• Title/Summary/Keyword: 셀룰로오스 섬유

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면 니트의 CPB 염색가공기술 및 현황

  • 구홍림
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2002.08a
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    • pp.71-116
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    • 2002
  • 섬유제품 중 의류용으로 소비자들이 가장 많이 선호하는 것은 면 섬유이고, 그중 니트제품이 차지하는 비율은 약 절반 정도이다. 면 섬유가 갖는 여러 가지 장점들을 대체하기 위하여 여러 가지 합성섬유가 개발되었으나, 천연섬유에 대한 소비자 인식이 높아지면서 스판덱스와 같은 탄성섬유를 제외한 합성섬유 소비는 점차 줄어들고 있는 반면, 면 섬유와 천연 원료에서 추출하는 모달, 텐셀, 라이오셀 등의 셀룰로오스계 신 소재는 그 소비가 증가하고 있는 추세이다. (중략)

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Synthesis of Water-soluble Fiber using Carboxymethylcellulose(CMC) and Development of Pilot Plant (카르복시메틸셀룰로오스 제조공정을 이용한 수용성 섬유 제조 및 파일럿 플랜트 개발)

  • Song, Ho-Jun;Lee, Seungmoon;Choi, Youngmin;Chung, Eui-Hyun;Maken, Sanjeev;Park, Jin-Won
    • Clean Technology
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    • v.11 no.4
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    • pp.189-194
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    • 2005
  • Carboxymethylcellulose(CMC) which is water-soluble fiber was manufactured by mercerization and etherification in the earlier study. Experimental parameters were conversion time for each step, concentration of reagent and temperature. To know the presence of functional group, CMC was analyzed by FT-IR(Fourier Transform Infrared) spectroscopy. Ethanol was recovered using evaporator and purity of ethanol analyzed by GC-MASS was 97% and 83% after mercerization and etherification respectively. For the pilot plant, if CMC is folded by 40 times it showed maximum efficiency. Maximum solubility was obtained when the ratio of NaOH and MCA is 3 : 4.5.

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Bacterial Cellulose Membrane for Wastewater Treatment: A Review (폐수 처리를 위한 박테리아 셀룰로오스 막: 리뷰)

  • Jang, Eun Jo;Patel, Rajkumar
    • Membrane Journal
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    • v.31 no.6
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    • pp.384-392
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    • 2021
  • Growing pollution due to industrialization leads to difficulties in survival of mankind. Generation of clean water from wastewater by membrane separation process is emerging cost efficient technology. Membrane prepared from renewable resources are in lots of demand to reduce burden on synthetic polymers which is one of the source of environmental pollution. Bacterial cellulose (BC) is very pure and distinct form of cellulose nanofibrils (CNF). Nanopapers prepared from CNF are used ad ultrafiltration (UF) and nanofiltration (NF) membrane for different applications. High crystallinity of BC gives rise to excellent mechanical property, an essential criterion for wastewater treatment membrane. In this review, BC based membrane for application in dye, oil, heavy metal and chemical removal from wastewater is discussed.

Linen-like Finishing of Cotton Fabric Using N-Methylmorpholin N-Oxide (N-Methylmorpholin N-Oxide를 이용한 면직물의 의마가공)

  • 손현식;김진호;윤경훈;이양헌
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.281-284
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    • 2002
  • 마 섬유는 흡습성이 좋고 건조가 빠르고, 습윤 시 강도가 증가되며 열전도율이 크고 통기성이 크며, 강도와 내열성이 천연 섬유 중 가장 우수하며 매끄러운 표면을 가지고있어서 광택과 방오성이 좋다. 그러나 세사방적이 어렵고 강연도가 지나치게 커서 의복소재로서 극히 제한적으로 사용되어왔으나, 최근에는 큰 강연도를 장점으로 활용하여 여름용 의복소재로 다시 각광받고 있다. 따라서 면, 레이온, 셀룰로오스계 섬유제품들에 대하여 마 제품과 유사한 효과를 낼 수 있는 다양한 의마가공법이 개발되어왔다[1,2]. (중략)

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A Study on the Practicality of Fiber Reinforced Concrete to Control Plastic Shrinkage Crack (균열제어를 위한 섬유보강 콘크리트의 실용화 연구)

