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Trend of Nitrogen Oxide Reduction Technologies in Cement Industry (시멘트 산업에서의 질소산화물 저감 기술 동향)

  • Seo, JunHyung;Kim, YoungJin;Cho, KyeHong;Cho, JinSang;Han, KyungHo;Yoon, DoYoung
    • Resources Recycling
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    • v.29 no.6
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    • pp.114-124
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    • 2020
  • In the cement industry, NOx emission is recognized as an important problem, and NOx reduction technologies can be divided into process change, staged combustion, low NOx burner, selective non-catalytic reduction and selective catalytic reduction method. The operation of the selective non-catalytic reduction method, which is the most used in the cement industry, is expected to make it difficult to meet the emission standards to be strengthened in the future, and it is necessary to improve equipment such as SCR and secure technologies. Recently, we are developing technologies for simultaneous application of SNCR and SCR, dust and denitrification filter technology, and removal technology using NO oxidation.

Optimal Parameter Extraction based on Deep Learning for Premature Ventricular Contraction Detection (심실 조기 수축 비트 검출을 위한 딥러닝 기반의 최적 파라미터 검출)

  • Cho, Ik-sung;Kwon, Hyeog-soong
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.23 no.12
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    • pp.1542-1550
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    • 2019
  • Legacy studies for classifying arrhythmia have been studied to improve the accuracy of classification, Neural Network, Fuzzy, etc. Deep learning is most frequently used for arrhythmia classification using error backpropagation algorithm by solving the limit of hidden layer number, which is a problem of neural network. In order to apply a deep learning model to an ECG signal, it is necessary to select an optimal model and parameters. In this paper, we propose optimal parameter extraction method based on a deep learning. For this purpose, R-wave is detected in the ECG signal from which noise has been removed, QRS and RR interval segment is modelled. And then, the weights were learned by supervised learning method through deep learning and the model was evaluated by the verification data. The detection and classification rate of R wave and PVC is evaluated through MIT-BIH arrhythmia database. The performance results indicate the average of 99.77% in R wave detection and 97.84% in PVC classification.

Using Mean Shift Algorithm and Self-adaptive Canny Algorithm for I mprovement of Edge Detection (경계선 검출의 향상을 위한 Mean Shift 알고리즘과 자기 적응적 Canny 알고리즘의 활용)

  • Shin, Seong-Yoon;Pyo, Seong-Bae
    • Journal of the Korea Society of Computer and Information
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    • v.14 no.7
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    • pp.33-40
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    • 2009
  • Edge detection is very significant in low level image processing. However, majority edge detection methods are not only effective enough cause of the noise points' influence, even not flexible enough to different input images. In order to sort these problems, in this paper an algorithm is presented that has an extra noise reduction stage at first, and then automatically selects the both thresholds depending on gradient amplitude histogram and intra class minimum variance. Using this algorithm, can fade out almost all of the sensitive noise points, and calculate the propose thresholds for different images without setting up the practical parameters artificially, and then choose edge pixels by fuzzy algorithm. In finally, get the better result than the former Canny algorithm.

Research and Development Trends of Ion Exchange Membrane Processes (이온교환막 공정의 연구개발 전망)

  • Lee, Hong-Joo;Choi, Jaehwan;Chang, Bong-Jun;Kim, Jeong-Hoon
    • Prospectives of Industrial Chemistry
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    • v.14 no.6
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    • pp.21-28
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    • 2011
  • 이온교환막을 이용한 전기적 탈염기술은 막모듈 내에 양이온교환막과 음이온교환막을 교대로 장착시키고 모듈의 양단 전극에 전압을 적용함으로써 물속에 용존되어 있는 양이온과 음이온들을 전기의 힘을 이용하여 선택적으로 투과시키는 원리를 기반으로 하는 청정공정 기술이다. 이온교환막 공정은 전통적으로 산/알칼리의 생산, 산업폐수의 중금속의 제거, 해수의 담수화, 반도체 산업의 초순수의 제조, 해수에서 식염의 제조, 발효산업의 유기산 및 아미노산의 회수 등 다양한 산업분야에서 응용되어 왔다. 최근에는 이러한 기존의 응용분야에서 벗어나 새롭게 응용분야가 넓어지고 있다. 이온교환막과 다공성 탄소전극을 결합한 막축전식 해수담수화기술, 해수와 담수의 염도차를 이용한 역전기투석식 해수발전 등의 새로운 선택분리기능 및 응용분야를 가진 이온교환막의 개발 및 공정에 관한 연구가 활발히 이루어지고 있다. 그러나 국내에서는 이온교환막이 아직 상용화되지 않고 있어 이온교환막을 이용한 응용연구가 활발하게 진행되지 못하고 있어 그 개발이 시급하다. 본 논문에서는 먼저 이온교환막을 이용한 전기투석식 탈염기술, 물분해 전기투석, 전기탈이온 공정에 관한 동향을 조사하였다. 아울러 미래의 이온교환막의 응용기술인 해수담수화기술로서 역삼투법과 경쟁하여 에너지를 낮게 소모할 것으로 예상되는 분리막을 이용한 막축전식 탈염기술과 무한한 신재생에너지원인 해수와 담수를 이용한 역전기투석 해수발전기술에 대해 기술의 원리들과 최근의 연구동향 등을 정리하였다.

