• Title/Summary/Keyword: 소성 점도

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Development of Nano Carbon Tile for Far-Infrared Thermotherapy Effect (원적외선 온열효과를 위한 나노탄소타일 개발)

  • Yoon, Dal-Hwan;Uhm, Woo-Yong
    • Journal of IKEEE
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    • v.21 no.1
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    • pp.24-29
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    • 2017
  • In this paper, we have developed the nano carbon tile and chip which is based on a reducing process of oxidation and the viscous fluid control, after hardening to the stylene monomer and methylol acrylamide monomer using an acrylic emulsion junction material. Then we can obtain the sphere form structure of diagonal 1~3 mm, they have mixture the acrylic emulsion junction material(45%) and the coconut carbon powder(55%) of size 300~500 mesh for 25~30 min. Finally, if we have dry for the formated carbon including 30~90 minute at $90{\sim}300^{\circ}C$, then be obtained for pure carbon formation of 95%. In order to identify the safety of the friendly circumstance carbon formation, we have tested the far-infrared ratio, energy analysis, gas density and anti-disease germs experiment.

Adsorption Performance of Basic Gas over Pellet-type Adsorbents Prepared from Water Treatment Sludge (정수장 슬러지로부터 제조한 입상흡착제의 염기성 가스 흡착 성능)

  • Bae, Junghyun;Park, Nayoung;Lee, Choul Ho;Park, Young-Kwon;Jeon, Jong-Ki
    • Korean Chemical Engineering Research
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    • v.51 no.3
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    • pp.352-357
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    • 2013
  • In this study, the pellet-type adsorbents were prepared by extrusion using water treatment sludge. Effects of binder and calcination on physical and chemical properties of pellet-type adsorbents were investigated. The porous structure and surface characteristics of the adsorbents were studied using nitrogen adsorption, compression strength, scanning electron microscope, X-ray diffraction, and infrared spectroscopy of adsorbed pyridine. With increasing of binder content to 5 wt%, the compressive strength of pellet-type adsorbent could be improved more than three times, but the surface area reduced by 30%, and thus the breakthrough time of trimethylamine was shortened. The breakthrough time of the trimethylamine, a basic gas, could be increased more than three times through calcination, which seems to be due to generation of acid sites composed of Lewis acid and Br$\ddot{o}$nsted acid sites on the adsorbent surface.

Flexural Behavior and Design of Concrete-filled U-shape Hybrid Composite Beams Fabricated from 570MPa High-strength Steel (570MPa급 고강도강을 적용한 콘크리트 채움 U형 하이브리드 합성보의 휨거동 및 설계)

  • Lee, Cheol Ho;So, Hyun Joon;Park, Chang Hee;Lee, Chang Nam;Lee, Seung Hwan;Oh, Ha Nool
    • Journal of Korean Society of Steel Construction
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    • v.28 no.2
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    • pp.109-120
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    • 2016
  • Flexural tests of full-scale concrete-filled U-shape hybrid composite beams were conducted. Ordinary (SS400) and high-strength (SM570) steel plates were used in the web and in the bottom flange of U-shape steel section respectively. The primary objectives were to develop the hybrid section configuration with maximized flexural capacity and to investigate its flexural strength and deformation capacity. All the hybrid test specimens in this study exhibited the plastic moment capacity and resonable deformability. It is shown that the plastic stress distribution can be assumed in calculating the flexural strength of the proposed hybrid composite beams if the plastic neural axis is located within 15% of the total beam depth from the top of the composite slab. The procedure for computing the effective flexural stiffness of hybrid composite beams is also recommended based on test results.

