• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2001.06a
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• pp.162-177
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• 2001

The hydrolysis rates of seven kinds of polyol ester base oils 〔POEs〕 of different branch shape were investigated by using a simple apparatus under mild acidic condition. Seven polyol ester base oils were made of poly hydric alcohols of two-four valence, normal or branched fatty acids of different carbon number. p-Toluene sulfonic acid was used as acid catalyst to accelerate the rate of hydrolysis. Partial esters and fatty acid produced by sequential hydrolysis of POEs were identified and their concentrations were determined by calibrated-internal standard method using Gas Chromatography. The rate constants of each step in sequential hydrolysis were determined by the least square method from rate equation and the concentration of each component, were compared with one another. It was shown that the rate of hydrolysis of POEs was strongly affected by whether molecular structure of fatty acid was straight chain or branch chain and which position was branched. The hydrolysis stability for all the POEs can be reasonably explained by using a steric hindrance effect anticipated fi:om their molecular structures affecting as water molecule makes an attack on the carbonyl carbon of POEs.

• The Journal of the Korea institute of electronic communication sciences
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• v.4 no.3
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• pp.224-229
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• 2009

In this paper, an efficient signal interference control technique to improve the convergence speed of Adaptive transversal filter with LMS algorithm is introduced. The convergence characteristics of the proposed algorithm, whose coefficients are multiply adapted in a symbol time period by recycling the received data, are analyzed to prove theoretically the improvement of convergence speed. According as the step-size parameter ${\mu}$ is increased, the rate of convergence of the algorithm is controlled. Increasing the eigenvalue spread has the effect of controlling down the rate of convergence of the adaptive equalizer and also increasing the steady-state value of the average squared error and also demonstrate the superiority of signal interference control to the filter algorithm increasing convergence speed by (B+1) times due to the data-recycling LMS Algorithms.

• Journal of the Korea Convergence Society
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• v.8 no.8
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• pp.325-332
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• 2017

This study was performed to investigate the effects of receiver's moving speed and pass types on anticipation timing response. Ten subjects were required to make a total of 24 passes in coincidence with an experimentally manipulated moving light signal in randomly three different conditions by performing chest and bound pass. Results of analyses revealed AE, CE, and VE increased as moving velocity became constant-acceleration condition. In addition, chest pass was more accuracy and consistency than bound pass on AE and CE. These findings indicated that moving velocity and pass type served as the major determination of coincident timing response on passing in basketball.

• The Korean Journal of Applied Statistics
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• v.30 no.5
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• pp.719-731
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• 2017

In September 2010, the Korea government increased the speed limit on the Gyeongbu Expressway (Cheonan IC.-Yangjae IC) from 100 to 110 km per hour. This paper considers ARIMA-Intervention model to analyze the effects of the speed limit change on the incidences of traffic accidents and injuries. In addition, in order to investigate the effects more clearly, we also analyze the difference between the two lines of Cheonan IC-Yangjae IC and Busan IC-Cheonan IC. As a result, we observe that the numbers of accidents and injuries have increased after the speed limit change. The increases are strikingly distinctive in comparison to other lines (Busan IC-Cheonan IC) where there have been no changes in the maximum speed limit.

• Tunnel and Underground Space
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• v.20 no.2
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• pp.119-124
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• 2010

Hopkinson's effect tests were carried out for various strain rates on three different types of rock in both saturated and dry states in order to examine the effects of strain rate and water saturation on tensile strength. The tensile strength increased with the increase of the strain rate not only in dry state but also in saturated state. It was also especially recognizable that the dynamic tensile strength of rock in the dry state was proportional to approximately a one-third multiple of strain rate no matter what the type of rock. It was found that water saturation decreased tensile strength in the dry state of sandstone and tuff, both with high porosity, but no significant difference could be recognized between the dry and the saturated states of granite, which has a low porosity of 0.49%.

• Microbiology and Biotechnology Letters
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• v.26 no.5
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• pp.465-469
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• 1998

The quantitative and rapid method for measuring the biodegradation of polymer materials in soil was developed. In this study, cellophane film was used as a model biodegradable polymer and the biodegradation was assayed by measuring the amount of glucose which was produced by a hydrolysis reaction using HCl after collecting the film from soil. Cellophane film was degraded 41.2% in 4 months during winter while it was degraded 76.5% in 2 months during summer. It means that biodegradation in soil is affected by environmental conditions. The biodegradation was also measured in an incubator (30$^{\circ}C$, humidity 50-55%) to exclude the environmental variations. Cellophane film was degraded 94% in that condition in 40 days. The biodegradation showed the first order kinetics and the rate constant was 0.067 (1/day). Acceleration of the biodegradation in soil was also studied. We added cultured soil microorganisms or nutrients such as N, P, and S into the soil. While the addition of microorganisms showed the temporary increase of rate constant, the addition of nutrients not only showed the increase of rate constant from 0.096 (1/day) to 0.21 (1/day) but also maintained the effect continuously.

