• Title/Summary/Keyword: 소듐

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Integrity Evaluation of Control Rod Assembly for Sodium-Cooled Fast Reactor due to Drop Impact (낙하충격에 의한 소듐냉각고속로 제어봉집합체의 건전성 평가)

  • Lee, Hyun Seung;Yoon, Kyung Ho;Kim, Hyung Kyu;Cheon, Jin Sik;Lee, Chan Bock
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.41 no.3
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    • pp.233-239
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    • 2017
  • The CA (Control Assembly) of an SFR has a CRA(Control Rod Assembly) with an inner duct and control rod. During an emergency situation, the CRA falls into the duct of the CA for a rapid shut-down. The drop time and impact velocity of the CRA are important parameters with respect to the reactivity insertion time and the structural integrity of the CRA. The objective of this study was to investigate the dynamic behavior and integrity of the CRA owing to a drop impact. The impact analysis of the CRA under normal/abnormal drop conditions was carried out using the commercial FEM code LS-DYNA. Results of the drop impact analysis demonstrated that the CRA maintained structural integrity, and could be safely inserted into the flow hole of the damper under abnormal conditions.

Effect of Heat Treatment and Acid Leaching of Siliceous Mudstone on the Purity of Silica Precursors (실리카 전구물질 순도에 미치는 규질이암의 열처리 및 산 침출 조건의 영향)

  • Cho, Kuk;Chang, Han-Kwon;Kil, Dae-Sup;Suh, Yong-Jae;Park, Jin-Ho;Jang, Hee-Dong
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.4
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    • pp.247-253
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    • 2007
  • The effect of heat treatment and acid leaching of siliceous mudstone on the purity of silica precursors, such as sodium silicate and silicic acid, was studied. As well as the temperatures for the heat treatment of siliceous mudstone, the concentrations of hydrochloric acid and sulfuric acid were varied to achieve the highest content of silicon in the precursors while minimizing energy and chemical consumption. It was found that the optimum conditions were achieved at the heat treatment temperature of $600^{\circ}C$ and hydrochloric acid of 1.56 M. The relative concentrations of silicon in the synthesized sodium silicate and silicic acid were as high as 99.2 and 99.5%, respectively.

Design and Integrity Evaluation of High-temperature Piping Systems in the STELLA-2 Sodium Test Facility (STELLA-2 소듐 시험 시설 고온 배관 계통의 설계 및 건전성 평가)

  • Son, Seok-Kwon;Lee, Hyeong-Yeon;Ju, Yong-Sun;Eoh, JaeHyuk;Kim, Jong-Bum;Jeong, Ji-Young
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.9
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    • pp.775-782
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    • 2016
  • In this study, elevated temperature design and integrity evaluation have been conducted using two different piping design codes for the high-temperature piping systems of sodium integral effect test loop for safety simulation and assessment(STELLA-2) being developed by KAERI(Korea Atomic Energy Research Institute). The design code of ASME B31.1 for power piping and French nuclear grade piping design guideline, RCC-MRx RD-3600 were applied, and conservatism of those codes was quantified based on the piping integrity evaluation results. The piping system of Model DHRS, Model IHTS and PSLS are to be installed in STELLA-2. The integrity evaluation results for the three piping systems according to the two design codes showed that integrity of the piping system was confirmed. As a code comparison result, ASME B31.1 was shown to be more conservative for sustained loads while RD-3600 was more conservative for thermal loads compared to B31.1.

Comparative Cycling Performance of Zn2GeO4 and Zn2SnO4 Nanowires as Anodes of Lithium- and Sodium Ion Batteries (Zn2GeO4와 Zn2SnO4 나노선의 리튬 및 소듐 이온전지 성능 비교 연구)

  • Lim, Young Rok;Lim, SooA;Park, Jeunghee;Cho, Won Il;Lim, Sang Hoo;Cha, Eun Hee
    • Journal of the Korean Electrochemical Society
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    • v.18 no.4
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    • pp.161-171
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    • 2015
  • High-yield zinc germanium oxide ($Zn_2GeO_4$) and zinc tin oxide ($Zn_2SnO_4$) nanowires were synthesized using a hydrothermal method. We investigated the electrochemical properties of these $Zn_2GeO_4$ and $Zn_2SnO_4$ nanowires as anode materials of lithium ion battery and sodium ion battery. The $Zn_2GeO_4$ and $Zn_2SnO_4$ nanowires showed excellent cycling performance of the lithium ion battery, with a maximum capacity of 1021 mAh/g and 692 mAh/g after 50 cycles, respectively, with a high Coulomb efficiency of 98 %. For the first time, we examined the cycling performance of $Zn_2GeO_4$ and $Zn_2SnO_4$ nanowires for sodium ion batteries. The maximum capacity is 168 mAh/g and 200 mAh/g after 50 cycles, respectively, with a high Coulomb efficiency of 97%. These nanowires are expected as promising electrode materials for the development of high-performance lithium ion batteries as well as sodium ion batteries.

Synthesis of porous-structured (Ni,Co)Se2-CNT microsphere and its electrochemical properties as anode for sodium-ion batteries (다공성 구조를 갖는 (Ni,Co)Se2-CNT microsphere의 합성과 소듐 이차전지 음극활물질로서의 전기화학적 특성 연구)

  • Yeong Beom Kim;Gi Dae Park
    • Clean Technology
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    • v.29 no.3
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    • pp.178-184
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    • 2023
  • Transition metal chalcogenides have garnered significant attention as anode materials for sodium-ion batteries due to their high theoretical capacity. Nevertheless, their practical application is impeded by their limited lifespan resulting from substantial volume expansion during cycling and their low electrical conductivity. To tackle these issues, this study devised a solution by synthesizing a nanostructured anode material composed of porous CNT (carbon nanotube) spheres and (Ni,Co)Se2 nanocrystals. By employing spray pyrolysis and subsequent heat treatments, a porous-structured (Ni,Co)Se2-CNT composite microsphere was successfully synthesized, and its electrochemical properties as an anode for sodium-ion batteries were evaluated. The synthesized (Ni,Co)Se2-CNT microsphere possesses a porous structure due to the nanovoids that formed as a result of the decomposition of the polystyrene (PS) nanobeads during spray pyrolysis. This porous structure can effectively accommodate the volume expansion that occurs during repeated cycling, while the CNT scaffold enhances electronic conductivity. Consequently, the (Ni,Co)Se2-CNT anode exhibited an initial discharge capacity of 698 mA h g-1 and maintained a high discharge capacity of 400 mA h g-1 after 100 cycles at a current density of 0.2 A g-1.