• Economic and Environmental Geology
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• v.46 no.2
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• pp.141-151
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• 2013

This study examines the mineralogy of sepiolites occurred within the carbonaceous rocks of Songak schist and Pyeongtaek migmatitic gneiss of Precambrian Seosan group, in the western part of Chungnam. Host rocks of the sepiolite were dolomitic rocks and have experienced hydrothermal alteration and metamorphism. Mesozoic granite is assumed as a main source of hydrothermal alteration for the dolomitic rocks. Some of the tremolite asbestos coexist with the sepiolites. Representative sepiolite and tremolite samples were collected from the layers cracks or fractures of the dolomitic rocks and/or examined with microscope with microscope, XRD, SEM and TEM. Sepiolites are mainly recognized along the cracks assumed as pathways of hydrothermal solution. Tremolites are mainly found at layers or cracks of the dolomitic rocks and occur as asbestos as well as non-asbestos forms. It was confirmed that some of the tremolite asbestos were coexisted with the sepiolites. Overall results suggest that the occurrences of sepiolites within the dolomitic rocks mainly result in the hydrothermal alteration and the fluid from the acidic rocks, possibly granites. It also suggests that coexisting tremolite asbestos were formed by similar geological environment.

• Journal of the Mineralogical Society of Korea
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• v.31 no.3
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• pp.193-213
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• 2018

Soil geochemical exploration to check anomalies related to mineralization was carried out targeting around Quy Hop area within Nghe An province, Northern Vietnam. The interval of sampling are horizontal 250 m with 13 line and longitudinal 300 m with 25 line, resulting in 325 soil samples. Based on the result of soil geochemical exploration, the pitting survey was carried out targeting the grid point with high TREO content, resulting in 73 soil samples within 8 pits. The geology of the survey area are consisted of Ban Chieng biotite granite complex intruding Bu Khang formation comprising of schist, gneiss and limestone. In order to elucidate the source rock of monazite and xenotime confirmed from heavy sand, soil geochemical exploration was carried out. By ICP-MS result of soil samples, total REE oxide content of background amount is about 1.4 times of crustal abundance, depleting the light rare earth (about 0.2 times) and enriching the heavy rare earth (about 1.5 times). By ICP-MS result of pit soil samples, we identified TREO more than 1,000 ppm in 6 pits. It may be considered that REE ore bodies may develop in NE-SW direction, compared with the geochemical results of Quy Chau area.

• Journal of Korean Society of Forest Science
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• v.85 no.4
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• pp.571-576
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• 1996

The geological and hydrological survey was carried out in Hyuseok-dong landslide area(10 ha), Youngchoon-myeon, Danyang-gun, Choongcheongbuk-do. The results showed that the bed rocks in this area consisted of shale, sandstone and limestone, and the piles of stones debris were also scattered around the hill above the study area. Soil texture was sandy loam, and bulk density of the soil in the lower part of the area was higher than that of the upper part, but void ratio of the soil in the lower part was lower than that of the upper part. Subsurface water was springing out to the surface in many places in this area. In this area, the storms over 70mm/day were frequent during the summer period from June through September. It was concluded that the occurrence of landslide had a close relationship with the geological characteristics, hydrological conditions and the rainfall distribution.

• Korean Journal of Soil Science and Fertilizer
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• v.39 no.5
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• pp.245-252
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• 2006

This experiment was conducted to investigate the distribution and compositions of clay mineral and to replenish the soil classification system in Korea. Soil layer samples were collected from 26 residuum and colluvium soil series out of 390 soil series in Korea, and then analyzed for soil physical and chemical characteristics, mineral and chemical compositions of clay in B horizon soils. Major clay minerals of residuum and colluvium were illite and chlorite in soils originated from the sedimentary rock such as limestone, shale, sandstone and conglomerate; quartz and kaolin in soils originated from rhyolite, neogene deposits, porphyry and tuff; and kaolin and quartz in the soils originated from granite, granite gneiss and anorthosite. Clay minerals in Korean soils were divided into 4 groups: mixed mineral group(MIX) mainly contained with illite, kaolin and vemiculite; kaolin group(KA) with kaolin and illite; chlorite group(CH) with chlorite and illite; and smectite group(SM) with kaolin, illite and smectite. The most predominant clay mineral group was kaolin group(KA) with kaolin and illite; an mixed mineral group(MIX) with illite, kaolin and vemiculite. Cation exchange capacity (CEC) of clay was low in the soils mainly composed with MIX and KA groups and silica-alumina molar ratio of clay was high in the soils composed with SM group

