O7·5H2O 계의 열분해 탈수반응 및 내구성 고찰)

  • Choi, Ho-Sang;Park, Young-Tae
    • Applied Chemistry for Engineering
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    • v.10 no.6
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    • pp.885-888
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    • 1999
  • This study was carried out to determine the reaction kinetic constant of the dehydration - thermal decomposition of $Na_2B_4O_7{\cdot}10H_2O/Na_2B_4O_7{\cdot}5H_2O$ and to investigate the durability during the repeated use of a chemical heat-storage material and the reproducibility of reaction system. The order of the dehydration reaction was 1st-order. The reaction rate was directly proportional to a partial pressure difference of water steam. The kinetic constant was 0.27 and the reproducibility of dehydration reaction for a kinetic constant and a reaction order was excellent. The activity variation in the durability test of a chemical heat-storage material was within range of ${\pm}5%$ during the repeatedly use in several times.

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Adsorption Kinetic Constants for Basic Odorant on Pellet-type Adsorbents Recycled from Water-treatment Sludge (정수 슬러지를 재활용한 펠렛형 흡착제 상에서 염기성 악취 물질의 흡착속도상수)

  • Kim, Goun;Park, Nayoung;Bae, Junghyun;Jeon, Jong-Ki;Lee, Choul Ho
    • Applied Chemistry for Engineering
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    • v.25 no.2
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    • pp.167-173
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    • 2014
  • The adsorption characteristics of the pellet-type adsorbent prepared from water treatment sludge for trimethylamine and ammonia were studied. The surface area and pore volume of the pellet-type adsorbent increased during calcination at $500^{\circ}C$. It was confirmed that the adsorbent prepared from water treatment sludge contained Br$\ddot{o}$nsted and Lewis acid sites. The breakthrough time of the adsorbent for both trimethylamine and ammonia was measured at different adsorbent weights and linear velocities while maintaining constant amounts of trimethylamine and ammonia. The kinetic saturation capacity and the adsorption rate constant for trimethylamine and ammonia were determined at different linear velocities by using the Wheeler equation. It was found that the kinetic saturation capacity and the adsorption rate constant were dependent on the linear velocity. An experimental equation could be derived to predict the breakthrough time of the adsorbent prepared from water treatment sludge for trimethylamine and ammonia at different adsorption conditions.