• Journal of the korean Society of Automotive Engineers
• /
• v.18 no.5
• /
• pp.53-68
• /
• 1996

마그네슘이 자동차 경량화에 관심이 되는 이유는 근본적으로 CAFE 규제와 같이 경량화를 통한 화석연료의 소모를 크게 억제해야 한다는 사회적인 규제이나, 지난 10여년간의 기술발전으로 내식성이 나쁘다거나 취급이 위험한 금속이라는 인식이 크게 개선된 데에도 있다. 다른 경량금속에 대한 Mg 지금 가격의 비교조건이 호전되었고 향후 원소 재공급의 다변화가 추진되고 있는 것도 환경을 변화시킨 중요한 요인이다. 그간 중요한 경량화 대체 재료로 연구투자가 많았던 유기고분자 재료 및 FRP 등과 같은 복합재료는 폐기부품의 재활용이 어려움 때문에 호나경친화적인 단점이 부각되어, 이 소재의 증가가 주춤해 있다. 마그네슘의 경우에는 재활용이 가능하고, 진동흡수효과가 매우 커서 소음발생을 크게 줄일 뿐만 아니라, 주행 및 내구성시험에서 치수안정성이 좋고 많은 종류의 전자기기 사용에 의한 전자파 차폐효과도 큰 장점을 가지고 있다. 본 고에서는 Mg 다이캐스팅으로 자동차부품의 경량화 현황과 선진국에서 보는 전망을 미국을 중심으로 정리하고, 이와 관련한 Mg 다이캐스팅으로 자동차부품의 경량화 현황과 선진국에서 보는 전망을 미국을 중심으로 정리하고, 이와 관련한 Mg 기술적인 이슈와 시장전망도 서술하였다. 그리고 현재 우리나라의 연구계와 부품업계에서 추진하고 있는 연구개발 동향을 자동차 업계에 소개하는 의미도 있다. 이처럼 우리나라의 현황을 정리해 보는 것은 국내 자동차 산업이 국제적인 경쟁을 하고 있고 Mg기술과 원료확보에서 일본의 견제를 받고 있는 우리의 현실에서도 필요한 작업으로 생각된다.값들로 구성되는 형상을 내구 성능, 성형성등을 고려하여 최종 형상으로 결정한다. 내구성능의 예측은 금속부품의 내구수명 예측에 널리 이용되고 있는 방법이 방진 고무부품의 경우에도 적용 가능한지를 검토하고, 방진 고무부품에도 일반적으로 적용될수 있는 내구수명 예측방안의 개발 가능성을 타진해 보았다. 본 연구의 목표는 시제품을 제작하기 이전에 설계된 부품에 대한 스프링 상수 및 내구특성을 체계적으로 규명하여 제품 시험의 횟수를 줄이고, 보다 정밀한 제품을 제작할 수 있도록 하기 위한 것이다.세포수는 초기 배반포기배에서 팽윤 배반포기배로 진행됨에 따라 두배에서 세배 정도 증가되었음을 알 수 있었다. 또한, differential labelling과 bisbenzimide기법에서 얻어진 각각의 총세포수를 비교하였을 때 총세포수는 발달의 진행 정도에 따라 증가되며 그와 동시에 동일한 군 간의 세포수도 거의 유사함을 알 수 있었다. 따라서, ICM과 TE를 differential labelling하는 기법은 수정란의 quality를 평가하는데 매우 유용한 기법으로서 착상전 embryo 발달을 연구하는데 효과적으로 이용될 수 있다는 것을 시사한다. 고도의 유의차를 나타낸 반면 비수구, 초생수로구 및 Bromegrass 목초구 간에는 아무런 유의차가 인정되지 않았다. 7. 농지보전 처리구인 배수구와 초생수로구는 비처리구에 비해 낮은 침두 유출량과 낮은 토양유실량을 나타내었다.구보다 14% 절감되는 것으로 나타났다.작용하는 것으로 사료된다.된다.정량 분석한 결과이다. 시편의 조성은 33.6 at%