Usefulness of Region Cut Subtraction in Fusion & MIP 3D Reconstruction Image (Fusion & Maximum Intensity Projection 3D 재구성 영상에서 Region Cut Subtraction의 유용성)

  • Moon, A-Reum;Chi, Yong-Gi;Choi, Sung-Wook;Lee, Hyuk;Lee, Kyoo-Bok;Seok, Jae-Dong
    • The Korean Journal of Nuclear Medicine Technology
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    • v.14 no.1
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    • pp.18-23
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    • 2010
  • Purpose: PET/CT combines functional and morphologic data and increases diagnostic accuracy in a variety of malignancies. Especially reconstructed Fusion PET/CT images or MIP (Maximum Intensity Projection) images from a 2-dimensional image to a 3-dimensional one are useful in visualization of the lesion. But in Fusion & MIP 3D reconstruction image, due to hot uptake by urine or urostomy bag, lesion is overlapped so it is difficult that we can distinguish the lesion with the naked eye. This research tries to improve a distinction by removing parts of hot uptake. Materials and Methods: This research has been conducted the object of patients who have went to our hospital from September 2008 to March 2009 and have a lot of urine of remaining volume as disease of uterus, bladder, rectum in the result of PET/CT examination. We used GE Company's Advantage Workstation AW4.3 05 Version Volume Viewer program. As an analysis method, set up ROI in region of removal in axial volume image, select Cut Outside and apply same method in coronal volume image. Next, adjust minimum value in Threshold of 3D Tools, select subtraction in Advanced Processing. It makes Fusion & MIP images and compares them with the image no using Region Cut Definition. Results: In Fusion & MIP 3D reconstruction image, it makes Fusion & MIP images and compares them by using Advantage Workstation AW4.3 05's Region Cut Subtraction, parts of hot uptake according to patient's urine can be removed. Distinction of lesion was clearly reconstructed in image using Region Cut Definition. Conclusion: After examining the patients showing hot uptake on account of volume of urine intake in bladder, in process of reconstruction image, if parts of hot uptake would be removed, it could contribute to offering much better diagnostic information than image subtraction of conventional method. Especially in case of disease of uterus, bladder and rectum, it will be helpful for qualitative improvement of image.

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CONSIDERATIONS OF ANESTHETIC METHOD OF DEEP IMPACTED MESIODENS (심부 매복 정중 과잉치 수술 시 마취방법 선택)

  • Min, Soo-Young;Song, Je-Seon;Lee, Jae-Ho;Choi, Hyung-Jun;Son, Heung-Kyu;Kim, Seong-Oh
    • Journal of the korean academy of Pediatric Dentistry
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    • v.39 no.1
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    • pp.90-96
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    • 2012
  • Supernumerary tooth occurs most frequently at premaxilla area. Followed by mandibular premolar area, mandibular fourth molar area, maxillary paramolar area. Mesiodens are mainly impacted in the palatal area and surgical approach is made at palatal side. The time of surgery remains controversial. In case of inverted or horizontal impacted supernumerary tooth, intraosseous tooth movement and vertical growth of premaxilla makes surgical extraction more difficult. And also the more quantity of removed bone is, the higher degree of difficulty is. Inverted mesiodens of these cases were impacted superior to apex level of adjacent permanent incisor. Although CT examination revealed exact location of impacted tooth, surgical procedure including ostectomy may take a long time more than expected. So, before surgical extraction, it's need to be considered several factors such as necessity of CT taking, degree of difficulty, direction of surgical approach, necessity of general anesthesia etc.