  • Jung, Yang-Hee;Choi, Il-Ho;Kim, Ook-Jong;Lee, Do-Bum
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2007.11a
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    • pp.15-18
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    • 2007
  • The purpose of this study is to suggest a reference for an extensive evaluation about effectiveness of four types of fibers to control plastic shrinkage crack of concrete. So in this study for the practical use in construction field, the plastic shrinkage cracks shown from four types of concrete reinforced by mixing four types of fibers are quantitatively evaluated in points of the workability and compressive strength. Test showed that the mixing of Cl, N, P fibers except for C2 fibers decreased fluidity of fresh concrete. Compressive strengths of four types specimens were similar. Plastic shrinkage cracks were reduced by mixing each fiber, especially C2 fibers was very effective to prevent the plastic shrinkage crack. Therefore the reinforced concrete mixed with C2 fibers exhibited superior mechanical performance than the others.

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Characteristics of Cellulose Aerogel Prepared by Using Aqueous Sodium Hydroxide-urea (Sodium Hydroxide-urea 수용액을 이용하여 제조한 셀룰로오스계 에어로겔의 특성)

  • Kim, Eun-Ji;Kwon, Gu-Joong;Kim, Dae-Young
    • Journal of the Korean Wood Science and Technology
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    • v.41 no.4
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    • pp.302-309
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    • 2013
  • The highly porous cellulosic aerogels were prepared by freeze-drying method using sodium hydroxide-urea aqueous solution in the process of dissolution, gelation, regeneration and organic solvent substitution. The structural characteristics of porous aerogel were analyzed using scanning electron microscopy and nitrogen adsorption apparatus. As a result, the dissolving pulp was completely dissolved, but filter papers and holocellulose were divided into two layers (dissolved and undissolved parts) in the process of centrifugation. The structure of aerogel from dissolved pulp showed porous pores in the surface and net-shaped network in the inner part. Aerogels from filter paper and holocellulose had the condensed porous network surface and the open-pore nano-fibril network inner structure. Undissolved form of fibers was observed in the aqueous solution of aerogel from holocellulose. The BET value ($S_{BET}$) of aerogel from dissolved pulp was ranged in 260~326 $m^2/g$, and it was decreased with the increase of concentration. Whereas, the $S_{BET}$ value of aerogel from filter paper (198~418 $m^2/g$) was increased with the increase of concentration. The $S_{BET}$ value of aerogel from holocellulose were 137 $m^2/g$ at 2% (w/w) of cellulose, and it was increased to maximum 401 $m^2/g$ at 4% (w/w) of cellulose. Then, it was decreased at 5% (w/w) of cellulose.

Developing Human-friendly UV Protective Cellulose Fabrics Using Chitosan and Green Tea Extract -Focusing on the Repetition Effect of Chitosan Mordanting and Green Tea Extract Dyeing- (키토산과 녹차추출물을 이용한 인체친화적 자외선 차단 셀룰로오스 섬유의 개발 -키토산 매염과 녹차추출물 재염의 효과를 중심으로-)

  • Jung, Hye-Kyung;Kim, Sin-Hee
    • Journal of the Korean Society of Clothing and Textiles
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    • v.33 no.5
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    • pp.817-826
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    • 2009
  • As UV radiation to the earth increased over recent years, many adverse effects of UV radiation have been reported. There are needs to develop UV-protective apparel and accessaries to protect skin from these harmful effects. Cellulose is one of the most frequently worn fiber during summer time. However, celllulose shows very low UV-protective property especially in case of thin and low fabric content. In this study, UV-protective cellulose textiles were developed using chiotsan mordanting and green tea dyeing. The repetition effect of chitosan and green tea treatment were focused. Three different cellulose fibers, cotton, linen, and ramie, were used for this study. All chitosan mordanted and green tea dyed fabrics showed increases in UV-protective property. The color of fabrics tended to darker as the numbers of mordanting process and green tea dyeing increased. UV-protective property did not increase significantly upon the repetition of mordanting and green tea dyeing treatment except ramie fabric. UV protective property was persisted upon washfastness test in all three cellulose fiber types.

