• Title/Summary/Keyword: 선형저밀도폴리에틸렌

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Crystallization Characteristics of Metallocene Low Density Polyethylene (메탈로센 선형 저밀도 폴티에틸렌의 결정화 거동)

  • 김경룡;한정우;조봉규;강호종
    • Polymer(Korea)
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    • v.25 no.6
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    • pp.833-839
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    • 2001
  • The crystallization characteristics of metallocene linear low density polyethylene was investigated by small angle light scattering and comparison was made with Ziegler-Natta linear low density polyethylene. The special efforts were made to find out the effects of branching number, length of branching and co-monomer content of m-LLDPE on the crystallization behavior of m-LLDPE. It was found that m-LLDPE has longer induction time to start crystallization from the amorphous state than that of conventional LLDPE with similar branching number, but the rate of crystallization seems not change much in both LLDPEs. Lowering of branching number in m-LLDPE resulted in both increasing of rate of crystallization and reducing induction time to crystallize. In general, the maximum size of spherulites of m-LLDPE is bigger than that of conventional LLDPE.

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Crystallization Characteristics of Metallocene Low Density Polyethylene/Low Density Polyethylene Blends (메탈로센 선형 저밀도 폴리에틸렌/선형 저밀도 폴리에틸렌 블렌드의 결정화 거동)

  • 김경룡;한정우;강호종
    • Polymer(Korea)
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    • v.25 no.6
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    • pp.840-847
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    • 2001
  • The crystallization characteristics of metallocene linear low density polyethylene (m-LLDPE)/linear low density polyethylene (LLDPE) blends were investigated. The effect of blending on the induction time for crystallization, spherulites growth rate, and maximum size of spherulites was mainly considered in this study. The formation of separate crystal which is well known crystallization behavior in LLDPE/LDPE blend was not found in m-LLDPE/LLDPE blends. The blending m-LLDPE to LLDPE caused the dramatic decrease in the induction time of m-LLDPE/LLDPE blends but it seems that the blend composition shows less effect on the induction time. Lower branching number in m-LLDPE resulted in the increasing of spherulites growth rate and the maximum size of spherulites is depend upon both the induction time and spherulites growth rate of LLDPE component affected by m-LLDPE.

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Mechanical Property Behaviors of Polyethylene Pipe due to Thermal-Degradation (열화시간에 따른 폴리에틸렌 파이프의 기계적 물성 거동)

  • Weon, Jong-Il;Choi, Kil-Yeong
    • Polymer(Korea)
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    • v.33 no.5
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    • pp.446-451
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    • 2009
  • Reliability evaluations of linear low density polyethylene (LLDPE) pipe with respect of thermal exposure time have been investigated in accordance with RS M 0042, which is a reliability standard for polymer pipe. As the thermal exposure time is prolonged, a progressive increase, until 250 days, in tensile strength and a slight increase in hardness are observed, while a proportional decrease in elongation at break is showed. These results can be explained by the increase of crystallinity, followed by the increase of crosslinking density, chain scission and the decrease in chain mobility, due to thermal oxidation as the exposure time increases. Long term hydrostatic pressure test result implies the existence of transition point from ductile to brittle fracture. Oxidation induction time (OIT) test is employed to monitor the thermo-oxidative degradation of LLDPE pipe. This result shows that after the exposure time is 250 days, the depletion of antioxidants added in LLDPE pipe occurs. An empirical equation as function of exposure time, under $100^{\circ}C$ thermal-degradation condition, is proposed to assess the remaining amount of antioxidants owing to thermo-oxidative degradation. Fourier transform infrared spectroscopy results show the increase of carbonyl (-C=O) and hydroxyl (O-H) function groups on the surface of thermally exposed LLDPE pipe. This result suggests that the hydrocarbon groups locally undergo the oxidation on the LLDPE surface due to thermal-degradation.

Modification of Linear Low Density Polyethylene by Irradiation of Electron Beam (전자선조사에 의한 선형저밀도폴리에틸렌의 개질)

  • 오장훈;천성득;황규면
    • The Korean Journal of Rheology
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    • v.10 no.4
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    • pp.256-258
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    • 1998
  • An experimental study was done to improve the processability and optical property of linear low density polyethylene(LLDPE) film. By modifying the molecular structure of LLDPE with electron beam we could get the improved processability and optical property of film. By appropriate dosing of electron beam and a small addition of UV-stabilizer it was possible to produce gel-free film with low haze. The proceassability was also improved.

