• Title/Summary/Keyword: 셀 형상

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Synthesis and Characteristics of Organic Soluble Polyaniline by Emulsion Polymerization (유화 중합법에 의한 유기 용매 가용형 폴리아닐린의 합성 및 그 특성)

  • 김진열;권시중;한성원;김응렬
    • Polymer(Korea)
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    • v.27 no.6
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    • pp.549-554
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    • 2003
  • Emeraldine salt of polyaniline-dodecylbenzenesulfdnic acid (PANI-DBSA) in organic solvents such as toluene and xylene was obtained by a direct one-step emulsion polymerization technique. When the molar ratio of DBSA to aniline monomer was 1.5:1, its solubility and electric property showed a maximum value and then the solid contents of PANI-DBSA was 8 wt% in toluene. The cast film of PANI-DBSA with no binder was obtained on glass or plastic substrates under ambient conditions. PANI solution can be also easily blended with polyurethane and polystyrene polymers in toluene. Improved electrical performance up to 5 S/cm was achieved with good light-transmittance up to 70% at 500 m thickness. They also showed more homogeneous morphology than that prepared with PANI-DBSA kom aqueous dispersion polymerization. The partially dispersed PANI-DBSA showed particles sizes of 50-400 m in organic solvents and their XRD pattern were observed from the powder sample.

Experimental Testing of Curved Aluminum Honeycomb/CFRP Sandwich Panels (곡면형상의 알루미늄 하니콤/CFRP 샌드위치 패널에 관한 실험적 연구)

  • Roy, Rene;Park, Yong-Bin;Kweon, Jin-Hwe;Choi, Jin-Ho
    • Composites Research
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    • v.26 no.2
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    • pp.85-90
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    • 2013
  • This paper presents the fabrication and 3-point flexion testing of carbon fiber reinforced polymer (CFRP) composite face/aluminum honeycomb core sandwich panels. Specimen sandwich panels were fabricated with three honeycomb types (3.18 mm, 4.76 mm, and 6.35 mm cell size) and three panel radii (flat, r = 1.6 m, r = 1.3 m). The curved sandwiches were fabricated normally with the core in the W-direction. The tensile mechanical properties of the CFRP $2{\times}2$ twill fabric face laminate were evaluated (modulus, strength, Poisson's ratio). The measured values are comparable to other CFRP fabric laminates. The flat sandwich 3-point flexion test core shear strength results were 11-30% lower than the manufacturer published data; the test set-up used may be the cause. With a limited sample size, the 1.3 meter panel curvature appeared to cause a 0.8-3.8% reduction in ultimate core shear strength compared to a flat panel.

Cable Tension Measurement of Long-span Bridges Using Vision-based System (영상처리기법을 이용한 장대교량 케이블의 장력 측정)

  • Kim, Sung-Wan;Cheung, Jin-Hwan;Kim, Seong-Do
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.2
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    • pp.115-123
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    • 2018
  • In a long-span bridge, the cables are important elements that support the load of the bridge. Accordingly, the cable tension is a very important variable in evaluating the health and safety of the bridge. The most popular methods of estimating the cable tensions are the direct method, which directly measures the cable stresses using load cells, hydraulic jacking devices, etc., and the vibration method, which inverses the tensions using the cable shapes and the measured dynamic characteristics. Studies on the use of the electromagnetic (EM) sensor, which detects the magnetic field variations caused by the change in the stress of the steel in the cable, are increasing. In this study, the lift-off test, the EM sensor, and the vibration method (Vision-based System and Accelerometer) were used to measure cable tension, and their results were compared and analyzed.

