• Title/Summary/Keyword: 성장온도

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Crystal structure investigation of AlN crystal grown on 6H-SiC seed by a physical vapor transport method (6H-SiC 종자 결정을 사용하여 PVT법으로 성장된 AlN 결정 연구)

  • Shin, Hee-Won;Lee, Dong-Hoon;Kim, Hwang-Ju;Park, Mi-Seon;Jang, Yeon-Suk;Lee, Won-Jae;Kim, Jung-Gon;Jeong, Seong-Min;Lee, Myung-Hyun;Seo, Won-Seon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.26 no.1
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    • pp.49-52
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    • 2016
  • The effect of process parameters such as the growth pressure and temperature on the AlN crystal growth has been investigated. AlN crystal was grown onto 6H-SiC seed crystal using PVT (Physical Vapor Transport) method. Crystal properties and morphology of AlN crystal was changed with growth pressure and temperature. Raman analysis confirmed that AlN crystals with different orientation were successfully grown on SiC seed crystal.

Microstructural ananalysis of AlN thin films on Si substrate grown by plasma assisted molecular beam epitaxy (RAMBE를 사용하여 Si 기판 위에 성장된 AIN 박막의 결정성 분석)

  • 홍성의;한기평;백문철;조경익;윤순길
    • Journal of the Korean Vacuum Society
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    • v.10 no.1
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    • pp.22-26
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    • 2001
  • Microstructures of AlN thin films on Si substrates grown by plasma assisted molecular beam epitaxy were analyzed with various growth temperatures and substrate orientations. Reflection high energy electron diffraction (RHEED) patterns were checked for the in-situ monitoring of the growth condition. X-ray diffraction(XRD), double crystal X-ray diffraction (DCXD), and transmission electron microscopy/diffraction (TEM/TED) techniques were employed to characterize the microstructure of the films after growth. On Si(100) sub-strates, AlN thin films were grown mostly along the hexagonal c-axis orientation at temperature higher than $850^{\circ}C$. On the other hand the AlN films on Si(111) were epitaxially grown with directional coherencies in AlN(0001)/Si(111), AlN(1100)/Si(110), and AlN(1120)/Si(112). The microstructure of AlN thin films on Si(111) substrates, with a full width at half maximum of almost 3000 arcsec at 2$\theta$=$36.2^{\circ}$, showed that the single crystal films were grown, even if they includ a lot of crystal defects such as dislocations and stacking faults.

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Effects of Fillers on Fatigue Crack Growth Rate of Ethylene Propylene Diene Monomer (충전제가 EPDM의 피로균열 성장속도에 미치는 영향)

  • Hong, Chang-Kook;Jung, Jae-Yeon;Cho, Dong-Lyun;Kaang, Shin-Young
    • Polymer(Korea)
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    • v.32 no.3
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    • pp.270-275
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    • 2008
  • Crack growth characteristics of elastomeric materials are an important factor determining the strength and durability. In this study, the fatigue crack growth characteristic of filled EPDM compounds with different reinforcing fillers, such as silica and carbon black, was investigated using a newly designed tester. Frequency and test temperature had significant effects on the fatigue crack growth. The crack growth rate decreased with increasing frequency and the rate increased with increasing temperature. A power law relationship between the tearing energy and crack growth was observed for filled EPDM compounds. The crack growth rate reduced with increasing filler contents. Silica filled EPDM showed a better fatigue resistance than carbon black filled EPDM. The crack growth rate of silica filled EPDM decreased up to 30 phr and increased again at 50 phr. The formation of microductile type pits was observed on the fatigue-failure surface of unfilled EPDM, and relatively coarse surface with randomly distributed tear lines was observed on the failure surface of silica filled EPDM.

A study on the repeatability of large size of AlN single crystal growth (AlN 단결정 성장에 대한 반복 성장성에 관한 연구)

  • Kang, Seung-Min
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.4
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    • pp.148-151
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    • 2018
  • A large single crystal of AlN was grown by PVT (Physical Vapor Transport) method. The AlN crystal shaped hexagonal of the diameter of about 46 mm and the thickness of 7.6 mm was grown using 33 mm seed crystal which was grown and made by ourselves. We tried to find out repeatable growth possibility for AlN crystal growth and then to evaluate the repeatability of the growth condition of the temperature of $1950{\sim}2100^{\circ}C$ and the ambient pressure of 0.1~1 atm.