• Economic and Environmental Geology
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• v.28 no.6
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• pp.635-646
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• 1995

Mineralized zone in the Dongyang talc deposits occurs on the lowest dolomite member of the Hyangsanri Dolomite belonging to the Ogcheon Supergroup. Ore bodies are emplaced as pipe-like body along the axis of minor folds plunging $40^{\circ}$ to the west developed in these dolomite layers. Amphibolite and chlorite schist are found along the upper or lower contact of all ore bodies (Kim et al., 1963; Park and Kim, 1966). Following the recrystallization and silicification of dolomite, tremolite and tabular and leafy talc(I) of the earlier stage formed, and microcrystalline talc(II) formed in the later stage. Talc(l) and tremolite formed by the reaction between dolomite and the fluid. Whereas talc (II) formed by the reaction between dolomite and fluid, or by the reaction between early formed tremolite and fluid. During the early stage of mineralization, the fluid was the $H_2O-CO_2$ system dominant in $CO_2$, In the later stage, the composition of the fluid changed to $H_2O-NaCl-CO_2$system, and finally to the $H_2O-NaCl$ system. The pressure and temperature conditions of the formation of tremolite associated with talc(I) were 1,640~2,530 bar, and $440{\sim}480^{\circ}C$, respectively. The pressure and temperature condition of talc(II) ore formation was 1,400~2,200 bar, and $360{\sim}390^{\circ}C$, respectively. These conditions are much lower than the metamorphic pressure and temperature of the rocks from the Munjuri Formation located about 5 km to the noJ:th of Dongyang talc deposit ${\delta}^{13}C$ and ${\delta}^{18}O$ values of dolomite which is the host rock of the talc ore deposit are 2.9~5.7‰ (PDB), and -7.4~l6.8‰ (PDB), respectively. These values are little higher than those from the Cambro-Ordovician limestones of the Taebaeksan region, but belong to the range of the unaltered sedimentary dolomite. ${\delta}^{18}O$and ${\delta}D$ values of the talc from Dongyang deposit are 8.6~15.8‰ (vs SMOW), and -65~-90‰ (vs SMOW), respectively, belonging to the range of magmatic origin. These values are quite different from those measured in the metamorphic rocks of Munjuri and Kyemyungsan Formation. ${\delta}^{34}S$ value of anhydrite is 22.4‰ (CDT), which is much lower than ${\delta}^{34}S$ (30‰ vs COT) of sulfate of early Paleozoic period, and indicates the possibility of the addition of magmatic sulfur to the system. Talc ores show the textures of weak foliation and well developed crenulation cleavages. Talc ore deposit in the area is concluded as hydrothermal replacement deposit formed before the latest phase of the deformations that Ogcheon Belt has undergone.

• Economic and Environmental Geology
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• v.11 no.4
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• pp.127-141
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• 1978

The major structures characteristic of the Taebaegsan sedimentary basin were regionally analyzed with special reference to its southeastern extension to the Yeonhwa-Ulchin district of economic interest in zinc-lead mineralization. The basin geometry, basement setting, sedimentary components, and the characteristics of deformation and igneous activity of the Taebaegsan basin differ basically from those of the adjacent mobile belt of the Ogcheon geosyncline, although the latter affected the basin's western side considerably. The subrectangular shape of the Taebaegsan basin reflects the checkered pattern of basement-block arrangement, and the carbonate-dominated lithologic components of the basin-fill indicate a cratonic depositional setting, which is comparable to some of the North American mid-continental craton. The Taebaegsan basin, however, has somewhat been less stable than the North American megacraton that is reflected in the former's thicker sedimentary fill and steeper faults of later deformation, showing a tendency to increase in thickness close to the basement-block boundaries, which may indicate contacts of possibly detached cratonic blocks of Precambrian age; these weak zones of block boundaries have been the loci of repeated sedimentation, deformation and related igneous intrusions. A series of downthrown or uplifted tilted blocks, in which the Cambro-Ordovician sedimentary wedges and the late Cretaceous to early Tertiary igneous intrusives are involved, occurs intermittently across the Yeonhwa-Ulchin district in a noticeable pattern of en echelon type. These sedimentary wedges are correlated to the Cambro-Ordovician section of the Hambaeg syncline to the west in stratigraphy and lithology, and are considered to have resulted from the northeastern and/or northwestern cross-faulting of the pre-existing syncline belt of easterly trend, extended from the main portion of the Hambaeg syncline. These structural junctions (or intersections) of the earlier syncline belt and the later cross-faults have been acted as a guide to ascending igneous materials and hydrothermal ore-forming fluids to form a zone of zinc-lead skarn deposits across the Yeonhwa-Ulchin district showing a stepwise recurrence of these deposits toward the east.

