• Title/Summary/Keyword: 석유화학

Search Result 882, Processing Time 0.025 seconds

A Study on Competitiveness and Effect Analysis for Developing a Port Specialized in Northern Sea Route (경쟁력분석에 따른 국내 북극항로 전진기지 구축방안에 관한 연구)

  • Park, Jin-Hee;Lee, Min-Gyu
    • Journal of Navigation and Port Research
    • /
    • v.39 no.3
    • /
    • pp.241-251
    • /
    • 2015
  • Recently, It became possible to transport freights and energy resources via Northern Sea Route(NSR) as global warming has been accelerated. As a result, all countries of the world and Korean local governments have had a struggle to take the advantageous position first in NSR development. However, this extreme competitions might have a negative effect on the national port industry and cause unnecessary social costs and economic losses. Therefore, the main target of this study is to find the most suitable port for NSR using AHP analysis. Most of the data was gained from previous literatures and public statistics and the weight of each factor was calculated by the result of expert survey. As a result, Busan port has the biggest competitiveness, followed by Yeosu Gwangyang, Ulsan and Incheon. From the result, this study suggested 3 possible scenarios. The first scenario specializing Busan port in NSR focuses more on developing the related businesses such as repair of ships, refueling, ship stores trade than attracting the more cargoes. the second is a strategy to make Ulsan port as a hub for energy resources, especially liquid cargo on NSR. the last is a mixed one to assign suitable roles to the ports according to their competitive capabilities.

Prediction of Leachate Migration from Waste Disposal Site to Underground LPG Storage Facility and Review of Contamination Control Method by Numerical Simulations (수치모의를 통한 지하 LPG 저장시설에 인접한 폐기물매립지에서의 침출수이동 예측 및 제어공법 검토)

  • 한일영;서일원;오경택
    • Journal of the Korean Society of Groundwater Environment
    • /
    • v.3 no.2
    • /
    • pp.51-59
    • /
    • 1996
  • In case waste disposal site is to be constructed close to the underground facilities such as LPG storage cavern which is completely maintained by groundwater pressure, it is generally requested that the possibility on leachate contamination of cavern area be reviewed and the countermeasure, if it is estimated cavern area is severely affected by leachate, be taken into consideration. Prediction was performed and leachate control plan was made using by analytical and the numerical analysis on the leachate migration which is likely to happen at the area between the proposed waste disposal site and the underground LPG storage cavern located at the U petrochemical complex. Analytical solutions were obtained by the conservative mass advection-diffusion equation and the effect of advection and dispersion factor on the leachate migration was reviewed through peclet number calculation and the functional relationship between the factors and leachate transport velocity was established, which leads to enable us to predict the leachate transport velocity without difficulties when different parameters (factors) are used for analytical solution. Numerical solutions were obtained by FEM using AQUA2D which is for the simulation of groundwater flow and contaminant transport. 3-D discrete fracture models were simulated and fracture flow analysis was performed and feasibility study on the water-curtain system was conducted through the fracture connectivity analysis in rock mass. As results of those analyses, it was interpreted that the leachate would trespass on the LPG storage cavern area in 30 years from the proposed wate disposal site and the vertical water-curtain system was effective mathod for the prevention of leachate's migration further into the cavern area.