A Design Approach to $CrO_x/TiO_2$-based Catalysts for Gas-phase TCE Oxidation (기상 TCE 제거반응용 $CrO_x/TiO_2$계 복합 산화물 촉매 디자인)

  • Yang, Won-Ho;Kim, Moon-Hyeon
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.4
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    • pp.368-375
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    • 2006
  • Single and complex metal oxide catalysts supported onto a commercial DT51D $TiO_2$ have been investigated for gas-phase TCE oxidation in a continuous flow type fixed-bed reaction system to develop a better design approach to catalysts for this reaction. Among the $TiO_2$-supported single metal oxides used, i.e., $CrO_x,\;FeO_x,\;MnO_x,\;LaO_x,\;CoO_x,\;NiO_x,\;CeO_x\;and\;CuO_x$, with the respective metal contents of 5 wt.%, the $CrO_x/TiO_2$ catalyst was shown to be most active for the oxidative TCE decomposition, depending significantly on amounts of $CrO_x\;on\;TiO_2$. The use of high $CrO_x$ loadings greater than 10 wt.% caused lower activity in the catalytic TCE oxidation, which is probably due to production of $Cr_2O_3$ crystallites on the surface of $TiO_2$. $CrO_x/TiO_2$-supported $CrO_x$-based bimetallic oxide catalysts were of particular interest in removal efficiency for this TCE oxidation reaction at reaction temperatures above $200^{\circ}C$, compared to that obtained with $CrO_x$-free complex metal oxides and a 10 wt.% $CrO_x/TiO_2$ catalyst. Catalytic activity of 5 wt.% $CrO_x-5$ wt.% $LaO_x$ in the removal reaction was similar to or slightly higher than that acquired for the $CrO_x$-only catalyst. Similar observation was revealed for 5 wt.% $CrO_x$-based bimetallic oxides consisting of either 5 wt.% $MnO_x,\;CoO_x,\;NiO_x\;or\;FeO_x$. These results represent that such $CrO_x$-based bimetallic systems for the catalytic TCE oxidation on significantly minimize the usage of $CrO_x$ that is well known to be one of very toxic heavy metals, and offer a very useful technique to design new type catalysts for reducing chlorinated volatile organic substances.

Development of an Analytical Method for Fluxapyroxad Determination in Agricultural Commodities by HPLC-UVD (HPLC-UVD를 이용한 농산물 중 Fluxapyroxad 잔류분석법 개발)

  • Kwon, Ji-Eun;Kim, HeeJung;Do, Jung-Ah;Park, Hyejin;Yoon, Ji-Young;Lee, Ji-Young;Chang, Moon-Ik;Rhee, Gyu-Seek
    • Journal of Food Hygiene and Safety
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    • v.29 no.3
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    • pp.234-240
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    • 2014
  • Fluxapyroxad is classified as carboxamide fungicide that inhibits succinate dehydrogenase in complex II of mitochondrial respiratory chain, which results in inhibition of mycelial growth within the fungus target species. This study was carried out to assure the safety of fluxapyroxad residues in agricultural products by developing an official analytical method. A new, reliable analytical method was developed and validated using High Performance liquid Chromatograph-UV/visible detector (HPLC-UVD) for the determination of fluxapyroxad residues. The fluxapyroxad residues in samples were extracted with acetonitrile, partitioned with dichloromethane, and then purified with silica solid phase extraction (SPE) cartridge. Correlation coefficient($R^2$) of fluxapyroxad standard solution was 0.9999. The method was validated using apple, pear, peanut, pepper, hulled rice, potato, and soybean spiked with fluxapyroxad at 0.05 and 0.5 mg/kg. Average recoveries were 80.6~114.0% with relative standard deviation less than 10%, and limit of detection (LOD) and limit of quantification (LOQ) were 0.01 and 0.05 mg/kg, respectively. All validation parameters were followed with Codex guideline (CAC/GL 40). LC-MS (Liquid Chromatograph-Mass Spectrometer) was also applied to confirm the analytical method. Base on these results, this method was found to be appropriate fluxapyroxad residue determination and can be used as the official method of analysis.