Nerve-Agent Selective Chemiresistors Fabricated by Oxime Decorated Polypyrrole Layer on Cellulose Paper (셀룰로오스 종이 상에 Oxime 도입된 polypyrrole 층을 제조한 신경작용제 선택적 화학저항 센서)

  • Changhoon Jeon;Taihwan Ha
    • Journal of the Korea Institute of Military Science and Technology
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    • v.27 no.4
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    • pp.528-534
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    • 2024
  • In continuous research of detecting highly toxic chemical warfare agents to ensure preparedness for the future battlefield, flexible and wearable sensor platforms with high sensitivity are still demanding. Herein we demonstrate a facile fabrication of polypyrrole-based chemiresistors on cellulose paper for the detection of nerve gas simulants. In order to optimize electrical properties of sensor platform, conducting polymer made of polypyrrole were first synthesized on flexible cellulose paper and interdigitated electrodes were formed thereon. Following confirmation of polypyrrole and/or oxime moiety through FT-IR analyses, electrical characteristics were measured in the various ratio of monomers between simple pyrrole and oxime-modified one. Typically for the optimized chemiresistor(2:8 molar ratio of simple pyrrole and oxime-modified one), eleven species of chemical warfare agents were examined and enhanced conductivity(104~105 order) was observed for three simulants(diethyl cyanophosphonate, diisopropyl fluorophosphonate and diethyl chlorophosphonate), which was mainly attributed to intermolecular hydrogen bonding, while no significant responses was recorded against sixteen common volatile organic chemicals.

Pretreatment of Cane Molasses for Production of Bacterial Cellulose and Its Physico-Chemical Properties (미생물 셀룰로오스 생산을 위한 당밀의 전처리 및 생산된 셀룰로오스의 물리화학적 특성)

  • Jung, Ho-Il;Jeong, Jin-Ha;Jeon, Young-Dong;Lee, Na-Ri;Park, Ki-Hyun;Kim, Yong-Gyun;Park, Geun-Tae;Son, Hong-Joo
    • Journal of Life Science
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    • v.19 no.10
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    • pp.1432-1437
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    • 2009
  • The aim of this study is to investigate cane molasses pretreatments for the production of cellulose by Acetobacter sp. V6, which has excellent bacterial cellulose (BC) producing capacity in the shaking culture. Among pretreatments of cane molasses, 1% (w/v) tricalcium phosphate (TP) treatment was more efficient in BC production. The physico-chemical properties of BCs that were produced in static and shaking cultures were also investigated. Although BC had an emulsifying ability, its emulsion stability was low. Water holding capacity (WHC) of BC was high; the WHC of BC produced in static culture was 14 times higher than that of $\alpha$-cellulose. In addition, the viscosity of BC was higher than that of $\alpha$-cellulose. Composition analysis by FT-IR showed no difference in composition between BC and plant cellulose. In the crystallinity analysis by XRD, all BC samples showed crystallinity. All BC samples showed reticulated structures consisting of ultrafine cellulose fibriles. Microfibriles of cellulose from static culture were especially more compact than those of cellulose from shaking culture.

Influence of Organic Fiber Kinds on Engineering Properties of Concrete (유기질 섬유 종류가 콘크리트의 공학적 특성에 미치는 영향)

  • Shin Hyun-Sup;Kim Kwang-Ryeon;Lee Gun-Cheol;Kim Byung-Gi;Han Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2006.05a
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    • pp.27-30
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    • 2006
  • This study investigated influence of organic fiber type and contents on engineering properties of concrete. Test showed that increase of fiber contents decreased fluidity of fresh concrete and it was even worse in concrete adding cellulose fiber. It is decided that concrete containing more than proper level of fiber should be considered. In addition, concrete adding more fiber, nylon and cellulose, resulted in increase of air content but it was satisfied in aimed value. Bleeding capacity of concrete containing more fiber significantly declined and setting time of that was also slightly retarded. For the properties of strength, both compressive and tensile strength of fiber containing concrete were indicated at similar value to control concrete. However, it is clear that if those concrete containing fiber revised the value of increased air contents at fresh state, the strength value of that would be slightly increased.

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