  • PDF

자성유체 윤활제의 개발 동향

  • 김영규;심우전;김청균
    • Tribology and Lubricants
    • /
    • v.12 no.1
    • /
    • pp.1-5
    • /
    • 1996
  • 자성유체는 자연에서 추출한 것이 아니라 자화성(Magnetizability)과 유도성(Flowability)을 동시에 갖도록 합성한 특수액체이다. 자성유체는 1960년대 중반에 미국의 NASA에서 처음 개발된 이후로 윤활, 밀봉, 감쇄, 의료 등의 분야에서 응용연구가 많이 진행되었기 때문에 고도의 정밀도를 요하는 항공, 우주산업, 컴퓨터와 반도체 분야 등에서 실용화가 크게 진전되고 있다. 특수물질일 자성유체는 전기적으로 도체인 10nm 정도의 미세한 자기입자(Magnetic particles)에 코팅을 한 후, 이것을 물, 탄화수소, 플루오르카본, 에스터 등의 매개유체(Carrier Fluids)에 혼합시켜서 콜로이드 상태로 사용하게 된다. 자성유체는 미세한 자기입자들이 매개유체내에서 서로 충돌하면서 반발력을 발생시켜서 상호간에 늘 콜로이드 상태를 유지하고 있으며, 이 특수유체가 자기장의 영향을 받게 되면 점도가 증가하면서 특이한 성질을 갖게 된다. 상대 접촉 운동면에 경계마찰이나 혼합마찰을 하게 되면 윤활상태는 비교적 나쁘다. 이러한 마찰지역에 콜로이드상의 자성유체 윤활제를 공급하면 기존의 윤활제에 비하여 대단히 효과적으로 윤활을 할 수 있게 된다. 그러나 자성유체 윤활제가 마찰부위에 원활하게 공급하기 위해서는 미끄럼 마찰부에서 자기장을 잘 형성시킬 수 있는 도체이어야 하기 때문에 특별한 윤활 시스템 설계가 제시되어야 한다. 자성유체 윤활제는 합성으로 제조된 특수물질로 여러가지 장점을 갖고는 있으나 기존 윤활유와의 적합성, 마찰열, 밀봉압력 등의 조건에서 제한적으로 사용될 수 밖에 없으므로 항공, 우주 산업이나 석유 화학분야와 같이 특수 환경에서만 사용되고, 또한 기존의 광유계 윤활제에 비하여 대단히 고가하는 문제점을 갖고 있다. 그러나 윤활 마찰면의 다양화와 가혹한 사용조건은 자성유체 윤활제의 연구개발 필요성을 크게 증대시키고 있다.xed Effects Model)을 결정하고, 각각에 해당하는 통계모형을 구축하였다. 이 결과 (1) 업종 및 기업규모별로 그룹간에 유의한 특성이 발견되었으며, (2) R&D 및 광고투자는 기업의 시장성과를 설명하는 중요한 변수이나, (3) R&D 투자의 경우는 광고에 비해 불확실성이 존재하는 것으로 나타났고, (4) 수리모형에서 도출된 한계원리가 통계모형에서도 유효한 것으로 드러났다.등을 토대로 한 10대 산업을 육성하기 위하여 과학기술부는 기술수요조사를 바탕으로 49개 주요기술을 도출하여, 과학기술 일류 국가 실현, 국민소득 2만불 달성이라는 국가적 슬로건을 내걸고 “차세대 성장동력” 창출을 위한 범정부차원의 기획과 연구비의 집중투자를 추진하고 있다.달성하기 위해서는 종합류류 전산망의 시급한 구축과 함께 화물차의 적재율을 높이고 공차율을 낮출 수 있는 운송체계의 수립이 필요한 것으로 판단된다. 그라나 이러한 화물전용차선의 효과는 단기적인 치유책일 수밖에 없기 때문에 물류유통 시설의 확충을 위한 사회간접자본의 구축을 서둘러 시행하여야 할 것이다.으로 처리한 Machine oil, Phenthoate EC 및 Trichlorfon WP는 비교적 약효가 낮았다.>$^{\circ}$E/$\leq$30$^{\circ}$NW 단열군이 연구지역 내에서 지하수 유동성이 가장 높은 단열군으로 추정된다. 이러한 사실은 3개 시추공을 대상으로 실시한 시추공 내 물리검층과 정압주입시험에서도 확인된다.. It was resulted from increase of weight of single cocoon. "Manta"2.5ppm produced 22.2kg of cocoon. It is equal to 9% increase in index, as compared to that of control. In case