• Economic and Environmental Geology
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• v.45 no.6
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• pp.599-622
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• 2012

The phase I soil geochemical exploration was carried out targeting around Chau Binh area far from about 14 km with southeastern direction from Quy Chau within Nghe An province. The interval of sampling are horizontal 300 m with 14 line and longitudinal 500 m with 15 line, resulting in 194 soil samples. Based on the result of the phase I soil geochemical exploration, the phase II detailed pitting survey was carried out targeting the grid point with high TREO content, resulting in 56 soil samples within 7 pits. The geology of survey area are consisted of Ban Chieng biotite granite complex and Dai Loc gneissic granite complex intruding Bu Khang formation comprising of schist, gneiss and limestone. Main mineralization in the study area have the characteristics of occurrence with tin, ruby and REE-bearing monazite(about 300 g/t) and xenotime(about 10 g/t) to be thought as occurring at the alteration zone of granite complex. In order to elucidate the source rock of monazite and xenotime confirmed from heavy sand, soil geochemical exploration was carried out. As a analysis result with ICP-MS on the soil samples from the phase I soil geochemical exploration, total REE oxide content of background amount to about 2 times of crustal abundance, enriching the heavy rare earth(about 2 times) and light rare earth(about 1.84 times). As a analysis result with ICP-MS on the soil samples from the phase II soil detailed pit survey, we identified outcrop considering as economic ore body at the grid point 4-7 pit with N40W attitude. As a synthetic consideration on the phase I soil geochemical exploration and phase II detailed pit survey, we tentatively designated areas considering as the extension of economic ore body with REE anomaly. In the near future, we have the plan to carry out the geophysical exploration and test drilling targeting the interval anticipated to the economic ore body.

• Journal of the Mineralogical Society of Korea
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• v.16 no.4
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• pp.333-339
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• 2003

A new mineral, Zn analogue of rancieite (Chimooite), has been discovered at the Dongnam mine, Korea. It occurs as compact subparallel fine­grained flaky or acicular aggregates in the massive manganese oxide ores which were formed by supergene oxidation of rhodochrosite­sulfide ores in the hydrothermal veins trending NS­N25E and cutting the Pungchon limestone of the Cambrian age. The flakes of chimooite are 0.2 mm for the largest one, but usually less than 0.05 mm. The acicular crystals are elongated parallel to and flattened on (001). This mineral shows gradation to rancieite constituting its marginal part, thus both minerals are found in one and the same flake. Color is bluish black, with dull luster and brown streak in globular or massive aggregates. Cleavage is perfect in one direction. The hardness ranges from 2.5 to 4. Under reflected light it is anisotropic and bireflectant. It shows reddish brown internal reflection. Chemical analyses of different parts of both minerals suggest that rancieite and chimooite constitute a continuous solid solution series by cationic substitution. The empirical chemical formula for chimooite has been calculated following the general formula, $R_2_{x}$ M $n^{4+}$$_{9­x}$ $O_{18}$ $.$n$H_2O$ for the 7 $\AA$ phyllomanganate minerals, where x varies from 0.81 to 1.28 in so far studied samples, thus averaging to 1.0. Therefore, the formula of Zn­rancieite is close to the well­known strochiometric formula $_Mn_4^{4+}$ $O_{9}$ $.$4$H_2O$. The mineral has the formula (Z $n_{0.78}$N $a_{0.15}$C $a_{0.08}$M $g_{0.01}$ $K_{0.01}$)(M $n^{4+}$$_{3.98}$F $e^{3+}$$_{0.02}$)$_{4.00}$ $O_{9}$ $.$3.85$H_2O$, thus the ideal formula is (Zn,Ca)M $n^{4+}$$_4$ $O_{9}$ $.$3.85$H_2O$. The mineral has a hexagonal unit ceil with a=2.840 $\AA$ c=7.486 $\AA$ and a : c = 1 : 2.636. The DTA curve shows endothermic peaks at 65, 180, 690 and 102$0^{\circ}C$. The IR absorption spectrum shows absorption bands at 445, 500, 1630 and 3400 c $m^{1}$. The mineral name Chimooite has been named in honour of late Prof, Chi Moo Son of Seoul National University.ity.versity.ity.y.