Predictive Model for Growth of Staphylococcus aureus in Suyuk (수육에서의 Staphylococcus aureus 성장 예측모델)

  • Park, Hyoung-Su;Bahk, Gyung-Jin;Park, Ki-Hwan;Pak, Ji-Yeon;Ryu, Kyung
    • Food Science of Animal Resources
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    • v.30 no.3
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    • pp.487-494
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    • 2010
  • Cooked pork can be easily contaminated with Staphylococcus aureus during carriage and serving after cooking. This study was performed to develop growth prediction models of S. aureus to assure the safety of cooked pork. The Baranyi and Gompertz primary predictive models were compared. These growth models for S. aureus in cooked pork were developed at storage temperatures of 5, 15, and $25^{\circ}C$. The specific growth rate (SGR) and lag time (LT) values were calculated. The Baranyi model, which displayed a $R^2$ of 0.98 and root mean square error (RMSE) of 0.27, was more compatible than the Gompertz model, which displayed 0.84 in both $R^2$ and RMSE. The Baranyi model was used to develop a response surface secondary model to indicate changes of LT and SGR values according to storage temperature. The compatibility of the developed model was confirmed by calculating $R^2$, $B_f$, $A_f$, and RMSE values as statistic parameters. At 5, 15 and $25^{\circ}C$, $R^2$ was 0.88, 0.99 and 0.99; RMSE was 0.11, 0.24 and 0.10; $B_f$ was 1.12, 1.02 and 1.03; and $A_f$ was 1.17, 1.03 and 1.03, respectively. The developed predictive growth model is suitable to predict the growth of S. aureus in cooked pork, and so has potential in the microbial risk assessment as an input value or model.

MOCVD를 이용한 자발성장 InAs 양자점의 적층 성장 시 발생하는 파장변화량 제어

  • Choe, Jang-Hui;An, Seong-Su;Yu, Su-Gyeong;Lee, Jong-Min;Park, Jae-Gyu;Lee, Dong-Han;Jo, Byeong-Gu;Han, Won-Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.150-151
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    • 2011
  • 양자점 Laser Diode(LD)는 낮은 문턱전류, 높은 미분 이득을 갖으며 또한 온도변화에도 안정적이기 때문에 광통신분야에서 광원으로 양자점 LD를 사용하기 위한 연구가 계속되고 있다. 양자점은 fill factor가 낮기 때문에 양자점의 밀도를 높이거나 양자점을 적층 성장하여 fill factor를 높인다. 그러나 양자점을 적층 성장하면 각 층간의 응력, 수직적 결합, 전기적인 결합이 생기며 이는 양자점의 전기적, 광학적 특성에 영향을 미친다. 본 연구에서는 metal organic chemical vapor deposition (MOCVD)을 이용하여 InP기판 위에 자발성장 법으로 InAs 양자점을 다주기 성장하였으며 photoluminescence (PL)을 이용하여 광학적 특성을 분석하였다. precursor는 trimethylindium (TMI), trimethylgalium (TMGa), $PH_3$, $AsH_3$를 사용하였으며 carrier gas는 $H_2$를 사용하였다. InAs 양자점은 1100 nm의 파장을 갖는 InGaAsP barrier 위에 성장하였고, InAs와 InGaAsP의 성장온도는 $520^{\circ}C$이며 InAs 양자점 성장시 V/III 비는 3.66으로 일정하게 유지하였다. 그림 1은 양자점 성장시간을 0.11분으로 고정하여 3주기(A), 5주기(B), 8주기(C) 성장한 구조이며 그림 2는 양자점 성장시간을 3주기마다 0.01분씩 줄여가며 3주기는 0.11분${\times}$3(D), 6주기는 0.11분${\times}$3+0.10분${\times}$3(E), 9주기는 0.11분${\times}$3+0.10분${\times}$3+0.09분${\times}$3(F) 으로 성장한 성장구조이다. 각 성장한 시료는 PL을 이용하여 파장과 반치폭을 측정하였다. 그림 3은 양자점 성장시간을 고정한 시료 A, B, C의 PL파장과 PL반치폭 데이터이다. PL파장은 A, B, C 시료 각각 1504 nm, 1571 nm, 1702 nm이며 반치폭은 각각 140 meV, 140 meV, 150 meV이다. PL파장과 반치폭은 각각 3주기에서 6주기로 증가할 때 67 nm, 0 meV 6주기에서 9주기로 증가할 때는 131 nm, 10 meV 증가하였다. 다음 그림4는 양자점 성장시간을 조절하여 성장한 양자점 시료 D, E, F의 PL파장과 PL반치폭 데이터이다. PL파장은 D, E, F 시료 각각 1509 nm, 1556 nm, 1535 nm이며 반치폭은 각각 137 meV, 138 meV, 144 meV이다. PL파장과 반치폭은 각각 3주기에서 6주기로 증가할 때 47 nm, 1 meV 증가하였고, 6주기에서 9주기로 증가할 때는 21 nm 감소, 6 meV 증가하였다. 양자점 성장시간을 고정하여 다주기를 성장하였고 또 3주기마다 양자점 성장시간을 달리하여 다주기를 성장하였으며 PL을 이용해 광학적 특성을 연구하였다. 성장된 양자점의 PL 파장과 PL 반치폭 변화를 통해 적층구조에서 성장 주기가 늘어날수록 양자점의 크기가 증가하는 것을 확인하였고 또한 적층성장을 할 때 양자점 성장시간을 줄임으로써 양자점의 크기 변화를 제어 할 수 있었다.