• Resources Recycling
• /
• v.31 no.1
• /
• pp.46-55
• /
• 2022

The recycling of coated cemented carbide scraps is becoming increasingly significant for the recovery of rare metals. However, coatings consisting of Group IV and V transition metal nitrides are one of the challenging factors in obtaining high-purity materials. We investigated the structural, elastic, and mechanical properties of Group IV and V transition-metal nitrides (TiN, VN, ZrN, NbN, HfN, and TaN) using first-principle calculations. Convergence tests were performed to obtain reliable calculated results. The equilibrium structures of the nitrides were in good agreement with those of a previous study, indicating the reliability of the data. Group IV transition metal nitrides show a higher covalent bonding nature. Thus, they exhibit a higher degree of brittleness than that of Group V transition metal nitrides. In contrast, Group V transition metal nitrides show weaker resistance to shear loading and more ductile behavior than Group IV transition metal nitrides because of the metallic bonds characterized by valence electron concentration. The results of the crystal orbital Hamilton population analysis showed good agreement with the shear resistance tendencies of all transition metal nitrides.

• Science of Emotion and Sensibility
• /
• v.26 no.1
• /
• pp.79-86
• /
• 2023

This study aims to create a highly conductive E-textile made by recycling PET with a Dip-coating process. PET fiber with hydrophobic properties is characterized by the difficulty in imparting great conductivity when both Virgin and Recycled are made of electronic fibers through a Dip-coating process. To advance the effectiveness of the Dip-coating process, a sample made of recycled PET was surface modified for 50 w 5 minutes and 10 minutes employing a Covance-2mprfq model from FEMTO SCIENCE. After that, the sample was immersed in an SWCNT dispersion (.1 wt%, Carbon Co., Ltd.) for 5 minutes, and then dip coating was conducted to allow the solution to permeate well into the sample through a padder (DAELIM lab). After the procedure was completed, the resistance measurement was measured with a multimeter at both ends and then accurately remeasured with a wider electrode. As a result of this contemplation, it was affirmed that great conductivity might be given through an impregnation process through the plasma surface modification. When the surface modification was performed for 10 minutes, the resistance was reduced by up to 2.880 times. Dependent on the results of this research, E-fibers employed in the smart wearable sector can also be made of recycled materials, improving smart wearable products that can save oil resources and reduce carbon emissions.

• Resources Recycling
• /
• v.28 no.5
• /
• pp.60-67
• /
• 2019

A valuable metal recovery from waste resources such as spent rechargeable secondary batteries is of critical issues because of a sharp increase in the amount of waste resources. In this context, it is necessary to research not only recycling waste lithium-ion batteries (LIBs), but also reusing valuable metals (e.g., Li, Co, Ni, Mn etc.) recovered from waste LIBs. In particular, the lithium hydroxide ($LiOH{\cdot}xH_2O$), which is of precursors that can be prepared by the recovery of Li in waste LIBs, can be reused as a catalyst, a carbon dioxide absorbent, and again as a precursor for cathode materials of LIB. However, most studies of recycling the waste LIBs have been focused on the preparation of lithium carbonate with a recovery of Li. Herein, we show the preparation of high purity lithium hydroxide powder along with the precipitation process, and the systematic study to find an optimum condition is also carried out. The lithium carbonate, which is recovered from waste LIBs, was used as starting materials for synthesis of lithium hydroxide. The optimum precipitation conditions for the preparation of LiOH were found as follows: based on stirring, reaction temperature $90^{\circ}C$, reaction time 3 hr, precursor ratio 1:1. To synthesize uniform and high purity lithium hydroxide, 2-step precipitation process was additionally performed, and consequently, high purity $LiOH{\cdot}xH_2O$ powder was obtained.