Application of Regional Landslide Susceptibility, Possibility, and Risk Assessment Techniques Using GIS (GIS를 이용한 광역적 산사태 취약성, 가능성, 위험성 평가 기법 적용)

  • 이사로
    • Economic and Environmental Geology
    • /
    • v.34 no.4
    • /
    • pp.385-394
    • /
    • 2001
  • There are serious damage of people and properties every year due to landslides that are occurred by heavy rain. Because these phenomena repeat and the heavy rain is not an atmospheric anomaly, the counter plan becomes necessary. The study area, Ulsan, is one of the seven metropolitan, and largest cities of Korea and has many large facilities such as petrochemical complex and factories of automobile and shipbuilding. So it is necessary assess the landslide hazard potential. In the study. the three steps of landslide hazard assessment techniques such as susceptibility, possibility, and risk were performed to the study area using GIS. For the analyses, the topographic, geologic, soil, forest, meteorological, and population and facility spatial database were constructed. Landslide susceptibility representing how susceptible to a given area was assessed by overlay of the slope, aspect, curvature of topography from the topographic DB, type, material, drainage and effective thickness of soil from the soil DB, lype age, diameter and density from forest DB and land use. Then landslide possibility representing how possible to landslide was assessed by overlay of the susceptibility and rainfall frequency map, Finally, landslide risk representing how dangerous to people and facility was assessed by overlay of the possibil. ity and the population and facility density maps The assessment results can be used to urban and land use plan for landslide hazard prevention.

  • PDF

Review of the CO2 Geological Storage Using Nanoparticle-stabilized CO2 Foam (나노입자기반 CO2 폼을 이용한 CO2 지중저장에 대한 기술적 고찰)

  • Son, Han Am
    • Economic and Environmental Geology
    • /
    • v.53 no.2
    • /
    • pp.213-220
    • /
    • 2020
  • When CO2 foam is injected into the saline aquifer, the relative permeability of CO2 decreases and its viscosity increases, thereby reducing mobility in porous media and ultimately improving CO2 storge with enhanced sweep efficiency. In general, surfactants were used to fabricate CO2 foam. Recently, nanoparticles have been used to form stable foam than surfactant. This paper introduces CO2 storage technology using nanoparticle stabilized CO2 foam. If the surface of the hydrophilic nanoparticles is partially modified into a CO2-philic portion, the particles have an affinity for CO2 and water, thus forming a stable CO2 foam even in deep saline aquifers under high temperature and high salinity conditions, thereby it can be stored in the pores of the rock. In terms of economics, injection method using nanopaticle-stabilized CO2 foam is more expensive than the conventional CO2 injection, but it is estimated that it will have price competitiveness because the injection efficiency is improved. From an environmental point of view, it is possible to inject chemical substances such as surfactants and nanomaterials into aquifers or reservoirs for specific purposes such as pollutant removal and oil production. However, some studies have shown that nanoparticles and surfactants are toxic to aquatic animals, so environmentally proven substances should be used. Therefore, further research and development will be needed to study the production and injection of nanoparticle-stabilized CO2 foam that are environmentally safe and economically reasonable.

The Study for Identification of waterborne Spilled Oil by Fast Gas Chromatography (Fast GC를 이용한 해상유출유 감식ㆍ분석 기법 연구)

  • Chung J. W.;Lee W.S.;Yoon J. Y.;Kim H. G.
    • Journal of the Korean Society for Marine Environment & Energy
    • /
    • v.7 no.3
    • /
    • pp.122-130
    • /
    • 2004
  • Crude oil is complex mixture of thousands of different organic compound formed from a variety of organic materials that are chemically converted under differing geological conditions over long periods of time. Also oil composition varies according to crude source, refining, processing, handling and storage. The oil fingerprint method is application of specific knowledge of petrochemicals and use of sophisticated analytical equipment and techniques to identify the source(s) of oil pollution. KNMPA currently utilizes three primary analytical techniques: Gas Chromatography (GC), Fluorescence Spectroscopy(FL) and Infrared Spectroscopy(IR). Of all these techniques, GC technique are most widely used. Gas Chromatography is used as a primary analytical method because high reliableness, high separating efficiency and repeatability, but it is timeconsumable. The study results of identification of waterborne spilled oil by Fast Gas Chromatograph method showed that analytical time is cut down to 30minutes in comparison with packed column method and chromatograms represent high resolution and high repeatability.

