• Journal of Soil and Groundwater Environment
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• v.9 no.1
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• pp.1-11
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• 2004

Foam reduces the mobility of gas phase in porous media to overcome gravity override and to divert acid into desired layers in the petroleum industry and to enhance the efficiency of environmental remediation. Recent experimental studies on foam show that foam exhibits a remarkably different flow rheology depending on the flow regime. This study, for the first time, focuses on the issues of foam diversion process under the conditions relevant to groundwater remediation, combining results from laboratory linear-flow experiments and a simple numerical model with permeability contrasts. Linear flow tests performed at two different permeabilities (k = 9.1 and 30.4 darcy) confirmed that two flow regimes of steady-state strong foams were also observed within the permeability range of shallow geological formations. Foam exhibited a shear-thinning behavior in a low-quality regime and near Newtonian rheology in a high-quality regime. Data taken from linear flow tests were incorporated into a simple numerical model to evaluate the efficiency of foam diversion process in the presence of permeability contrasts. The simple model illustrated that foam in the high-quality regime exhibited a successful diversion but foam in the low-quality regime resulted in anti-diversion, implying that only foam in the high-quality regime would be applicable to the diversion process. Sensitivity study proved that the success of diversion process using foam in the high-quality regime was primarily controlled by the limiting capillary pressures (${P_c}{^*}$) of the two layers of interest. Limitations and implications are also discussed and included.

• Journal of the Korea institute for structural maintenance and inspection
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• v.14 no.4
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• pp.141-147
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• 2010

Liquefied natural gas(LNG) is natural gas that has been converted temporarily to liquid form for ease of storage and transport it. Natural gas is the worlds cleanest burning fossil fuel and it has emerged as the environmentally preferred fuel of choice. In Korea, the demand of this has been increased since the first import from the Indonesia in 1986. LNG takes up about 1/600th the volume of natural gas in the gaseous state by cooling it to approximately $-162^{\circ}C(-260^{\circ}F)$. The reduction in volume therefore makes it much more cost efficient to transport and store it. Modern LNG storage tanks are typically the full containment type, which is a double-wall construction with reinforced concrete outer wall and a high-nickel steel inner tank, with extremely efficient insulation between the walls. The insulation will be installed to LNG outer tank for the isolation of cryogenic temperature. The insulation will be installed in the base slab, wall and at the roof. According to the insulation's arrangement, the different aspects of temperature transmission is shown around the outer tank. As the result of the thermal & stress analysis, by the installing cellular glass underneath the perlite concrete, the temperature difference is greatly reduced between the ambient temperature and inside of concrete wall, also reducing section force according to temperature load.

• Journal of Radiation Protection and Research
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• v.33 no.1
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• pp.35-40
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• 2008

A distillation tower is one of the important facilities which separates and refines a crude oil stream according to certain boiling points. Its operation efficiency can affect the productivity of a refinery substantially. The objective of this study is to elucidate some operational information on the internal conditions of a distillation tower from a measurement of density profile by using a sealed gamma-ray source and a radiation detector. Gamma radiation counts were measured by a BGO detector positioned diametrically outside the tower-wall, opposite to the gamma source(Co-60) as the detector and the source were lowered concurrently. From the results, structural abnormality of the trays was not found inside the tower. Considering the flow distribution patterns, however, a vapor phase was dominantly formed at the upper part of the tower and a liquid phase at the lower part. From the gamma scanning of the distillation tower, it is anticipated that the gamma absorption technique can be used as an important tool for confirming the structural soundness of trays and investigating flow distribution in refinery facilities.

• Proceedings of the Membrane Society of Korea Conference
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• 1996.06a
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• pp.91-120
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• 1996