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Thermal Behavior and Physical Properties of Low Density Polyethylene/Metallocene Linear Low Density Polyethylene Blends (저밀도 폴리에틸렌/메탈로센 선형 저밀도 폴리에틸렌 블렌드의 열적 거동 및 물성)

  • Kim, Jang-Yup;Hyun, Uk;Lee, Dong-Ho;Noh, Seok-Kyun;Lee, Sang-Won;Huh, Wan-Soo
    • Polymer(Korea)
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    • v.27 no.5
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    • pp.502-507
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    • 2003
  • The thermal and physical properties of low density polyethylene melt-blended with Metallocene linear low density polyethylenes were investigated. Since the Metallocene polyethylenes have similar MW and MWD except m-LLDPE4, it can be said that the thermal behavior and mechanical properties of the blends depend upon the l-octene comonomer content. The melting behavior of LDPE/m-LLDPE1 blends shows two melting peaks with LDPE contents higher than 50%, while the other blends show only one melting peak. It was observed that the blends show higher crystallization temperature and higher crystallinity with lower comonomer content. Initial modulus of a blend exhibited the behavior proportional to the crystallinity and the elongation at break of the blends was increased with increasing the m-LLDPE composition. Melt indices of the blends decreased with increasing the comonomer content of Metallocene LLDPE. Melt Index values of the blends show negative deviation.

A Study on Crystallization of Linear Low Density Polyethylene Particles from Decalin Solution (Decalin 용액에서 선형 저밀도 폴리에틸렌 입자의 결정화에 관한 연구)

  • Park, Keun-Ho;Jang, Young-Min
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.3
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    • pp.370-376
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    • 2012
  • We fabricated linear low density polyethylene (LLDPE) particles via crystallization from decalin solution. In the thermally induced phase separation (TIPS) process, formation of particles occurred during controlled cooling of LLDPE/decalin solution. Despite an increase of nucleation and growth rate for crystals at higher polymer concentrations, which generally results in larger particles than at lower concentration, the average diameter of LLDPE particles increased as LLDPE was more concentrated in decalin solution. In the FE-SEM micrographs, the observed particles from various concentrations were smaller than 10 ${\mu}m$, showing spherical morphologies. In addition to its effect on size, concentration of LLDPE had an broadening effect on the particle size distribution.

A Study on Recycling of Waste Polyethylene Film (폐폴리에틸렌 필름의 재활용에 관한 연구)

  • Lee, Hwan-Kwang
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.1
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    • pp.182-188
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    • 2008
  • The compounds of recycled polyethylene(PE) and fly-ashes were prepared. Polymers used were sorted PE from mixed plastics of household waste and Low Density Polyethylene(LDPE) and Linear Low Density Polyethylene(LLDPE) recycled from the scrap of packaging film plants. Fly-ashes were from the power plant and from the household waste incinerator. The tensile strength of recycled LDPE and LLDPE compounds decreased and the flexural modulus increased with greater amount of the power plant fly-ash. Anthracite fly-ash gave rise to slightly higher tensile and flexural strength of the LLDPE mixtures than bituminous coal fly-ash presumably due to higher content of unburned carbon. The incinerator fly-ash introduced to household waste PE enhanced both tensile strength and flexural modulus of the compounds. When LDPE and household waste PE were used together, the synergistic effect of incinerator fly-ash to household waste PE was offset by reduced crystallization of LDPE due to the filler particle. The compounds of household waste PE and incinerator fly-ash might be applied to structural materials for such as sewage pipe, which reduces the waste treatment cost and conserve the environment and resources.

Linear Low Density Polyethylene Preparation by Titanium-Based Ziegler-Natta Catalysts (티탄이 기본인 Ziegler-Natta 촉매에 의한 선형저밀도폴리에틸렌의 제조)

  • Dong-Ho Lee;Kyung-Eun Min;Cha-Ung Kim
    • Journal of the Korean Chemical Society
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    • v.31 no.1
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    • pp.110-117
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    • 1987
  • For the preparation of linear low density polyethylene (LLDPE), the copolymerization of ethylene and 1-butene was carried out with various catalysts of titanium alkoxidealkylaluminum compound in slurry phase. The effects of catalyst components, aging time, concentration of catalyst components, polymerization time and temperature on the catalytic activity and copolymer composition were examined. The properties of copolymer obtained were also considered with the correlation to the 1-butene contents. It has been found that the titanium tetra-n-butoxide-diethylaluminum chloride catalyst system was the most suitable for the production of LLDPE with higher catalytic activity, more 1-butene content and less soluble parts. The density, glass transition temperature, melting point and heat of fusion of copolymer were decreased with increasing 1-butene contents.