Removal of CO2 from Syngas(CO2 and H2) Using Nanoporous Na2CO3/Al2O3 Adsorbents (나노기공성 Na2CO3/Al2O3 흡착제를 이용한 합성가스(CO2, H2) 내 CO2 제거)

  • Bae, Jong-Soo;Park, Joo-Won;Kim, Jae-Ho;Lee, Jae-Goo;Kim, Younghun;Han, Choon
    • Korean Chemical Engineering Research
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    • v.47 no.5
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    • pp.646-650
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    • 2009
  • Hydrocarbon gases generated from the gasification of waste could be converted into $CO_2$ and $H_2$ using reforming catalysts and then $CO_2$ was selectively adsorbed and removed to obtain pure hydrogen. To optimize adsorption efficiency for $CO_2$ removal, $Na_2CO_3$ was supported on nanoporous alumina and the efficiency was compared with commercial alumina(Degussa). Nanoporous adsorbents formed more uniform pores and larger surface area compared to adsorbents using commercial alumina. The increase of $Na_2CO_3$ loading improved adsorption of $CO_2$. Finally, the highest adsorption capacity per unit mass of $Na_2CO_3$ could be achieved when the loading of $Na_2CO_3$ reached up to 20wt%. When the content of $Na_2CO_3$ increased above 20 wt%, it aggregated on the surface, and the pore volume was decreased. Used adsorbents could be recycled by the thermal treatment.

$CO_2$ Removal Process Analysis and Modeling for 300MW IGCC Power Plant (300MW급 IGCC Power Plant용 $CO_2$ 제거공정 분석 및 모델링)

  • Jeon, Jinhee;Yoo, Jeongseok;Paek, Minsu
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.130.2-130.2
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    • 2010
  • 2020년까지 대형 CCS (Carbon Capture and Storage) Demo Plant 시장 (100MW 이상) 이 형성될 전망이다. 발전 부문에서 대규모 CCS 실증 프로젝트는 총 44개이며 연소전(41%), 연소후(28%), 순산소(3%) 프로젝트가 계획되어 있다. 순산소 연소 기술은 실증진입단계, 연소후(USC) 기술은 상용화 추진단계, 연소전 (IGCC) 기술은 실증완료 이후 상용화 진입 단계이다. IGCC 발전의 석탄가스화 기술은 타 산업분야에 서 상용화 되어있어 기술신뢰성이 높다. IGCC 단위설비 기술 개발을 통한 성능개선 및 비용절감에 대한 잠재력을 가지고 있기 때문에 미래의 석탄발전기술로 고려되고 있다. IGCC 기술은 가장 상용화에 앞서있지만 아직까지 IGCC+CCS 대형 설비가 운전된 사례가 전 세계적으로 없으며 미국 EPRI 등에서 Feasibility Study 단계이다. 현재 국책과제로 수행중인 300MW급 태안 IGCC 플랜트를 대상으로 향후 CCS 설비를 적용했을 경우에 대해 기술 타당성 검증을 목적으로 IGCC+CCS 모델링을 수행하였다. 모델링은 스크러버 후단의 합성 가스를 대상으로 하였다. Water Gas Shift Reaction (WGSR) 공정 및 Selexol 공정을 구성하여 최종 단에서 수소 연료를 생산할 수 있도록 하였다. WGSR 공정은 Co/Mo 촉매반응기로 구성되었다. WGSR 모델링을 통하여 주입되는 스팀량 (1~2 mol-steam/mol-CO) 및 온도 변화 ($220-550^{\circ}C$)에 따른 CO가스의 전환율을 분석하여 경제적인 설계조건을 선정하였다. Selexol 공정은 $H_2S$ Absorber, $H_2S$ Stripper, $CO_2$ Absorber, $CO_2$ Flash Drum으로 구성된다. Selexol 공정의 $CO_2$$H_2S$ 선택도를 분석 하였으며 단위 설비별 설계 조건을 예측하였다. 모델링 결과 59kg/s의 합성가스($137^{\circ}C$, 41bar, 가스 조성은 $CO_2$ 1.2%, CO 57.2%, $H_2$ 23.2%, $H_2S$ 0.02%)가 WGSR Process를 통해 98% CO가 $CO_2$ 로 전환되었다. Selexol 공정을 통해 $H_2S$ 제거율은 99.9%, $CO_2$제거율은 96.4%이었고 14.9kg/s의 $H_2$(86.9%) 연료를 얻었다. 모델링 결과는 신뢰성 검증을 통해 IGCC+CCS 전체 플랜트의 성능예측과 Feasibility Study를 위한 자료로 활용될 예정이다.

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