경제발전과 더불어 산업의 많은 분야에서 순수 및 초순순의 사용이 증가하고 있으나, 환경오염에 의한 원수의 오염에 따라 순수 및 초순순제조의 장치비와 처리비용의 증가가 야기되고 있다. 현재 국내에는 화력, 원자력발전소를 비롯하여 열병합발전소, 석유화학공장, 제약회사, 전기 전자부품회사, 반도체회사 및 철강회사 등 많은 분야에서 순수 및 초순수 제조장치의 구성과 성능이 많은 차이를 나타내고 있다. 국내의 초순수 제조장치는 90% 이상이 이온교환수지를 사용하는 이온교환법과 UF, R/O System과 같은 Membrane을 사용하는 Membrane System을 병행하여 적용하고 있다. 국내 초순수처리 Plant에서는 통상 전처리 System과 1차 순수제조 System 및 초순수 System이 상호 연결되어 Plant가 구성 운영되고 있다. 전처리 System에는 응집침전, 여과 흡착, 살균 등이 적용되고 있으며 여과 System에 Membrane을 적용할 수 있으나 국내에서는 특별한 경우를 제외하고 대부분 전처리 여과 System에 Media Filter를 사용한다. 전처리 System도 순수처리 장치의 전처리로는 없어서는 안되는 System이지만 여기에는 전처리 System을 제외하고 국내에서 적용하고 있는 초순수처리 System의 공정현황과 각 System별 특징을 설명하고 있다. 초순순 System에는 요구 수질에 따라 다소 차이가 있지만 반도체 공업에서 사용되는 초순수 System이 이중 최고의 Grade로 반도체공업에서 적용되고 있는 System을 기준하였다. 특히 Membrane을 적용한 초순수제조 System이 증가하고 있어 R/O, ED, EDR, CDI, (EDI)와 같은 Membrane System의 특성과 원리를 검토하였다.대적으로 높은 산소확산계수와 물에 대해서는 낮은 투과도를 가져야 한다. 높은 산소확산계수는 반응을 빠르게 하는 잇점이 있으며 물에 대한 낮은 투과도는 센서내의 전해질 물질을 유지보호하는 역할을 한다. 분리막이 산소전극에 이용될 경우 높은 산소 확산계수 이외에도 적절한 기계적 강도, 열적 안정성 등이 요구된다. 몰입이 가능하여 임계치가 저하된 것으로 여겨진다. 또한 광학적 이득의 존재는 이 구조에 의한 극단파장 반도체 레이저다이오드의 실현 가능성을 나타내는 것이다.548 mL에 비해 통계학적으로 의의 있게 적었다(p<0.05). 결론: 관상동맥우회로 조성수술에서 전방온혈심정지액을 사용할 때 희석되지 많은 고농도 포타슘은 fliud overload와 수혈을 피하고 delivery kit를 사용하지 않음으로써 효과적이고 만족할 만한 심근보호 효과를 보였다.를 보였다.4주까지에서는 비교적 폐포는 정상적 구조를 유지하면서 부분적으로 소폐동맥 중막의 비후와 간질에 호산구 침윤의 소견이 특징적으로 관찰되었다. 결론: 분리 폐 관류는 정맥주입 방법에 비해 고농도의 cisplatin 투여로 인한 다른 장기에서의 농도 증가 없이 폐 조직에 약 50배 정도의 고농도 cisplatin을 투여할 수 있었으며, 또한 분리 폐 관류 시 cisplatin에 의한 직접적 폐 독성은 발견되지 않았다이 낮았으나 통계학적 의의는 없었다[10.0%(4/40) : 8.2%(20/244), p>0.05]. 결론: 비디오흉강경술에서 재발을 낮추기 위해 수술시 폐야 전체를 관찰하여 존재하는 폐기포를 놓치지 않는 것이 중요하며, 폐기포를 확인하지 못한 경우와 이차성 자연기흉에 대해서는 흉막유착술에 더 세심한 주의가 필요하다는 것을 확인하였다. 비디오흉강경수술은 통증이 적고, 입원기간이 짧고, 사회

• Journal of Life Science
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• v.23 no.10
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• pp.1273-1279
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• 2013

Aromatic hydrocarbons, such as phenol, have been detected frequently in wastewater, soil, and groundwater because of the extensive use of oil products. Bacterial strains (56 isolates) that degraded phenol were isolated from soil and industrial wastewater contaminated with hydrocarbons. GN13, which showed the best cell growth and phenol degradation, was selected for further analysis. The GN13 isolate was identified as Neisseria sp. based on the results of morphological, physiological, and biochemical taxonomic analyses and designated as Neisseria sp. GN13. The optimum temperature and pH for phenol removal of Neisseria sp. GN13 was $32^{\circ}C$ and 7.0, respectively. The highest cell growth occurred after cultivation for 30 hours in a jar fermentor using optimized medium containing 1,000 mg/l of phenol as the sole carbon source. Phenol was not detected after 27 hours of cultivation. Based on the analysis of catechol dioxygenase, it seemed that catechol was degraded through the meta- and ortho-cleavage pathway. Analysis of the biodegradation of phenol by Neisseria sp. GN13 in artificial wastewater containing phenol showed that the removal rate of phenol was 97% during incubation of 30 hours. The removal rate of total organic carbon (TOC) by Neisseria sp. GN13 and activated sludge was 83% and 78%, respectively. The COD removal rate by Neisseria sp. GN13 from petrochemical wastewater was about 1.3 times higher than that of a control containing only activated sludge.

• Fire Science and Engineering
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• v.30 no.5
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• pp.1-8
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• 2016

Safety management in hazardous areas with potentially explosive gas atmospheres (here in after referred to as hazardous areas) in large scale facilities dealing with combustible or flammable materials at home and abroad is very important (significant) for the coexistence of the company and local society based on business continuity management (BCM) and reliance. For the safety management in hazardous areas, two systems are mainly used: (1) the control system for the prevention of combustible or flammable substances and (2) the explosion proof system for the elimination of ignition sources when flammable gases are leaked to inhibit the transition to fire or explosion accidents. While technology and regulations on explosion proof facilities or devices for electrical ignition sources are well developed and defined, those for thermal ignition sources need to be more developed and established. In this study, the internal combustion engine in hazardous areas was investigated to determine the risk of ignition. For this purpose, document searches were conducted on the relevant international standards and accidents cases and risk analysis reports. In addition, this study assessed the application cases of the diesel engine's safety equipment, such as spark arresters regarding the site of process safety management (PSM) system in central Korea. To practically apply these results to the hydrocarbon industry, the safety management method for explosion prevention in hazardous areas was provided by risk identification for ignition sources of internal combustion engines, such as diesel engines.