Co-sputtering법으로 제작된 화합물 반도체 박막형 태양전지에서 $CuInSe_2$(CIS) 광흡수층의 열처리 효과

  • Kim, Hae-Jin;Lee, Hye-Ji;Son, Seon-Yeong;Park, Seung-Hwan;Kim, Hwa-Min;Hong, Jae-Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.269-269
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    • 2010
  • 현재 화석연료의 부족으로 인한 에너지 수급의 불균형, 자연환경의 파괴로 인해 대체에너지 개발이 절실히 요구되고 있다. 이러한 문제점을 극복하기 위한 방안으로 태양전지에 대한 관심이 높아지고 있다. 기존 결정형 실리콘 태양전지와 비교해 화합물 반도체를 기반으로 한 박막형 태양전지는 친환경적인 제품이면서 제조원가를 절감시킬 수 있고, 반영구적인 수명 및 값싼 기판을 활용할 수 있는 장점으로 인해 활발한 연구가 진행되고 있다. 본 실험에서는 Co-sputtering법으로 제작된 $CuInSe_2$(CIS)를 광활성층으로 한 박막형 태양전지에서 실온 ${\sim}550^{\circ}C$의 다양한 온도에서 후열 처리된 CIS 박막들의 전기적, 구조적, 광학적인 특성들을 분석하였다. 제작된 박막들 가운데 Hall Effect 측정결과 $550^{\circ}C$에서 후열 처리된 박막이 가장 높은 1.227E+22(/$cm^3$)의 캐리어 농도와 1.581(cm/$V{\cdot}s$)의 홀 이동도를 가지며, 3.092E-4(${\Omega}{\cdot}cm$)의 가장 낮은 비저항 값을 갖는 것으로 나타났다. EFM 측정결과 열처리 하지 않은 박막에 비해 후열처리된 CIS 박막의 전도성이 전체적으로 높아졌다. 특히, $550^{\circ}C$에서 후열 처리된 박막의 표면은 전체적으로 전기 전도성이 높은 결정립들이 골고루 분포하며 가장 높은 표면 포텐셜 에너지 값을 갖는 것으로 나타났다. 박막들의 구조적 특성을 분석하기 위해 SEM과 XRD를 측정한 결과, $350^{\circ}C$에서 후열 처리된 박막들은 열처리 되지 않은 박막과 비교해 표면형상 변화가 일어났으며, $550^{\circ}C$에서 후열 처리된 CIS 박막들은 $CuInSe_2$(112) 방향이 향상된 chalcopyrite-like 구조를 가지면서 박막 밀도가 높고 결정립의 크기가 증가된 것을 확인하였다. 이는 박막 성장시 기판온도의 상승으로 CIS 박막 내에서 셀레늄의 확산과 상호작용으로 3원 화합물이 재결정화되어 구조적인 특성향상에 기여하였기 때문이다. 결론적으로 본 연구는 CIS 광활성층에서 후열 처리의 효과들 뿐만아니라 박막 증착시 co-sputtering법을 이용함으로써 증착시간의 감소 및 대면적화와 대량생산으로도 적용 가능함을 제시하고자 한다.

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Ocean bottom reverberation and its statistical characteristics in the East Sea (동해 해역에서 해저면 잔향음 및 통계적 특징)

  • Jung, Young-Cheol;Lee, Keun-Hwa;Seong, Woojae;Kim, Seongil
    • The Journal of the Acoustical Society of Korea
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    • v.38 no.1
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    • pp.82-95
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    • 2019
  • In this study, we analyzed the beam time series of ocean reverberation which was conducted in the eastsouthern region of East Sea, Korea during the August, 2015. The reverberation data was gathered by moving research vessel towing LFM (Linear Frequency Modulation) source and triplet receiver array. After signal processing, we analyzed the variation of ocean reverberation level according to the seafloor bathymetry, source/receiver depth and sound speed profile. In addition, we used the normalized data by using cell averaging algorithm and identified the statistical characteristics of seafloor scatterer by using moment estimation method and estimated shape parameter. Also, we analyzed the coincidence of data with Rayleigh and K-distribution probability by Kolmogorov-Smirnov test. The results show that there is range dependency of reverberation according to the bathymetry and also that the time delay and the intensity level change depend on the depths of source and receiver. In addition, we observed that statistical characteristics of similar Rayleigh probability distribution in the ocean reverberation.

Development and Verification of 4-Electrode Resistivity Probe (4전극 전기비저항 탐사장비의 개발 및 검증)

  • Kim, Joon-Han;Yoon, Hyung-Koo;Jung, Soon-Hyuck;Lee, Jong-Sub
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.3C
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    • pp.127-136
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    • 2009
  • The objective of this study is the development and verification of the 4-electrode resistivity probe (4ERP) for the estimation of electrical properties of the saturated soils. The 4ERPs with wedge and plane types are manufactured to obtain the electrical resistivity without polarization at the electrodes by using Wenner array. The wedge type is for the penetration into the soil samples and the plane type is for the installation into the cells used for the laboratory tests. The consolidation tests are carried out by using 6 types of glass beads and 3 types of sands in size. The test results show that the electrical resistivity increases with a decrease in the porosity, and the constant m used in Archie's law is dependent on the particle shape rather particle size. The one dimensional liquefaction tests show that the porosity obtained by the 4ERP is similar to that determined by the volume fraction. The penetration of the 4ERP into the large scale calibration chamber produces the resistivity profiles. This study demonstrates that the 4ERP may effectively estimate the porosity of the saturated soils.

Structural Characteristics of Pultruded Composite Bridge Deck of Hollow Section (인발성형 중공단면 복합소재 교량 바닥판의 구조적 특성 분석)

  • Lee, Sung Woo;Kim, Byung Suk;Jo, Nam Hoon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.1A
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    • pp.35-43
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    • 2006
  • In this paper, procedures and research results involved in the development of glass reinforced composite bridge deck of hollow section were presented. Laminate design for the 3 cell deck section was performed. Structural characteristics such as serviceability, strength, failure and stability for DB24 load were analytically studied through the finite element analysis for the composite deck plate girder bridge. Composite deck tube was fabricated with pultrusion and extensive tests such as flexural test, girder-connection test, barrier-connection test, compression fatigue test and flexural fatigue test were carried out to evaluate structural behavior experimentally. Also, field load test was conducted for the demonstration plate girder bridge with composite deck and requirements for the strength and serviceability were reviewed.