Removal of Pb2+ Ions from Water by Surfactant-templated Mesoporous Silicates (계면활성제가 담지된 메조포러스 실리케이트에 의한 수중 납이온 제거)

  • Choi, Hyun Suk;Lee, Dong Gue;Cho, Guk Jin;Lee, Chae Young;Chung, Jin Suk;Yoo, Ik-keun;Shin, Eun Woo
    • Korean Chemical Engineering Research
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    • v.44 no.2
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    • pp.172-178
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    • 2006
  • Mesoporous silicate materials have been used as adsorbents for the removal of heavy metals from water by introducing functional groups such as thiol and amine. In this research, it was investigated whether surfactants used as templating agents in synthetic processes can act as adsorption sites for heavy metals. Three mesoporous silicates-SBA-15, MCM-41, and HMS were synthesized using, respectively, block copolymer, hexadecyltrimethylammoniumbromide (HDTMA), and dodecyamine as surfactants. X-ray diffraction and $N_2$ gas adsorption analysis confirmed that the mesoporous silicates were well prepared and FT-IR spectra resulted in the existence of the surfactants in as-synthesized mesoporous silicates and the removal of surfactants after calcination. The interactions between $Pb^{2+}$ ions and the mesoporous silicate materials with/without surfactants were observed. In adsorption kinetic experiments, it revealed that the calcined mesoporous silicates and the surfactant-loaded SBA-15 almost had no adsorption capacity for $Pb^{2+}$ ions. In contrast, the surfactant-loaded MCM-41 and HMS showed, respectively, the adsorption capacities of 26.60 and 115.16 mg/g which were acquired through the fits of adsorption kinetic data to the pseudo second order kinetic model. The adsorption capacities were comparable to those of other mesoporous adsorbents for heavy metals.

Analysis of Physicochemical Properties and Firing Temperature for the Clay Bricks Excavated from the Maritime Province of Severia (연해주 콕샤로프카-1 평지성 출토 토벽의 물리화학적 특성 및 소성온도 분석)

  • Kim, So-jin;Heo, Jun-su;Kim, Jin-hyoung;Kim, Dong-hun;Han, Min-su
    • Korean Journal of Heritage: History & Science
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    • v.46 no.2
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    • pp.206-219
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    • 2013
  • This study aims to estimate firing temperature and physicochemical properties of the four clay bricks excavated from the Maritime Province of Siberia. Analysis result shows that the specimens are composed of clay, quartz and feldspar, and some specimens include carbonized organic materials which were probably added in order to enhance its physical strength in bricks. Major mineral components of the bricks are quartz, illite and clay minerals. The result identifying the existence of silimanite by XRD suggests that white material of the Koc 1 was painted for a certain purpose. Unlike most specimens which contained hematite, several samples contain Mullite. Such result suggests that some bricks were fired at high temperature. Furthermore, the results from TG analysis which does not display exothermic peak which appears at between $800^{\circ}C$ to $1,000^{\circ}C$ but display endothermic peak at $900^{\circ}C$ and it also confirms that they were exposed at $900^{\circ}C$ or higher.

Rheological Models for Simulations of Concrete Under High-Speed Load (콘크리트 재료의 동적 물성 변화를 모사하기 위한 유변학적(Rheological)모델 개발 및 평가)

  • Hwang, Young Kwang;Lim, Yun Mook
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.35 no.4
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    • pp.769-777
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    • 2015
  • In this study, the rheological models were introduced and developed to reflect rate dependent tensile behaviour of concrete. In general, mechanical properties(e.g. strength, elasticity, and fracture energy) of concrete are increased under high loading rates. The strength of concrete shows high rate dependency among its mechanical properties, and the tensile strength has higher rate dependency than the compressional strength. To simulate the rate dependency of concrete, original spring set of RBSN(Rigid-Body- Spring-Network) model was adjusted with viscous and friction units(e.g. dashpot and Coulomb friction component). Three types of models( 1) visco-elastic, 2) visco-plastic, and 3) visco-elasto- plastic damage models) are considered, and the constitutive relationships for the models are derived. For validation purpose, direct tensile test were simulated, and characteristics of the three different rheological models were compared with experimental stress-strain responses. Simulation result of the developed visco-elasto-plastic damage(VEPD) model demonstrated well describing and fitting with experimental results.

