• Title/Summary/Keyword: 성 반응

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Fractional gas hold-up in trayed bubble column (Trayed 기포탑 반응기에서 높이에 따른 기포입자의 거동분석)

  • Yang, Jung Hoon;Hur, Young Gul;Yang, Jung-Il;Kim, Hak-Joo;Chun, Dong Hyun;Kim, Byung Kwon;Lee, Ho-Tae;Jung, Heon
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.77.1-77.1
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    • 2011
  • 슬러리 기포탑 반응기는 열 및 물질 전달의 용이성, 낮은 운전비용 및 장치의 간단성의 장점을 가지고 있어서 Fischer-Tropsch 반응, bio-reaction 등에 많이 응용되고 있다. 특히, 반응물은 기체 상태로 반응기에 투입이 되는데, 이 기포입자의 상승하는 힘을 바탕으로 기상/액상/고상이 균일하게 혼합되게 된다. 많은 연구자들이 이러한 기포탑 반응기의 성능을 개선하고자, 다양한 반응기 디자인에 대하여 보고하고 있다. 특히 반응기 내부에 tray를 설치함으로써, 기포 포집율을 증진시기고 액상의 역류를 최소화시키는 연구가 활발히 진행되고 있다. 본 연구에서는, 다양한 기공크기를 갖는 tray를 활용함으로써 높이에 따른 기포 포집율의 변화 및 반응기 내에 기포 입자의 거동 특성에 대하여 살펴보았다.

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Synthesis and Property of Hydrophilic-Hydrophobic Random Multiblock Poly(ether sulfone)s as Polyelectrolytes for Fuel Cell Application (연료 전지용 소수성/친수성 랜덤 멀티블럭 공중합체의 합성과 특성)

  • Choi, Kyu-Buem;Kim, Sang-Un;Kim, Young-Jun;Hong, Young-Taik
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.197-198
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    • 2009
  • 고분자 전해질막으로 사용할 수 있는 소수성/친수성 랜덤 멀티블럭 공중합체를 합성하였다. 공중합체는 수산화기를 각 말단에 가지고 있는 소수성 올리고머, 친수성 올리고머 및 반응성이 좋은 커플링 단량체로 친핵성 치환 반응을 활용하여 합성 하였다. 높은 반응성의 커플링 단량체의 존재로 비교적 낮은 온도에서 합성이 됨으로서 고온에서의 에테르-에테르 교환반응에 의한 랜덤화를 억제할 수 있었으며, 높은 중합도의 공중합체를 합성 할 수 있었다. 각 수산화기로 같은 말단으로 조정된 올리고머는 투입 비율의 조정으로 쉽게 이온교환용량을 조정할 수 있었다. 솔루션 캐스팅 방법으로 강도를 가지고 잘 휘어지며 투명한 전해질막을 제조할 수 있었다. 전해질막은 이온전도도, 물흡수율, 부피 변화율, 연료 투과성 등의 측정이 되었다.

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Kinetic Studies on Enzymatic Hydrolysis of Cellulose(II) - Evaluation of Several Factors for Enzyme Adsorption and Initial Hydrolysis - (섬유소 가수분해반응에 관한 연구(II) - 효소흡착과 가수분해반응에 관여하는 여러인자의 영향 -)

  • Lee, Yong-Hun;Kim, Chul
    • KSBB Journal
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    • v.6 no.2
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    • pp.167-174
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    • 1991
  • Enzymatic cellulose hydrolysis depends on the several factors such as the structural features (CrI, particle size and surface area, etc.), the nature of cellulase enzyme system, the inhibitory effects of products, and enzyme deactivation. At the presence of products on the initial hydro- lysis rate of cellulose, cellobiose has more severe inhibitory effect than glucose. Othewise, the inhibition effect of products for adsorbed enzyme is related to the glucose and cellobiose conentration hyperbolically. Enzyme deactivation of FPA and ${\beta}-glucosidase$ were expressed by exponential decay profile.

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Segregation Mode of Plant Height in Crosses of Rice Cultivars ⅩIV. Segregation of Culm Length and $GA_3$ Response in Crosses of Dwarf Cultivars (수도 품종간 교잡에 있어서 간장의 유전분리 ⅩIV. 단간 품종간 조합에 있어서 간장과 $GA_3$ 반응성의 분리)

  • ;Mun-Hue Heu
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.35 no.2
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    • pp.165-170
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    • 1990
  • In order to determine the relationship between dwarf gene and GA$_3$ response, three dwarf cultivars, Fukei 71, Seolak, and Tanginbozu, which were known to have d 50, d 47 and d 35 gene, respectively, were used as parents in this study. Three parents and their F$_1$ and F$_2$ generations were grown. Tillers of each plant were devided into two parts at 15 days after transplanting and was transplanted. One part of them was sprayed with GA$_3$ 50 ppm at booting stage. The internode length were measured at ripening stage in terms of GA$_3$ response. The internode was significantly elongated in Seolak and Tanginbozu, but not in Fukei 71. All F$_1$ plants of the crosses were tall, and their internode and culm were significantly elongated with the spraying of GA$_3$. Dwarf plants which are not responded to GA$_3$ were selected in the F$_2$'s of Seolak/Fukei 71 and Fukei 71/Tanginbozu crosses, and backcrossed to Fukei 71. All of these BC$_1$F$_1$ plants were uniform in the culm length and not responded to GA$_3$ treatment. The dwarf gene, d 50 of Fukei 71 seems to be closely associated with the facter of non-response to GA$_3$.

