• Title/Summary/Keyword: 소다

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Synthesis of zeolite A membranes on alumina support by hydrothermal reaction (수열반응에 의한 알루미나 지지체에 제올라이트 A 박막의 합성)

  • Ko, Tae-Seog
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.3
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    • pp.95-101
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    • 2007
  • The synthesis of NaA zeolite membrane on a porous alumina support from clear solution by using hydrothermal reaction was investigated. Effects of reaction temperature, reaction time and seeding for transformation of zeolite A membrane and powder which are produced in the reactor were monitored through X-ray diffraction (XRD) analysis and scanning electron microscopy (SEM). The transformation process of producing Zeolite A membrane starts from the formation of the compact and continuous membrane on the surface of porous support from clear solution. The large Zeolite A poly-crystal was then farmed through the dissolution process. Finally, the process was advanced from sodalite to amorphous. In case of powder, sodalite is formed in the early stage of reaction because of surrounding space difference between membrane and powder crystal. Discrete surrounding space of powder crystal makes easy to transform to sodalite. From Zeolite A to amorphous through transformed product was rapidly advanced at high temperature while the membrane with somewhat low coverage was obtained at low temperature. A compact and continuous zeolite A membrane was synthesized at $120^{\circ}C$ in 12-hour period.

Removal of Arsenic From Closed Mine Tailings by Alkali-Leaching Method (알칼리 용출법에 의한 폐광산 광미중의 비소제거에 관한 연구)

  • 이재령;오종기;이화영;김성규;박재구
    • Journal of Korea Soil Environment Society
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    • v.2 no.2
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    • pp.73-79
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    • 1997
  • Removal of the Arsenic components from the closed mine tailings has been attempted by the alkali-leaching method. Two tailings collected from the Daduck and Yuchon mine which were already closed many years ago were leached with caustic soda solutions. The Arsenic components in the leach liquor resulted from the alkali treatment of tailings could be removed fairly well in the form of insoluble calcium-Arsenic compound by the precipitation with calcium chloride. As a result, the extraction of about 60~90% Arsenic from the tailings could be obtained depending on the leaching conditions and the influence of temperature and the slurry density on the extraction of Arsenic was also found to be very small at the NaOH concentration more than 0.5N. In addition, it seemed that a caustic soda solution over 0.5N NaOH could be used repeatedly for the leaching of tailings since the consumption of NaOH was not so great in a leaching of them. As far as the precipitation of Arsenic components was concerned, more than 99% of Arsenic could be precipitated within 10 minutes by the addition of 2wt% CaC12 in to the leach liquor.

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Subacute Toxicity Study of Poly(sodium acrylic acid-acrylic acid) in Rats (폴리(아크릴산소다-아크릴산)의 랫드에 대한 아급성 독성시험에 관한 연구)

  • 서경원;박기숙;한범석;장동덕;김창옥;김효정
    • Journal of Food Hygiene and Safety
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    • v.8 no.2
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    • pp.105-117
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    • 1993
  • The objective of this investigation was to characterize the subacute toxic potency of orally administered poly(sodium acrylic acid-acrylic acid), super absorbent polymer. Four groups of rats were maintained on diets containing 0, 1.25, 2.5 or 5% of poly(sodium acrylic acid-acrylic acid). The mean dosages of poly(sodium acrylic acid-acrylic acid) were estimated to be 1025 mg/kg/day, 2009 mg/kg/day and 4728 mg/kg/day in the male groups. The estimated average dosages of poly(sodium acrylic acid-acrylic acid) in the female groups were 1011 mg/kg/day, 2088 mg /kg/day and 4576 mg/kg/day, respectively. Few test compound-related toxic effects were observed in body weight gain, clinical signs, hematological parameters and serum biochemical values. Urinalyses, gross necropsy and histopathology revealed no evidence of specific toxicity. Food and water consumption tended to increase in the animals fed the diet of 2.5% and 5%. Our data indicate that no-observed effect level of poly(sodium acrylic acid-acrylic acid) was estimated to be 1.25% in the diet (mean dosage: 1025 mg/kg/day in male rats, 1011 mg/kg/day in female rats).

