• Bulletin of the Korean Space Science Society
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• 1992.10a
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• pp.22-22
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• 1992

식쌍성 Algo1과 44i Boo에 대해 각각 두 개의 비교성을 이용하여 광전관측을 수행하여 광도곡선을 얻었다. 색효과는 목적성과 비교성의 색의 차이에 기인한 효과로서 광도곡선상에 체계적인 오차로 남게 된다. 따라서, 자료보정 과정에서 전체 소과계수인 k만으로 보정하게 디면 색효과에 의한 체계적인 오차는 광도곡선상에 그대로 남게 된다. 즉, 쌍성관측에서는 비교성을 목적성과 거의 같은 위치의 것을 택하여 관측하기 때문에 투과 대기량의 차이와 곱해져 등급에 영향을 주는 1차 소광계수에 의한 효과보다는 색의 차에 기인한 2차 소광계수에 의한 효과가 더 크다는 의미이다. 물론 투과 대기량의 크기가 큰 곳에서는 1차 소광계수에 의한 효과도 커지게 된다. Algo1의 경우, 비교성과 점검성을 이용하여 얻은 광도걱선들은 평탄영역에서 이들의 색의 차이 때문에 다르게 나타났으며, 색항을 보정한 결과 두 광도곡선이 거의 유사하게 나타났다. 44i Boo의 경우는 평탄 영역이 거의 보이지 않고, 색에 의한 효과는 광도곡선의 전 영역에 걸쳐 나타났으며, 비교성이 점검성에 비하여 목적성으로부터 더 멀리 떨어진 관계로 k1,k2항이 모두 중요하게 나타났다. 한편, 1,2차 소광 보정 이후에도 날짜에 따라 다른 그림을 보여 준 것은 기기 효과에 기인한 것으로 보여졌으며, 자료에 가장 큰 오차로 기여하는 것은 시간에 따른 대기 상태의 변화이기 때무에 보다 정확한 자료보정을 하기 위해서는 동-서쪽으로 나누어 소광보정을 하는 것이 바람직 할것으로 보여졌다.

• Journal of Soil and Groundwater Environment
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• v.12 no.6
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• pp.53-59
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• 2007

Optimal quenching curves have been studied for the accurate analysis of $^{14}C$ in groundwater polluted by reducing efficiency of volatile organic compounds (VOCs) in liquid scintillation counter (LSC). The quenching parameters (SQP(E)) were measured for ten VOCs such as benzene, toluene, ethylbenzene, o-(m-,p-)xylene, trichloroethylene (TCE), tetrachloroethylene(PCE), carbon tetrachloride and chloroform. The quenching curves were plotted using $^{14}C$ standard solution and chloroform as a quenching agent. Optimal plotting conditions were determined for standard solution, LSC measuring time and the concentration of chloroform. The quenching effects of chlorinated organic compounds such as TCE, PCE, carbon tetrachloride and chloroform were greater than those of BTEX (benzene, toluene, ethylbenzene and xylene). Optimum measuring time was 100 minutes far 7,000 dpm/mL standard solution. A few mL of chloroform should be added for good quenching curves. These quenching curves have good correlation coefficients (> 0.99) and the curves could be applied to accurate analysis of $^{14}C$ in groundwater and tap water.

• Journal of the Korean Chemical Society
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• v.42 no.1
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• pp.22-27
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• 1998

Fluorescence quenching of coumarin 153 and coumarin 481 with N,N-dimethylaniline in various solvents was investigated. Quenching rate constants are related to diffusion-limited rate constants to some extent. It is noted that smaller discrepancy was observed between the diffusion-limited rate constant and the experimental quenching rate constant when the stick boundary condition rather than the slip boundary condition was applied for estimating the diffusion coefficients. In nonpolar solvent like cyclohexane fluorescence quenching is adequately explained by the diffusion controlled process within the experimental error, but in acetonitrile the quenching rate constant was estimated to be consistently smaller than the diffusion limited rate constant. This may suggest that fluorescence quenching of coumarin dyes be affected not only by the molecular diffusion but also by the intramoleccular process such as charge separation.

• Journal of Advanced Navigation Technology
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• v.11 no.2
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• pp.187-195
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• 2007

In this paper, the optimal values of optical phase conjugator (OPC) position and dispersion coefficients of fiber sections depending on the extinction ratio of WDM channel signals are numerically induced in WDM system with OPC used to compensate the distorted signals due to nonlinearities and chromatic dispersion. The considered WDM system consist of 16 channels with 40 Gbps data rate and each channel is assumed to be NRZ format with the extinction ration of 5 dB, 10 dB, or 20 dB. It is confirmed that the only one parameter among two considered parameters is used to effectively compensate overall WDM channels, and each optimal value of these parameters independent on the extinction ratio. That is, overall WDM channels are excellently transmitted within 2 dB power penalty whether by positioning OPC into 496 km or by setting dispersion coefficient difference between two fiber sections to 0.055 ps/nm/km, these optimal values are not dependence on the extinction ratio.