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Evaluation on Reactivity of By-Product Pozzolanic Materials Using Electrical Conductivity Measurement (전기전도도 시험방법을 활용한 산업부산물 포졸란재료의 반응성 평가)

  • Choi, Ik-Je;Kim, Ji-Hyun;Lee, Soo-Yong
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.5
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    • pp.421-428
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    • 2016
  • In this work, pozzolanic activities of various waste materials were compared with those of well-known by-product pozzolanic materials. Undensified and densified silica fume, ASTM class F and class C fly ash, and metakaolin were chosen as well-known pozzolanic materials, and bentonite powder, ceramic powder obtained from wash basin, and waste glass wool, which can possibly possess pozzolanic property, were chosen for comparison. Drop in electrical conductivity at $40^{\circ}C$ saturated lime solution was measured for each materials. The amount of Ca(OH)2 decomposed from cement paste at $450{\sim}500^{\circ}C$ was also measured to evaluate pozzolanic activity. The 28 day compressive strength were used to observe the mechanical property enhanced by incorporation of various waste materials. According to the experimental results, using "difference between maximum conductivity value and conductivity value at 4 hour" was found to be a reasonable approach to determine pozzolanic activity of a material. Pozzolanic activity measured using electrical conductivity correlates very well with that measured using the amount of Ca(OH)2 remained in the cement paste. Relatively good agreement was also found with electrical conductivity and 28 day compressive strength. It was found that electrical conductivity measurement can be used to evaluate pozzolanic activity of unknown materials.

오염지하수정화를 위한 반응벽체의 설계 및 시공

  • 이동호;지원현;이재원;박준범
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.434-437
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    • 2004
  • 본 반층벽체 적용지역의 경우, 침출수의 영향으로 암모니아성 질소의 농도가 최대 29.12mg/L까지 검출되고 있으며 반응물질은 암모니아성 질소제거에 적합한 제올라이트를 선정하였다. 투수성 및 다짐강도를 고려하여 왕사와 50:50의 비율로 혼합, 적용하였으며 지하수 평균유속은 0.0864m/d이고 평균지하수위는 원지반 기준 - 4.0m의 분포를 나타내었다. 지질조사 결과, 적용구간의 지질구조는 매립층, 풍화토, 풍차암, 연암의 순서로 분포하고 있으며, 반응벽체의 설계깊이는 현장 시추조사 결과를 바탕으로 지하수의 Under-pass를 방지하기 위하여 연암층 50cm까지 관입시키도록 설계하였다. 최종적으로 선정된 반응벽체의 규모는 35m(길이) $\times$ 1.2m(두께) $\times$ 8.5 ~ 9.42m(구간별 깊이)로 설계에 반영되었다. 현재, 지하수감시정을 이용한 모니터링 결과, 상부지하수 감시정에서의 오염원은 우기의 영향으로 간헐적으로 발생하고 있으나 하부 지하수 감시정에서의 암모니아성 질소농도는 불검출 되거나 0.5 mg/L 이하로 유지되고 있다.

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A Study in reuse of Hydrolyzed Reactive Dyes (가수분해된 반응성염료의 재사용에 관한 연구)

  • 최형민;김혜경
    • Journal of the Korean Society of Clothing and Textiles
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    • v.23 no.1
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    • pp.111-119
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    • 1999
  • 가수분해된 네 개의 반응성 염료를 이용하여 견, 양모 나일론 섬유를 염색할 때 영향을 미치는 여러 인자들에 대하여 연구하였다 염의 투입을 가수분해 전과 후로 달리하였을 때 염색된 직물의 K/S 값에 미치는 영향은 염료와 직물의 종류에 따라 각기 달랐으며 염의 영향은 염료의 분자 크기가 클 때 더 크게 나타났다. 이는 염 노동의 증가시 염욕 안에서의염료 용해도가 염료 분자가 클 때 더많은 영향을 받기 때문인 것으로 생각된다. 욕비 증가시에는 염색된 직물의 K/S값은 초기에 감소를 보이다가 높은 욕비에서 K/S값이 증가되었는데 이는 염의 농도의 감소로 인한 영향으로 사료된다. 가수분해된 반응성 염료로 염색된 직물의 수세 견뢰도는 염료의 분자 크기에 의해 영향을 받았으며 직물의 마찰 땀 견괴도는 Gray scale에서 3보다 높았다 본 연구의 결과는 면섬유 염색에 사용한 가수분해된 반응성 염료를 이용하여 견, 양모, 또는 나일론섬유의 염색에 재 사용할 수 있는 가능성을 제시하여 준다.