  • PDF

Competitiveness of Energy Intensive Manufacturing Industries on Greenhouse Gas Mitigation Policies: Using Price Setting Power Model (온실가스 저감정책에 대한 에너지 다소비 제조업의 경쟁력 분석: 가격설정력 모형을 이용하여)

  • Han, Minjeong;Kim, Youngduk
    • Environmental and Resource Economics Review
    • /
    • v.20 no.3
    • /
    • pp.489-529
    • /
    • 2011
  • When greenhouse gas mitigation policies are implemented, energy intensive manufacturing industries are influenced much due to an increase in cost. However, industries that have price setting power are damaged less by the policies. Therefore, this paper analyzes vulnerability of energy intensive manufacturing industries to the policies by measuring price setting power of the industries. We analyzed price setting power model through ECM, employing the import prices and wages as independent variables. The industries that their prices react to import prices are price takers, which their prices are determined by rival's ones. On the other hand, the industry that their prices react to wages that mean domestic cost are price setters, and they will be less vulnerable to the policies. In addition, fluctuation of energy prices would be reflected in import prices because it influences other countries than my one. Thus, we employed energy prices as control variable to measure the net effects of import prices. As empirical results, petroleum products, chemical products, non-metallic mineral products, textiles, and motor vehicles sector have price setting power, so the industries have competitiveness on greenhouse gas mitigation policies.

  • PDF

The Enlargement of EU and the Flows of Direct Investment within EU (유립연합 형성과 역내 직접투자 흐름)

  • Moon, Nam-Cheol
    • Journal of the Korean association of regional geographers
    • /
    • v.10 no.2
    • /
    • pp.371-388
    • /
    • 2004
  • EU is enlarging geographically by the process of expansion and is intensifying the economic bloc by the formation of European Union and European Monetary Union. This situation increases the direct investment in the intra-EU members and changes the intra-EU flows. First, EU is formed by the economic geographical space of the North and the South with a differentiation of economic factors and the degree of economic development. The North played a leading role for an augmentation of the intra-EU direct investment after the formation of EU. Second, the manufacturing industry of the intra-EU direct investment by industry was increased remarkably. In the intra-EU direct investment flow by region and industry, the South made relatively an outflow of the service industry and an inflow of the manufacturing industry. But the North made an outflow of the manufacturing industry and an inflow of the service industry. Third, in the intra-EU direct investment flows by manufacturing industry, the North concentrated in the petro-chemistry, metal-machinery and agro-food industry, however, the South which have relatively weak competitiveness compared to the North tends to show balanced investment patterns in all industries.

  • PDF

Characteristics of Metal-Phthalocyanine for Catalytic Combustion of Methanol (메탄올의 촉매연소에 대한 금속-프탈로시아닌의 특성)

  • Seo, Seong-Gyu;Yoon, Hyung-Sun;Lee, Sun-Won
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.22 no.10
    • /
    • pp.1809-1816
    • /
    • 2000
  • The catalytic combustion of methanol as a model volatile organic compound(VOC) was been investigated over metal-phthalocyanine(PC) in a fixed bed flow reactor system. The catalytic activity of Co-PC pretreated with air and methanol mixture at $450^{\circ}C$ and 60 cc/min for 1 hr was very excellent. The order of catalytic activity on methanol combustion was summarized as follows: metal free-PC < Zn-PC < Fe-PC < Cu($\alpha$)-PC < Co-PC. By TG/DTA analysis, the tendency of thermal decomposition was increased as follows: metal free-PC < Zn-PC < Cu($\alpha$)-PC < Co-PC < Fe-PC. Under this pretreatment condition, the basic structures of Co-PC, Cu($\alpha$)-PC and Fe-PC were destroyed, and the new metal oxide such as $Co_3O_4$ from Co-PC was confirmed by EA and XRD analysis. But Zn-PC and metal free-PC were retained its basic structure under this pretreatment condition. On the combustion of methanol over Co-PC, HCHO and $HCOOCH_3$ were observed as an intermediate products in the high concentration of reactant or the short contact time(W/F).