• Journal of the Korean Chemical Society
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• v.40 no.2
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• pp.128-134
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• 1996

The kinetics of the hydrolysis of dihydro-1, 4-oxathiin derivatives were investigated by ultraviolet spectrophotometry in H2O at $25^{\circ}C.$ A rate equation which can be applied over a wide pH range was obtained. The substituent effects on the hydrolysis of dihydro-1, 4-oxathiin derivatives were studied and the rate of hydrolysis was shown to be accelerated by electron accepting groups. Final product of the hydrolysis was 2-(2-hydroxyethylthio)acetoacet-anilide enol form. On the basis of rate equations derived and judging from hydrolysis products obtained and from general base effect and substituent effects, plausible mechanism of the hydrolysis in various pH range have been proposed. Below pH 3.5, the hydrolysis was initiated by the protonation and followed by the addition of water to 2-carbon. Above pH 10.0, the hydrolysis was proceeded by the addition of hydroxide to 2-carbon. In the range of pH 4.0∼10.0, the addition of water to dihydro-1,4-oxathiin is rate controlling step.

• The Journal of the Korea Contents Association
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• v.19 no.4
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• pp.403-412
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• 2019

There has been a lively debate between self-employed and wage workers on the speed of minimum wage hikes. Minimum wage is a redistributive policy that evokes confrontation and conflict whereby individuals' views on the policy coincide with their material self-interest. With this in mind, the researcher analyzed whether an individual's labor market status was explanatory to his/her view on the speed of minimum wage hike. Moreover, in light of the likelihood that the varying degree to which self-employed can afford minimum wage hike affects their differential preferences for the policy, the researcher attempted to identify whether there was a moderation effect of income class on the relationship. In the actual analysis, the researcher investigated employment policy survey dataset using a multinomial logit model. The results suggest that, among self-employed, 'gradual increase' and 'rapid increase' of minimum wages are less preferred $vis-{\grave{a}}-vis$ 'minimal increase,' which is the reference. As to the moderation effect, when a self-employed has a middle-income class status, his/her negative preference for the policy is likely to be attenuated. One implication of this study is that subsidizing self-employed small business owners, who are most dissatisfied with the current speed at which minimum wages rise, would be an effective prescription on reducing social conflicts.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 1997.04a
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• pp.63-72
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• 1997

본 논문은 분사제트 주위에 형성되는 와류를 조절하여 제트를 제어하기 위하여 유동가시화, 속도분포 및 난류성분을 측정하는 실험을 수행하였다. 와류를 조절하기 위한 방법으로 제트노즐 주위에 환형관을 설치하여 환형관으로부터 2차제트를 분사 또는 흡입함으로써 제트주위에 형성되는 전단류를 변화시켰다. 2차제트 분사시 주제트 주위에 형성되는 와류의 발달을 억제함으로써 제트 포텐셜코어의 길이가 아주 길어지는 제트유동을 얻을 수 있었다. 환형관으로부터 주제트주위의 유체를 흡입하는 경우 제트주위의 전단류가 흡입비 R=1.3∼l.65에서 대류불안정성에서 절대불안정성으로 바뀜으로써 형성된 와류가 하류에서 제트중심부까지 발전, 결합되는 것을 방지하여 더 긴포텐셜코어와 중심에서 낮은 난류강도를 얻었다. 위의 결과는 환형관 주위에 부착한 깃의 높이 변화에 따라서 변화하였는데, 이것은 깃이 환형관을 통한 흡입유동의 유로역할을 함으로써 제트밖으로부터 흡입되는 것을 방지할 수 있었다. 분사제트 벡터링을 위하여 제트노즐 주위의 환형관을 이등분하여 한쪽으로만 제트주위의 유동을 흡입함으로써 제트주위에 다른 전단류를 형성함과 동시에 Coanda효과를 이용하여 분사제트를 편향시켰다. 편향되는 정도 및 난류성분은 홉입속도 비에 따라서 크게 바뀌었다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2017.05a
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• pp.67.1-67.1
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• 2017

구리는 탄성이방성이 큰 재료로 Si 박막상에 성장시키면 (111) 방향으로 우선 배향된 박막을 얻을 수 있다. 본 연구는 이러한 (111) 우선 방위를 갖는 Cu 박막의 전기도금층의 재결정 후의 매우 평탄한 표면을 갖는 박막에서 에칭에 따른 박막의 단차와 표면형상을 통해 결정방위별 에칭 특성을 비교 분석한 결과이다. 10 vol% 질산용액에서 에칭한 결과는 구리의 용해에 따라 각 결정면에 대한 고유의 facetted surface morphology를 나타내며, 대표적인 결정 방위인 (111), (110), (100)에 대해 triangular flake, ridge and rectangular pyramidal shapes을 나타내는 것을 알 수 있었다. 에칭속도의 정량적 측정을 위해 120초간 2.2M 농도의 질산용액으로 에칭을 실시하였고, nanosize의 as-plated initial region, (111), (110), (100) oriented regions의 각각에서 383, 270, 276, 317 nm/min의 에칭속도를 갖는 것을 확인하였다. Facet surface의 관찰을 통해 에칭반응이 (111) front surface를 갖는 열역학적 평형상태에서 일어나며, 이러한 결정방위별 에칭속도 차이는 각 결정S면이 갖는 Kink or ledge의 밀도의 차이에 기인할 것으로 판단된다. 즉, 에칭이 평형상태에서 step flow mechanism에 의해 열역학적 평형상태를 유지하면서 진행이 된다. 본 연구는 향후 다양한 에칭관련 용액 효과, 구리 박막의 응력 및 불순물에 의한 효과를 볼 수 있는 기본 방법을 제공해 줄 것으로 기대한다.