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Development of Surface Modified Tencel Fabrics through the Control of Fibrillation(Part II) - Fibrillation control effect through reactive dye treatment - (피브릴화 조절을 통한 다양한 감성의 텐셀소재 개발(제2보) -반응성 염료에 의한 피브릴화 조절 효과-)

  • Shin, Younsook;Son, Kyonghee
    • Journal of the Korean Society of Clothing and Textiles
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    • v.25 no.10
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    • pp.1738-1744
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    • 2001
  • 본연구의 목적은 반응성 염료를 이용한 텐셀섬유의 피브릴화 조절 효과를 표면 형태, 감량율, 역학적 성질 및 태의 변화의 측면에서 고찰하는데 있다. 반응성 염료에 의한 가교는 섬유의 비결정 영역의 구조를 변화시켜 피브릴화를 억제하였으며 또한 효소의 작용에 영향을 주어 감량율을 감소시켰다. 반응성 염료에 의한 가교는 역학적 성질 중 특히 전단강성, 압축에너지, 압축레질리언스를 증가시켰다. 염색후 효소처리한 시료는 다른 시료보다 numeri와 fukurami 값이 높아 더 나은 종합태를 보였다. 공정순서에 따라 약간씩 차이가 있는 촉감을 나타냈다.

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The Effect of Coal Particle Size on Char-$CO_{2}$ Gasification Reactivity by Gas Analysis (가스분석을 이용한 석탄 입자크기가 촤-$CO_{2}$ 가스화 반응성에 미치는 영향 연구)

  • Kim, Yong-Tack;Seo, Dong-Kyun;Hwang, Jung-Ho
    • Korean Chemical Engineering Research
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    • v.49 no.3
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    • pp.372-380
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    • 2011
  • Char gasification is affected by operating conditions such as reaction temperature, reactants gas partial pressure, total system pressure and particle size in addition to chemical composition and physical structure of char. The aim of the present work was to characterize the effect of coal particle size on $CO_{2}$ gasification of chars prepared from two different types of bituminous coals at different reaction temperatures(1,000-$1,400{^{\circ}C}$). Lab scale experiments were carried out at atmospheric pressure in a fixed reactor where heat was supplied into a sample of char particles. When a flow of $CO_{2}$(40 vol%) was delivered into the reactor, the char reacted with $CO_{2}$ and was transformed into CO. Carbon conversion of the char was measured using a real time gas analyzer having NDIR CO/$CO_{2}$ sensor. The results showed that the gasification reactivity increased as the particle size decreased for a given temperature. The sensitivity of the reactivity to particle size became higher as the temperature increases. The size effects became remarkably prominent at higher temperatures and became a little prominent for lower reactivity coal. The particle size and coal type also affected reaction models. The shrinking core model described better for lower reactivity coal, whereas the volume reaction model described better for higher reactivity coal.

Study on Mechanical Responses Induced by Hypoxia in Porcine Isolated Cerebral Artery (돼지 적출뇌혈관의 저산소 유발 수축반응에 관하여)

  • Kim, Yoong
    • The Korean Journal of Pharmacology
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    • v.29 no.2
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    • pp.203-212
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    • 1993
  • This study was designed to observe hypoxia-induced mechanical responses of porcine cerebral artery and to clarify their possible mechanisms. Hypoxia produced a transient vasoconstriction, recovering to the basal tension within 10 min and subsequent reoxygenation produced a biphasic (relaxalion-contraction) response in rings with endothelium under resting tension. Hypoxia produced a further contraction in rings precontracted with KCl or $PGF_{2{\alpha}}$, and following reoxygenation caused only sustained relaxation. Removal of the endothelium and pretreatment with nimodipine or indomethacin markedly attenuated the hypoxia- and reoxygenation-induced contractions. The KCl-induced contraction was not affected in hypoxic state, but contractions induced by $PGF_{2{\alpha}}$ or endothelin (ET) were inhibited in the hypoxia, the latter being more sensitive to the hypoxia. Upon reoxygenation, the attenuated contraction rapidly recovered to the original tension. Both hypoxia and reoxygenation significantly increased cyclic GMP content in the intact preparations, but not in the endothelium-removed ones. Acetylcholine (ACh) produced concentration-dependent relaxations in the intact endothelial rings precontracted with $PGF_{2{\alpha}}$ or endothelin, and the ACh-induced relaxation was inhibited by removal of endothelium and by hypoxia. ACh also increased cyclic GMP content in tissues pretreated with $PGF_{2{\alpha}}$ and the increase of cyclic GMP was abolished in hypoxic state. These results suggest that hypoxia- and reoxygenation-induced contractions are dependent on endothelium and extracellular calcium, and related to the release of prostaglandin-like substance(s).

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