• Economic and Environmental Geology
• /
• v.37 no.1
• /
• pp.143-151
• /
• 2004

This study focused on examining the possibility of recycling mine solid waste as environmental materials, especially for porous media. Basic properties including mineralogical compositions, chemical compositions, and particle size distribution of the tailings from the Sangdong W mine were checked. The mineralogical and chemical compositions of the tailings samples were not much different in depth. According to Korean Standard Leaching Test for Wastes(KSLT), concentrations of heavy metals leached from the tailings were below the standard values. As a result of particle size analysis, the median diameter (d$_{50}$) of the tailings was in the range of 10 to 30 ${\mu}{\textrm}{m}$. The stable tailings slurry made up of 3 ${\mu}{\textrm}{m}$ in d$_{50}$ was prepared using Attrition Mill. The milling condition was 40 vol% in slurry concentration, 700 rpm in stirring speed, and 1 hour in milling time. PEI was added as dispersing agent. Concentrated slurry was extended to 3 times by foaming method. In the case of 3 times foamed slurry, the total and open porosity of ceramic supports sintered at 1,075$^{\circ}C$ for 90 minutes was about 80% and 72%, respectively. Pore size was in the range of 30∼350${\mu}{\textrm}{m}$. Therefore, the tailings could be recycled starting material for environmental materials such as macroporous ceramic support.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.8 no.4
• /
• pp.93-99
• /
• 2000

Treatment of shaving scrap, a chrome containing solid scrap generated by leather manufacturing process, has been so far depended on mainly incineration, soil landfill and ocean dumping, which give bad impact on environment and cause pollution. Shaving scrap generates from the mechanical work for controlling the final thickness of leather and its main components are collagen protein and pan of chromium compound. For the purpose of reusing this leather waste as resources, researches in connection with collagen fiber recovery, gelable protein recovery and liquid fertilizer is being speedily progressed. In the experiment, shaving scrap went through wet pulverizing treatment by physical and chemical methods. Then, making the leather sheet evenly, it is mixed with natural latex and every kind of binding materials in the container, and the mixtures were passed through experimental hydraulic press machine and applied to Fourdrinier machine respectively. Lastly, a test for fading out physical strength and properties of multiple-purpose of leather-like material was performed on a continuous leather sheet prepared by the experiment. In result, the physical strength and properties of leather-like material showed noticeable differences according to mixing ratio of binding materials, beating methods and the Ends of binding materials selected, and generally tear strength was the weakest property among others. Also, by the pilot scale experiment in sequence, it was possible to manufacture recycled goods made of soft and hard types of leather-like material with various performances.

• Applied Chemistry for Engineering
• /
• v.34 no.5
• /
• pp.515-521
• /
• 2023

In this study, waste carbon fiber obtained by pyrolysis of carbon fiber reinforced plastic (CFRP) was used to produce carbon fluoride through vapor phase fluorination and recycled as a reducing electrode material for lithium primary batteries. First, the physicochemical properties of the waste carbon fiber obtained by pyrolysis were determined, and the structural and chemical properties of carbon fluoride were analyzed to evaluate the effect of vapor phase fluorination on the waste carbon fiber. XRD analysis confirmed that the hexagonal network carbon laminated structure (002 peak) of the waste carbon fiber was gradually converted into a carbon fluoride structure (CF_X, 001 peak) as the temperature of gas phase fluorination increased. The discharge capacity of the lithium primary battery produced using this carbon fluoride was up to 862 mAh/g. This was compared to the discharge capacity of carbon fluoride-based Li-ion batteries made of other carbon materials. These results suggest that carbon fluoride made from waste CFRP-based carbon fibers can be used as a reducing electrode material for Li-ion batteries.

• Journal of the Korea Convergence Society
• /
• v.8 no.2
• /
• pp.113-120
• /
• 2017

The purpose of this present study was to evaluate the surface radiation dose reduction and radiograph artifact images in computed tomography (CT) for the manufactured radiation shields by using sea-shells. The radiation convergence shields were made from silicons, sea-shells, barium powders, producted circle types of diameter 50 mm, thickness 3.5 mm for 5 kinds (only silicon shield, only barium shield, mixed sea-shells with silicon shield, mixed barium with silicon shield, mixed sea-shells with barium and silicon shield). Radiation generation and acquisition were used 4-channel multi-detector CT. The results of this study showed that mixed sea-shells with silicon shields could reduce the surface dose of 5.3% without radiograph artifact images. In the future, we will expect the radiation convergence shield as environmentally friendly materials by using the recycling of sea-shells with the advantages of silicon which can make various shapes.

