• Composites Research
• /
• v.18 no.4
• /
• pp.14-20
• /
• 2005

To determine the effect of chemical structure of aromatic amino curing agents on thermal and mechanical properties, standard epoxy resin DGEBF (diglycidylether of bisphenol F) was cured with diaminodiphenyl methane (DDM) and diaminodiphenyl sulphone (DDS) in a stoichiometrically equivalent ratio. From this work the effect of aromatic amino curing agents on the thermal and mechanical properties is significantly influenced by the chemical structure of curing agents. In contrast, the results show that the DGEBF/DDS system having the sulfone structure between the benzene rings had higher values in the thermal stability, density, shrinkage ($\%$), thermal expansion coefficient, tensile modulus and strength, flexural modulus and strength than the DGEBF/DDM system having methylene structure between the benzene rings, whereas the DGEBF/DDS system presented low values in maximum exothermic temperature, conversion of epoxide, and grass transition temperature. These results are caused by the relative effects of sulfone group having strong electronegativity and methylene group having (+) repulsive property. The result of fractography shows that the grain distribution of DGEBF/DDS system is more irregular than that of the DGEBF/DDM system.

• Journal of the Korean Institute of Gas
• /
• v.14 no.3
• /
• pp.21-25
• /
• 2010

An objective of this study is to develop a polyurethane foam(PUF) maintaining its mechanical strength at room temperature as well as at extremely low temperature. The effect of temperature on the physical properties of PUF with the increase in polyol functionality was investigated. At room and cryogenic temperature, compressive strengths of the PUFs increased up to 70% and 30% with an increase in polyol functionality, respectively. At room temperature tensile strength of PUFs tends to increase as functionality of polyol increases, however, the strength at $-190^{\circ}C$ shows different tendency. Compressive strength of PUF is higher in cryogenic temperature than in room temperature. However, as the number of polyol functionality become more than 4, tensile strength of PUF is lower in cryogenic temperature than in room temperature.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.12 no.6
• /
• pp.109-118
• /
• 2008

Carbon fiber reinforced polymer(CFRP) can be bonded to the soffit of a concrete beam as a means of repairing and strengthening the beam. In such beams, materials, concrete and carbon fiber sheets, are different in coefficient of thermal expansion. Consequently, interfacial shear stresses can be increased and debonding failure may occur at the plate ends due to temperature rising. This paper presents a method of approximate closed-form solutions for the interfacial shear stresses and conducts a beam test to compare the numerical results. In case of temperature rising over $30^{\circ}C$, interfacial stress of 0.91MPa is occurred at the end of sheet. Therefore, using carbon fiber sheet for strengthening the concrete beam, it is necessary to consider the thermal effects and to evaluate the long time behavior of the concrete beam by temperature change.

• Applied Chemistry for Engineering
• /
• v.10 no.7
• /
• pp.990-995
• /
• 1999

To determine the effect of chemical structure of linear amine curing agents on thermal and mechanical properties, standard epoxy resin DGEBA was cured with ethylene diamine(EDA) and hexamethylene diamine(HMDA) in a stoichiometrically equivalent ratio. From this work, the effect of linear amine curing agents on the thermal and mechanical properties is significantly influenced by the chemical structure or chain length of curing agents. In contrast, the results show that the DGEBA/EDA system having the two carbons had higher values in the thermal stability, maximum conversion of epoxide, density, glass transition temperature, tensile modulus, flexural strength, and flexural modulus than the DGEBA/HMDA system having the six carbons, whereas the DGEBA/EDA cure system had relatively low values in the shrinkage(%), thermal expansion coefficient, tensile strength, and had similar values in the maximum exothermic temperature, and conversion of epoxide compared to the DGEBA/HMDA cure system. This findings indicate that packing ability in the HMDA structure affects the thermal and mechanical properties.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.35 no.4
• /
• pp.779-789
• /
• 2015