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Study on Growth Optimization of InAs/GaSb Strained-Layer Superlattice Structures by High-Resolution XRD Analysis (고분해능 XRD 분석에 의한 InAs/GaSb 응력초격자 구조의 성장 최적화 연구)

  • Kim, J.O.;Shin, H.W.;Choe, J.W.;Lee, S.J.;Kim, C.S.;Noh, S.K.
    • Journal of the Korean Vacuum Society
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    • v.18 no.4
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    • pp.245-253
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    • 2009
  • For the growth optimization of InAs/GaSb (8/8-ML) strained-layer superlattice (SLS), the structure has been grown under various conditions and modes and characterized by the high-resolution x-ray diffraction (XRD) analysis. In this study, the strain modulation is induced by changing parameters and modes, such as the growth temperature, the ratio of V/III beam-equivalent-pressure (BEP), and the growth interruption (GI), and the strain variation is analyzed by measuring the angle separation of 0th-order satellite peak in XRD patterns. The XRD results reveal that the growth temperature and the V/III(Sb/Ga) ratio are major parameters to change the crystallineity and the strain modulation in SLS structures, respectively. We have observed that the SLS samples with compressive strain prepared in this study are show a transition to tensile strain with decreasing V/III(Sb/Ga) ratio, and the GI process is a sensitive factor giving rise to strain modulation. These results obtained in this study suggest that optimized growth temperature and V/III(Sb/Ga) ratio are $350^{\circ}C$ and 20, respectively, and the appropriate GI time is approximately 3 seconds just before InAs growth that the crystallineity is maximized and the strain relaxation is minimized.

Deposition Kinetics and Properties of Cu Films Deposited on the TiN Substuate (TiN 기판위에 형성된 Cu막의 성장양상 및 막특성)

  • Gwon, Yeong-Jae;Lee, Jong-Mu
    • Korean Journal of Materials Research
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    • v.6 no.1
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    • pp.116-123
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    • 1996
  • CVD와 무전해 도금법을 이용하여 TiN 기판상에 구리막을 성장시켰고 그 각각에 대해 증착조건에 따른 성장막의 morphology, 성장기구 및 비저항, 막의 치밀성 등의 물리적 특성을 조사하였다. CVD 증착막의 결정립 크기와 입간의 기공은 막두께에 비례하여 커지는 경향을 나타내었으며 비저항은 4.7$\mu$$\Omega$cm로 구리의 체적비저항값과 거의 비슷한 것으로 나타났다. 무전해 도금막은 초기에는 layer-by-layer mode로 나중에는 is-land growth mode로 성장하는 경향을 보였다. CVD구리막의 막질은 후열처리 분위기에 따라서도 상당한 차이를 보였다. CVD구리막의 막질은 후열처리 분위기에 따라서도 상당한 차이를 보였으며, 활성화 에너지로부터 35$0^{\circ}C$를 기준으로 증착기구가 변하는 것을 확인할 수 있었던 반면, 무전해 도금은 60-8$0^{\circ}C$의 온도 구간에서 증착기구는 변하지 않았으나 도금 온도가 높을수록 막표면이 거칠어지는 경향을 나타내었다. 7:1 BHF 에칭 실험의 결과 무전해도금에 의한 구리막에 비해 CVD구리막의 에칭속도가 더 빨랐으며 막질도 덜 치밀한 것으로 나타났다.

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Effects of the Czochralski growth parameters on the growth of $LiNbO_3$ crystals ($LiNbO_3$단결정에 미치는 CZ 성장조건의 영향)

  • Lee, Sang-Hak;Yun, Ui-Park
    • Korean Journal of Materials Research
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    • v.2 no.1
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    • pp.52-57
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    • 1992
  • The macro defects of $LiNbO_3$ crystals grown by the Czochralski method were strongly influenced by the single crystal growth parameters such as growth rate, thermal gradient and crystal rotation rate. The optimum growth conditions of a $LiNbO_3$ single crystal with 1" in diameter were $70~100^{circ}C/cm$ temperature gradient, 5~10 mm/hr growth rate and 40 rpm crystal rotation rate. In these conditions, we could grow crystals which had no cellular structure with easy diameter control, and any crack was not formed after the crystal was cooled.oled.

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Growth and characterization of the high quality ZnTe epilayers for opto-electronic devices (광전소자를 위한 고품질 ZnTe 단결정 박막의 성장과 특성)

  • 정양준;김대중;유영문;최용대
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.13 no.3
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    • pp.127-131
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    • 2003
  • High quality zincblende ZnTe(100) epilayers have been grown on semi-insulating $CaAs(100\pm2^{\circ})$substrate by hot-wall epitaxy. To grow high quality ZnTe epilayers, the growth temperature dependence of the surface topography, the growth rate, and the crystalline properties were investigated. From the photoluminescence measured at 10 K, the light hole and heavy hole free exciton emissions splitted by thermal tensile strain were observed and their first excited state emissions were also measured. The low temperature doublet of the heavy hole free exciton is because of the energy separation between longitudinal exciton and transverse exciton due to exciton-polariton coupling.