• Applied Chemistry for Engineering
• /
• v.10 no.1
• /
• pp.118-123
• /
• 1999

The recycle of the polycarbonate(PC)/acrylonitrile-butadiene-styrene(ABS) separated from the instrument panel (In-Panel) of the automotive was investigated. The small amount of polyurethane(PU) foam contained in the separated PC/ABS decreased the mechanical properties of the recycled PC/ABS. However, it is found that the PU foam formed the dispered phase of small particles at high temperature ($260^{\circ}C$) under high shear of the twin extruder, whereas it formed the big particles at low extrusion temperature ($220^{\circ}C$). The mechanical properties of the recycled PC/ABS extruded at high temperature was better than those at low temperature, which enabled the recycled PC/ABS seperated from In-Panel to be applied to the radiator grille without the addition of the compatibilizers or virgin PC/ABS. This was ascribed to the smaller particle sizes of the PU foam formed at high extrusion temperature under high shear.

• 한국신재생에너지학회:학술대회논문집
• /
• 2005.06a
• /
• pp.487-490
• /
• 2005

재생 가능한 자원인 동식물성 기름으로부터 만들어지는 수송용 연료 바이오디젤은 낮은 대기오염물질 배출과 $CO_2$ Neutral 특성으로 환경친화적인 연료로 인정올 받으며 전세계적으로 그 생산량이 급격히 증가하고 있다 한국에서는 년간 20만톤의 폐식용유가 배출되며 이중 약 10만톤이 회수 가능한 것으로 추산된다. 폐식용유의 무단 폐기로 인한 수질오염과 폐기물의 자원 재활용 및 에너지 생산 관점에서 폐식용유를 바이오디젤 원료로 사용하는 연구가 많이 진행되었다. 높은 함량의 유리지방산을 함유한 폐식용유를 효율적으로 전이에스테르화(methanolysis) 하기 위해서는 먼저 산 촉매를 이용한 유리지방산의 전환 제거가 필요하다 본 연구에서는 다양한 종류의 강산성 이온교환 수지를 폐식용유의 전처리(pre-esterification)용 고체 산 촉매로 회분식 반응기에서 테스트하였으며 그 결과 Amberlyst-15가 유리지방산의 에스테르화 반응에 가장 적합한 것으로 나타났다. 회분식 반응기에서 도출된 최적 전처리 반응조건을 적용한 200시간 이상의 연속 전처리 운전결과 폐식용유에 함유된 $5\%$의 유리지방산이 $90\%$이상 전환제거 되었다 전처리 반응 후의 폐식용유를 균질계 염기촉매(KOH) 존재하에 메탄올과 전이에스테르화 반응을 시킨 결과 바이오디젤로 불리는 지방산메틸에스테르(Fatty Acid Methyl Ester, FAME)의 생산 수율은 $85\%$로 얻어졌으며 국내 바이오디젤 표준 규격에 따른 연료특성 분석 결과 FAME의 농도 규격을 제외한 모든 항목이 국내 규격을 만족하였다 폐식용유 바이오디젤의 FAME 농도가 $94.3\%$로 국내 규격$96.5\%$에 미달하는 문제는 식물성 원료유로 제조한 고순도 바이오디젤과 혼합 사용하거나 감압 증류 공정을 통해 고농도의 폐식용유 바이오디젤을 제조하여 해결 가능하다. 대전시 신성동 소재의 음식점에서 수거한 폐식용유를 원료로 하여 생산한 바이오디젤의 차량 배출가스 실증 테스트 결과 경유 차량의 주 오염물질인 PM과 Soot 및 기타 오염물질의 배출량은 감소하였으나 NOx의 배출량은 약간 증가하는 것으로 나타났다