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Hydraulic Experiment on Roughness Coefficient of PE pipe (폴리에틸렌관의 조도계수에 관한 수리모형실험)

  • Dongwoo Ko;Byeong Wook Lee;Jae-Seon Yoon;Hyun-Gu Song
    • Proceedings of the Korea Water Resources Association Conference
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    • 2023.05a
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    • pp.288-288
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    • 2023
  • 도로, 철도 등의 횡단통로, 오폐수관로, 지하배수관 등 연약지반에서 상재하중과 부등침하에 의한 파괴 위험을 줄이기 위해 구조적인 안전성과 내구성이 개선된 다양한 관로들이 활용되고 있다. 관은 매설특성에 따라 콘크리트관, 도관, 합성수지관, 덕타일 주철관, 파형강관, 유리섬유 강화 플라스틱과 폴리에스테르수지 콘크리트관 등의 종류로 구분된다(환경부, 2017). 수리설계 시 이러한 관의 단면 규모 결정 및 흐름 특성을 파악하기 위해 관수로 유량측정에 이용되는 Manning의 경험식을 이용하고 있으며, 관로의 주요 재질에 따른 다양한 조도계수가 제시되어 있다. 새로운 재질을 이용하여 제작된 관은 수리실험을 통해 조도계수를 결정하는 것이 바람직하지만, 조도계수 실험은 대규모의 실험시설과 유량공급이 요구되기 때문에 여러 한계가 있다. PE관의 경우, 미국의 ASTM 표준에 의해 저밀도 폴리에틸렌(LDPE), 선형 저밀도 폴리에틸렌(LLDPE), 고밀도 폴리에틸렌(HDPE) 등으로 분류되는데 본 연구에서는 HDPE 재질의 서로 직경이 다른 다중벽관 PE관을 대상으로 조도계수를 결정하기 위한 현장 실규모 수리실험을 수행하였다. 본 실험에서는 식생, 수로의 불규칙성, 수로노선, 침전과 세굴, 장애물, 계절적 변화, 부유물질과 소류사는 무시되며 표면조도, 관의 크기와 형상, 수위와 유량이 조도계수에 영향을 미치는 주요 인자라고 할 수 있다. 수리실험은 실물모형(Prototype)으로 한국농어촌공사 농어촌연구원의 대형수리모형실험장에서 수행되었으며. 길이 24 m, 직경 150 mm의 PE 관은 고정식 개수로, 직경 800 mm의 관은 대형유사순환수로에 각각 설치되었다. 관로의 전면에 차폐막을 설치하여 상류부 수위를 안정시킨 상태에서 실험을 수행하였고, 차폐막으로부터 하류방향으로 약 7 m(측정기준지점), 11 m, 13 m, 15 m, 17 m 떨어진 곳에서 각각 수위와 유속을 측정하였다. 실험 결과, φ150관은 직경대비 수심이 클수록 조도계수가 감소하는 경향이 나타났고, φ800관은 직경대비 수심의 변화에 따른 조도계수의 경향이 크게 드러나지 않았다. 결론적으로 PE관의 조도계수는 수심별로 변화하는 것으로 나타났으며, 특정 수심을 지나면 조도계수가 다시 감소할 것으로 판단된다.

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Study of Structural Design of Polyethylene Pleasure Boat (폴리에틸렌 플레저 보트의 구조설계에 관한 연구)

  • Cho, Seok Swoo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.12
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    • pp.1551-1561
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    • 2012
  • Boat or yacht hulls are mainly built using FRP composite materials. FRP boat hull manufacturing has been restricted since 2000 under international regulations on ocean environment safety. FRP composite materials cannot be recycled and require more than 100 years to biodegrade. Therefore, alternatives to FRP have been proposed by many boat builders. Steel, aluminum, and FRP are commonly used as boat hull materials. Their design specifications are proposed as Korean register of shipping. However, the design specifications for inexpensive materials for a small boat have not yet been studied. Small shipbuilders manufacture and sell HDPE canoes or HDPE kayaks. In this study, a hull form was designed based on actual boats. The thickness of an HDPE boat hull was determined based on ISO 12215-5 structural design specifications.