Improvement of Corrosion Resistance of 316L Stainless Steel by Gas Nitriding (가스 질화를 통한 316L스테인리스강의 내식성 개선)

  • Hyunbin Jo;Serim Park;Jisu Kim;Junghoon Lee
    • Journal of the Korean Electrochemical Society
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    • v.27 no.1
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    • pp.8-14
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    • 2024
  • Austenitic stainless steel 316L has been used a lot of applications because of its high corrosion resistance and formability. In addition, copper brazing is employed to create complex shape of 316L stainless steel for various engineering parts. In such system, copper-based filler metals make galvanic cell at metal/filler metal interface, and it accelerates corrosion of stainless steel. Furthermore, Cu-rich region formed by diffused copper in austenitic stainless steel can promote a pitting corrosion. In this study, we used an ammonia (NH3) gas to nitride the 316L stainless steel for improving the corrosion resistance. The thickness of the nitride (nitrogen high) layer increased with the treatment temperature, and the surface hardness also increased. The potentiodynamic polarization test showed the improvement of corrosion resistance of 316L stainless steel by enhancing the passivation on nitride layer. However, in case of high temperature nitriding, a chromium nitride was formed and its fraction increased, so that the corrosion resistance was decreased compared to the intact 316L stainless steel.

The Effect of Surface Tension on Shear Wave Velocities according to Changes of Temperature and Degree of Saturation (온도와 포화도의 변화에 의한 표면장력이 전단파 속도에 미치는 영향)

  • Park, Jung-Hee;Kang, Min-Gu;Seo, Sun-Young;Lee, Jong-Sub
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.6C
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    • pp.285-293
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    • 2012
  • The surface tension, which is generated in the unsaturated soils, increases the stiffness of the soils. The objective of this study is to estimate the effect of the surface tension, which varies according to the temperature, on the shear wave velocity. Nine specimens, which have the different degree of saturation (0%, 2.5%, 5%, 10%, 20%, 40%, 60%, 80%, 100%), are prepared by using sand-silt mixtures. Experiments are carried out in a nylon cell designed for the measurement of shear waves. A pair of bender elements, which are used for the generation and detection of shear waves, is installed as a cross-hole type. The shear waves are continuously monitored and measured as the temperature of specimens decreases from $15^{\circ}C$ to $1^{\circ}C$. The results show that shear wave velocities of the fully saturated and fully dried specimens change a little bit as the temperatures of specimens decrease. However, the shear wave velocities of the specimens with the degree of saturations of 2.5%, 5%, 10%, 20%, 40%, 60% and 80% continuously increase as temperature decreases from $15^{\circ}C$ to $1^{\circ}C$. Furthermore, a fully saturated specimen is dried at the temperature of $70^{\circ}C$ in order to observe the shear waves according to degree of saturation. The shear wave velocities measured at the temperature of $70^{\circ}C$ are generally lower than those measured at temperature of $15^{\circ}C$. This study demonstrates that the dependence of shear wave velocities on the temperature according to the degree of saturation should be taken into account in both laboratory and field tests.

Application of Vision-based Measurement System for Estimation of Dynamic Characteristics on Hanger Cables (행어케이블의 동특성 추정을 위한 영상계측시스템 적용)

  • Kim, Sung-Wan;Kim, Nam-Sik
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.1A
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    • pp.1-10
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    • 2012
  • Along with the development of coasts, islands and mountains, the demand of long-span bridges increases which, in turn, brings forth the construction of cable-supported bridges like suspension and cable-stayed bridges. There are various types of statically indeterminate structures widely applied that supported the main girder with stay cables, main cables, hanger cables with aesthetic structural appearance. As to the cable-supported bridges, the health monitoring of a bridge can be identified by measuring tension force on cable repeatedly. The tension force on cable is measured either by direct measurement of stress of cable using load cell or hydraulic jack, or by vibration method estimating tension force using cable shape and measured dynamic characteristics. In this study, a method to estimate dynamic characteristics of hanger cables by using a digital image processing is suggested. Digital images are acquired by a portable digital camcorder, which is the sensor to remotely measure dynamic responses considering convenient and economical aspects for use. A digital image correlation(DIC) technique is applied for digital image processing, and an image transform function(ITF) to correct the geometric distortion induced from the deformed images is used to estimate subpixel. And, the correction of motion of vision-based measurement system using a fixed object in an image without installing additional sensor can be enhanced the resolution of dynamic responses and modal frequencies of hanger cables.