• Membrane Journal
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• v.30 no.4
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• pp.252-259
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• 2020

Olefins are industrially important materials used for the synthesis of various petrochemicals. During the polymerization process, unreacted olefin monomers are discharged together with a large amount of nitrogen. For economic benefits, these olefin gases should be efficiently separated from nitrogen. In this study, a poly(glycidyl methacrylate-co-methyl methacrylate) (PGM) comb-like copolymer was synthesized and 4,4'-diaminoazobenzene (DAAB) was introduced to the copolymer to prepare a cross-linked membrane for C₃H₆/N₂ separation. PGM and DAAB were readily reacted at room temperature through an epoxide-amine reaction without additional thermal treatment. PGM-based membrane, which is a glassy polymer, showed a faster permeation of N₂ compared to C₃H₆. The pristine PGM membrane exhibited the N₂ permeability of 0.12 barrer and the high N₂/C₃H₆ selectivity of 32.4. As DAAB was introduced as a cross-linker, the thermal stability of the membrane was significantly improved, which was confirmed by TGA result. The N₂/C₃H₆ selectivity was decreased at 1 wt% of DAAB content, but the N₂ permeability increased by approximately 4.7 times. We analyzed N₂/C₃H₆ gas separation properties through a glassy polymer-based membrane, which has not been widely studied. Also, we proposed that thermal stability of the membrane can be greatly improved by the cross-linking method.

• Environmental and Resource Economics Review
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• v.19 no.2
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• pp.413-440
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• 2010

Since 2000, as importance of sourcing energy emphasized caused by instability of international oil price, interests toward Caspian countries as an alternative markets has increased. Especially, Azerbaijan, as middle Asian emerging exporting country, has performed drastic economic boom because of massive amount of foreign capital flowed in and construction of BTC pipeline. However, despite this economic surge, there are unbalanced economy which is merely focusing on energy industry and pressure from increase in real exchange rate and inflation. In order to analyze the sustainability of Azerbaijan economy, the total sample time period of this paper is from January 2001 to December 2007 and the term is divided into before and after BTC line construction. Vector Error-Correction Model has been applied to analysis confirming short-term and long-term effect. As a result, Azerbaijan now face the symptoms of the recession during the time period and this is due to high oil price and increase in export influenced by BTC oil pipeline resulting in decrease in real interest rate. This conclusion is to affect competitiveness of manufacturing industry, base industry for economic proliferation, in a negative way.

• Korean Chemical Engineering Research
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• v.46 no.4
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• pp.732-738
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• 2008

Simulated moving bed (SMB) process is a continuous chromatographic technology used to separate a large amount of petrochemicals, fine chemicals, pharmaceuticals, and so on, drawing a great attraction of related industries. With the recent development of biotechnology, the SMB process has been adopted for the separation of various useful bio-products. Attempts to understand the separation mechanism of the SMB process in many aspects are reported in many publications. These researches have dealt with the improvement of SMB for easier operation and solving problem in process. The feed mixture fed into the SMB process may be of different concentration batch by batch rather than in uniform concentration. Retention behaviors of feed (psicose (A) and fructose (B) mixture) existing in the SMB unit in dynamic steady-state and feed (psicose (C) and fructose (D) mixture) newly injected into the SMB were analyzed. It was observed that the existing components, (A) and (B), were eluted relatively faster as the injection time of new feed was earlier during the port-switching period. In addition, the components (C) and (D) were eluted earlier as fresh feed was injected earlier in a port-switching time.

• Journal of Environmental Policy
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• v.7 no.4
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• pp.1-34
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• 2008

It is recognized that RPS(Renewable Portfolio Standard) and FIT(Feed-in Tariff) are two main policy instruments to promote Renewable Electricity(RE). The Korean Government announced in 2008 that RE promotion scheme will be changed to RPS from current FIT system in 2012. But we believe RPS is inferior to FIT for promoting less developed technologies such as photovoltaics or wind power. This is because the achievement of RE promotion in countries adopting RPS is markedly worse than that in European counties or Janpan adopting FIT. If the policy change is inevitable, when considering the lessons from Japan's failure as well as supporting the less developed technologies, it is recommended that either the market should be divided into several technology and scale categories, or more RPS-Credit per kWh should be assigned to the photovoltaic and wind power than instead of letting the all technologies compete in the "open category". It is also recommended that (1) Renewable Energy Promotion Fund(tentative name) based on a part of current energy related tax revenue should be introduced, or (2) cost of supporting the Renewable Electricity should automatically be transferred into the electricity bill of electricity consumers following the German System.