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Washing for Debittering of Brewers Yeast Slurry (맥주효모 슬러리의 쓴맛을 제거하기 위한 세척)

  • Kim, Jae-Sik
    • Korean Journal of Food Science and Technology
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    • v.33 no.2
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    • pp.205-208
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    • 2001
  • The bitterness of brewers yeast slurry decreased by washing with mild caustic soda solution followed by washing with 0.85% (w/v) NaCl solution The higher concentration of caustic soda was, the lower the bitterness unit(BU) of washed yeast slurry was. The lethal rate of yeast cells increased. When the concentration of caustic soda solution increased from 0.05%(w/v) to 0.25%(w/v), the BU of brewers yeast slurry was decreased from 45 to 3, but yeast cells viability decreased from 93% to 0%. The optimum washing conditions of brewers yeast slurry were as follows: the concentration of caustic soda solution was $0.07{\sim}0.1%$(w/v) and the contact time of brewers yeast slurry with caustic soda was $10{\sim}20$ minutes. The similar washing effect was obtained when the brewers yeast slurry was washed with 20%(v/v) ethanol solution.

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Hydrolysis of Sarin(GB) in Aqueous NaOH Solution (가성소다 수용액에서 사린(GB)의 가수분해)

  • Lee, Yong-Han;Lee, Jong-Chol;Hong, Deasik
    • Korean Chemical Engineering Research
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    • v.45 no.2
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    • pp.172-177
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    • 2007
  • The hydrolysis reaction of sarin(GB), one of the nerve agents was studied in aqueous sodium hydroxide(NaOH) solutions to find the experimental conditions which can convert GB into the less toxic compounds. 10 wt% of GB was added into the aqueous NaOH(2.05 eq) in a small-scale jacket-attached reactor connected to a circulator. The reaction rate constants were measured at three temperatures(50, 70 and $90^{\circ}C$) and the reaction times required to degrade the material to > 99% were calculated at different temperatures. In this study, 10 wt% of GB was degraded to 99.99% in 1.2hr at $90^{\circ}C$ by the aqueous NaOH solution. The major hydrolysate of GB was isopropyl methylphosphonate.

Effect of Concentrations of Wheat Flour and Sugar on Sponge Fermentation of Soda Cracker (밀가루 및 당 농도가 소다크랙커의 스폰지 발효에 미치는 영향)

  • Kim, Sang-Yong;Lee, Byung-Don;Kim, Jung-Min;Oh, Deok-Kun
    • Korean Journal of Food Science and Technology
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    • v.29 no.2
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    • pp.387-389
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    • 1997
  • Effect of concentrations of wheat flour and glucose on the sponge fermentation of soda cracker by the mixed lactic acid bacteria of L. brevis, L. fermentum and L. plantarum was investigated. When glucose was added to the wheat flour solution, pH was higher and TTA (total titrable acid) was lower as compared with the medium without glucose. This results suggested that glucose in the solution stimulate cell growth but inhibit the production of organic acids. With increasing of wheat flour concentration, pH decreased and TTA increased during the sponge fermentation of soda cracker.

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The Chemical Composition and Working Techniques of the Glass Beads Excavated in the Jisan-dong No. 73-74 Ancient Tombs, Goryeong (고령 지산동 73~74호분 출토 유리구슬의 제작 기법과 화학 조성)

  • Kim Nayoung;Kim Euna;Kim Gyuho
    • Conservation Science in Museum
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    • v.31
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    • pp.21-37
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    • 2024
  • This paper sought to garner an understanding of Daegaya glass culture by observing the micro-structure and analyzing the chemical composition of 43 glass beads excavated from the No.73 and 74 ancient tombs in Jisan-dong, Goryeong, which are estimated to have a central age of 5th century CE. The visible characteristics and micro-structure of these artifacts were observed with a optical microscope and an scanning electron microscope, while their chemical composition was analyzed with an energy-dispersing spectrometer attached to the scanning electron microscope. As a result, the glass beads of Jisan-dong, Goryeong were identified to have been formed using various methods such as drawing, casting, and folding techniques, with the majority molded by the drawing technique. In terms of chemical composition, 32.6% were in the potash glass group and 67.4% in the soda glass group, with the latter divided into various fluxes such as high alumina glass, netron glass, and plant ash glass. Compared to Baekje's cultural region in the same age, the composition of these ancient glass artifacts demonstrates a high share of the potash glass group. This shows that, despite the shift from the potash glass group to the soda glass group in ancient Korean glass culture, glass composition differs from region to region or depending on the cultural sphere of influence. In the soda glass group, high-alumina glass comprised 23.3%, natron glass 43.0%, and plant ash glass was 1.2%. Among them, the main type of Korean soda glass is high-alumina glass, as natron glass and plant ash glass are known to have appeared later, but the results of scientific analysis of the glass beads excavated in Jisan-dong can be expected to provide important clues about the inflow and transformation of ancient glass on the Korean Peninsula. In the No. 73, 74, and 74-1 ancient tombs, which were found to have been built in chronological order by the excavation survey, the glass beads showed only slight variations depending on their production period. Nonetheless, the chemical composition of glass is deemed to have a close correlation to color.