Because cable-supported bridges have long spans and large members, their movements and geometrical changes by temperatures tend to be bigger than those of small or medium-sized bridges. Therefore, it is important for maintenance engineers to monitor and assess the effect of temperature on the cable-supported bridges. To evaluate how much the superstructure expands or contracts when subjected to changes in temperature is the first step for the maintenance. Thermal movements of a cable-stayed bridge in service are evaluated by using long-term temperatures and displacements data. Displacements data are obtained from extensometers and newly installed GNSS (Global Navigation Satellite System) receivers on the bridge. Based on the statistical data such as air temperatures, each sensor's temperatures, average temperatures and effective temperatures, correlation analysis between temperatures and displacements has been performed. Average temperatures or effective temperatures are most suitable for the evaluation of thermal movements. From linear regression analysis between effective temperatures and displacements, the variation rate's of displacement to temperature have been calculated. From additional regression analysis between expansion length's and variation rate's of displacement to temperature, the thermal expansion coefficient and neutral point have been estimated. Comparing these parameters with theoretical and analytical results, a practical procedure for evaluating the real thermal behaviors of the cable-supported bridges is proposed.

• Applied Chemistry for Engineering
• /
• v.17 no.1
• /
• pp.73-81
• /
• 2006

Heat treatment condition for the stabilization of foamed glass block through the foaming process of the hydrolized waste glass was investigated and scale-up test for the manufacturing of foamed glass was also attempted for the actual foaming process. Proper heat treatment condition was quenching from the foaming temperature to $550{\sim}600^{\circ}C$ for stabilization, and then annealing from stabilization temperature to $200^{\circ}C$ and holding up at $200^{\circ}C$ for removal thermal stress, and then annealing to the room temperature with cooling speed of $0.3^{\circ}C/min$. Through this heat treatment conditions, foamed glass block with size of $250mm{\times}250mm{\times}90mm$ was produced successfully. The properties of this foamed glass block showed density of $0.28{\pm}0.06g/cm^3$, thermal conductivity of $0.048{\pm}0.005kcal/hm^{\circ}C$, moisture absorption of $0.5{\pm}0.09vol%$, linear expansion coefficient of $(8.6{\pm}0.2){\times}10^{-6}m/m^{\circ}C$($400^{\circ}C$), flexural strength of $15.0{\pm}0.6kg/cm^2$, and compression strength of $39.5{\pm}0.6kg/cm^2$.

• Composites Research
• /
• v.12 no.4
• /
• pp.71-78
• /
• 1999

To determine the effect of chemical structure of linear amine curing agents on thermal and mechanical properties, standard epoxy resin DGEBA was cured with diaminodiphenyl methane (DDM), diaminodiphenyl sulphone (DDS) in a stoichiometrically equivalent ratio. From this work, the effect of aromatic amine curing agents. In contrast, the results show that the DGEBA/DDS cure system having the sulfone structure between the benzene rings had higher values in the conversion of epoxide, density, shrinkage (%), glass transition temperature, tensile modulus and strength, flexural modulus and strength than the DGEBA/DDM cure system having methylene structure between the benzene rings, whereas the DGEBA/DDM cure system presented higher values in the maximum exothermic temperature, thermal expansion coefficient, and thermal stability. These results are caused by the relative effects of sulfone group having strong electronegativity and methylene group having (+) repulsive property and stem from the effect of the conversion ratio of epoxide group. The result of fractography shows that the each grain size of the DDM/DGEBA system with feather-like structure is larger than that of the DDS/DGEBA system.

• Korean Journal of Optics and Photonics
• /
• v.21 no.3
• /
• pp.123-128
• /
• 2010

Sum frequency generation was utilized to obtain a yellow laser with the wavelength of 578.4 nm for a probe laser of an Yb lattice clock. The output of an Nd:YAG laser with wavelength of 1319 nm and that of an Yb-fiber laser with wavelength of 1030 nm were passed through a waveguided periodically-poled lithium niobate (WG-PPLN) for sum frequency generation. It is required that the probe laser has a linewidth of the order of 1 Hz to fully resolve the Yb lattice clock transition. Thus, the linewidth of the probe laser was reduced by stabilizing the frequency to a super-cavity. This was made of ULE with a low thermal expansion coefficient, and was mounted on an active vibration-isolation table at the optimal point for the reduced sensitivity to vibration. Also, this was installed in a vacuum chamber, and the temperature was stabilized to 1 mK level. This system was installed in an acoustic enclosure to block acoustic noise. The finesse of the super-cavity was measured to be 380 000 from the photon life time of the cavity.