• Journal of the Korean Chemical Society
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• v.43 no.4
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• pp.423-429
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• 1999

A spectrofluorimetric method for the determination of Fe(III) in aqueous solution with 4,5-dihydroxy-1,3-benzenedisulfonic acid(Tiron) as a fluorimetric reporter was developed. Tiron, which is very soluble in water,is a good fluorimetric reagent. However, when Tiron was complexed with Fe(III), the fluorescent intensity was decreased proportionally with the concentration of Fe(III) by a quenching effect. The excitation and fluorescene wavelength of Tiron showing the quenching effect by Fe(III) at pH 4.5 were 312 nm and 341 nm, respectively. The highest sensitivities were shown at Tiron concentration of $1.0{\times}10^{-2}M$. To enhance the quenching effect, the Fe(III)-Tiron complex solution was heated to 80$^{\circ}C$ for 90 minutes. As for Fe(III), the most interfering ion was Cu(II). The interference effects could be mostly eliminated by pH adjustment or by adding EDTA. The concentration ranges showing the linear response to Fe(III) was from $5.0{\times}10^{-7}M\;to\;6.0{\times}10^{-5}M$ With this proposed method, the detection limits of Fe(III) was $2.8{\times}10^{-6}M$. Recovery of Fe(lII) in a synthetic sample was almost quantitative. Based on experimental results, it is proposed that the above technique can be applied to the practical determination of Fe(III).

• Journal of Advanced Navigation Technology
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• v.28 no.1
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• pp.123-128
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• 2024

When mid-span spectral inversion (MSSI), which inverts the propagated wave into phase-conjugated wave in the middle of the entire transmission distance, is combined with dispersion-managed link, it is very effective in compensating for the wavelength division multiplexed (WDM) signal distortion due to chromatic dispersion and nonlinear effects. In this MSSI combined dispersion-managed link, the shape of the dispersion map, channel data rate, channel wavelength and wavelength spacing, etc. affect the compensation and, consequently, determine the transmission distance and capacity of the WDM signal. In this paper, the compensation according to the extinction ratio of the return-to-zero (RZ) pulse that constitutes the WDM signal in the MSSI combined distributed control link was numerically analyzed. As a result of the simulation, it was conformed that the extinction ratio to obtain the best compensation should be determined depending on the shape of the dispersion map and the size of the residual dispersion per span, which determines the specific shape of the dispersion map. These results show a significant difference from the results in a general optical transmission system, where as the extinction ratio increases, the power difference between the '1' and '0' signals increases, thereby improving reception performance.

• Journal of the Korean Chemical Society
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• v.26 no.3
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• pp.172-178
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• 1982

A psoralen-DNA monoadduct analogue, 4',5'-dihydropsoralen (DHP) is synthesized and its photophysical properties such as fluorescence quantum yield (0.08), phosphorescence quantum yield (0.013), fluorescence lifetime (0.95ns), and phosphorescence lifetime(0.039s) were measured in ether solution and in frozen matrix state at 77K. The photocycloaddition reaction of DHP with tetramethylethylene(TME) was carried out in solution and in the frozen state. The major photoadduct was isolated and characterized by elemental analysis and physical methods such as UV, IR, NMR, and mass spectrometry. The major DHP-TME photoadduct was proved to be an 1 : 1 $C_4$-cycloadduct formed through 2 + 2 cycloaddition of the pyrone double bond of DHP to TME.

• The Bulletin of The Korean Astronomical Society
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• v.37 no.1
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• pp.60.2-60.2
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• 2012

Sco OB1의 핵심성단 NGC 6231를 호주 Siding Spring 천문대 1m 망원경을 사용하여 -40'${\times}$40' 영역을 관측하였다. 측광자료를 바탕으로 성단의 반경, 성간소광 법칙, 나이 및 초기질량함수를 결정하였다. 성단의 반지름은 구성원의 질량에 상관없이 거의 10' ($R{\approx}4.6pc$)으로 동일한 값을 보였다. 전체적으로는 정상적인 성간소광 법칙을 따르지만, 성단의 중심으로 갈수로 큰 $R_V$를 보여주며, 이는 과거에 있었을 것으로 추정되는 초신성의 효과로 추정된다. 질량이 큰 별과 X-선으로 선택된 성단의 전주계열성은 비슷한 평균나이를 보이지만 전주계열성은 훨씬 큰 나이분산을 보였다. 성단전체 초기질량함수의 기울기는 Salpeter 초기질량함수의 기울기와 매우 유사한 ${\Gamma}$=-1.1${\pm}$0.1을 보였으며, 성단 중심거리에 따른 초기질량함수의 기울기는 -1.0${\pm}$0.2에서 -1.8${\pm}$0.5까지 체계적으로 변화를 하였다. 질량이 큰 O형 별의 쌍성비율이 중심거리에 따른 변화를 보이지 않음에 비추어 볼 때, NGC 6231의 질량분리 양상은 역학적 진화의 결과가 아니라 원초적 질량분리현상으로 결론을 내릴 수 있다.

• Proceedings of the Korean Magnestics Society Conference
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• 2011.12a
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• pp.126-128
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• 2011

• Korean Journal of Optics and Photonics
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• v.25 no.1
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• pp.1-7
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• 2014

Multiple scattering effects in cloud are important error sources of the Mie scattering Lidar inversion method, which should be measured to correct the Lidar equation in single wavelength Mie Lidar. We have calculated the multiple scattering effects in liquid water clouds by using a Monte Carlo method, and we have applied these multiple scattering effects in measuring water cloud effective size and LWC (Liquid Water Content). When cloud effective size is less than $2.5{\mu}m$, we can easily extract cloud effective size and LWC by using two wavelength Lidar such as extinction coefficients measured at 355nm and 1064nm. For a larger size cloud, we can find that saturated degree of linear polarization is strongly correlated with cloud effective size, LWC, and extinction coefficients. From these correlations we know that we can measure LWC and cloud effective size if we use single wavelength Rotational Raman Lidar and Mie scattering polarization Lidar.