Plastic Shrinkage Cracking Reduction of Press Concrete Using Admixtures in Basement (주차장바닥에서 혼화재료들을 사용한 누름콘크리트의 소성수축 균열저감)

  • Kim, Young-Su;Lee, Dong-Un
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.11
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    • pp.416-424
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    • 2019
  • In Korea, press concrete in basements is mainly applied using plain concrete. This system has undesirable defects such as cracks caused by plastic shrinkage and irregular temperature distribution. To solve this problem, metal lath and fibers have been used in the past. However, they have not been effective in controlling cracks. This study analyzed the reduction of plastic shrinkage cracking for press concrete using various admixtures in a basement has been. In the air contents test, the specimens with various admixtures showed air contents similar to plain concrete (4.5±1.5%). The specimens using silica fume, super plasticizer agent, and SBR showed higher compressive strength by about 10-15% than plain concrete. Cracking decreased when the MC, super plasticizer, and SBR were added. When MC was used in the concrete, the plastic shrinkage did not occur.

Scientific Analysis of the Neolithic Red Earthenwares(II) (신석기시대(新石器時代) 주칠토기(朱漆土器)의 과학적(科學的) 분석(分析)(II))

  • Yu, Hei-sun;Jang, Sung-yoon
    • Conservation Science in Museum
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    • v.2
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    • pp.69-76
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    • 2000
  • This study, a part of scientific analysis of the 23 Neolithic red earthenwares excavated from southeastern coast and islands. We analyzed earthenware through statistical method and hardness analysis of clay, following the analysis of clay composition, its firing temperature, pigment composition and its thickness. Clay composition was analyzed by using ICP-AES and XRF, and then Principal Component Analysis (one of multivariate methods) was used for classification. As a result, clay of the earthenware was classified into 3 groups(Bumbang, Youkjido and other sites). In addition, hardness analysis of pigment and clay based on the depth of earthenware surface showed that pigment layer containing lots of Fe2O3 had higher hardness than clay part, which can be interpreted that Fe2O3 contributes to raising hardness in case of high temperature firing. The fact that pigment hardness is higher than that of clay part implies that pigment was applied before firing.

$DeNO_{x}$ Performance of Activated Carbon Catalysts Regenerated by Surfactant Solution (계면활성제 수용액에 의해 재생된 활성탄 촉매의 탈질 성능)

  • Park, Hye-Min;Park, Young-Kwon;Jeon, Jong-Ki
    • Korean Chemical Engineering Research
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    • v.49 no.6
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    • pp.739-744
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    • 2011
  • Activated carbon SCR(CSCR) catalyst that is used to remove $NO_x$ in exhaust gas including boron discharged from the production process of liquid crystal display(LCD) shows deactivation when boron is deposited to block the pores within the catalyst or to cover its active sites. The spent carbon catalyst is regenerated by washing with various surfactants, drying and calcination. For comparison of the physical and chemical properties before and after the regeneration with the variables, type of surfactants and calcination condition, element analysis by ICP, $N_{2}$ adsorption were conducted. $DeNO_{x}$ in SCR with $NH_3$ was carried out in a fixed bed reactor at $120^{\circ}C$. The activated carbon catalyst regenerated through washing with a non-ionic surfactant in $H_{2}O$ at $90^{\circ}C$ and calcination under $N_{2}$ gas at $550^{\circ}C$ shows similar level of surface area and $NO_x$ removal efficiency with those of fresh catalyst.

Numerical Simulation of Membrane of LNG Insulation System using User Defined Material Subroutine (사용자지정 재료 서브루틴을 활용한 LNG선박 단열시스템 멤브레인의 수치해석)

  • Kim, Jeong-Hyeon;Kim, Seul-Kee;Kim, Myung-Soo;Lee, Jae-Myung
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.27 no.4
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    • pp.265-271
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    • 2014
  • 304L stainless steel sheets are used as a primary barrier for the insulation of membrane-type liquefied natural gas(LNG) carrier cargo containment system. 304L stainless steel is a transformation-induced-plasticity(TRIP) steel that exhibits complex material behavior, because it undergoes phase transformation during plastic deformation. Since the TRIP behavior is very important mechanical characteristics in a low-temperature environment, significant amounts of data are available in the literature. In the present study, a uniaxial tensile test for 304L stainless steel was performed to investigate nonlinear mechanical characteristics. In addition, a viscoplastic model and damage model is proposed to predict material fractures under arbitrary loads. The verification was conducted not only by a material-based comparative study involving experimental investigations, but also by a structural application to the LNG membrane of a Mark-III-type cargo containment system.