  • PDF

가교키토산 복합막을 이용한 에틸렌글리콜/물 혼합액의 투과증발분리

  • 남상용;이영무
    • Proceedings of the Membrane Society of Korea Conference
    • /
    • 1996.10a
    • /
    • pp.82-83
    • /
    • 1996
  • 키토산 막을 이용한 유기혼합물 중의 물을 효율적으로 분리해내는 투과증발공정은 많은 발전을 거듭해 왔으며, 특히 에탄올중의 물을 효율적으로 탈수하는 것에는 탁월한 성능을 보고한 바 있다. 키토산은 주로 게등의 갑각류의 외피에서 얻을 수 있는 키닌을 주원료로 하는 물질로서 친수성이 뛰어난 막재료뿐만 아니라 생체적 합성이 요구되는 생체재료로도 널리 사용이 되고 있는 물질이다. 에틸렌즐리콜은 석유화학공정에서 생성되는 에틸렌 옥시이드를 원료로 하여 제조가 되고 있는 물질이다. 에틸렌글리콜은 PET의 원료로서 사용이 많이 되고 있으며, 겨울철에는 자동차등의 부동액이나 눈이 많이 내리는 지역에서 효율적으로 눈을 제거하기 위하여 공항의 활주로등에서 주로 사용이 되고 있는 물질이다. 에틸렌글리콜의 제조공정중에서 물을 효과적으로 제거하는 방법으로는 증류법이 있을 수 있으나 에틸렌글리콜의 비점이 물보다 현저히 높기 때문에, 공비혼합물을 생성하지 않는 이 혼합물의 특성과는 무관하게, 투과증발법을 이용할 경우 에너지의 절감이 이루어지게 되기 때문에 매우 효용적이고 추천할만할 공정이다. 또한 활주로의 부동액등으로 사용되는 경우 에틸렌글리콜의 재활용이 이루어질 경우 경비의 절감이나 환경적인 문제의 해결등의 장점이 있어서 물의 분리가 요구되고 있다. 이 경우에는 마찬가지로 에틸렌글리콜과 물의 분리는 일반적인 분리에 비해서 투과증발법이 유용하다고 할 수 있다. 본 실험에서는 키토산 막의 효율적인 응용예로서 기존의 알콜의 탈수와 더불어서 에틸렌글리콜의 탈수를 고찰해보고자 하였다.관리가 간편하며, 용존산소량을 줄일수 있다는 점에서 장점이 있으나, 전 ultra pure water의 system이 열적으로 안정해야 하고 경제적인 문제가 수반하는 단점을 가지고 있다. 후자의 경우, 미량의 과산화수소수 (1~10,000 ppm)를 이용해 처리 해주는 방법의 경우 경제적으로 큰 장점이 있고, 처리가 단순하다는 장점이 있으나 과산화수소수 자체에 포함하고 있는 높은 impurit level, 그리고 처리후 장시간의 flushing time을 가져야 한다는 단점등이 존재 하고 있다.요구된다. 몰입이 가능하여 임계치가 저하된 것으로 여겨진다. 또한 광학적 이득의 존재는 이 구조에 의한 극단파장 반도체 레이저다이오드의 실현 가능성을 나타내는 것이다.548 mL에 비해 통계학적으로 의의 있게 적었다(p<0.05). 결론: 관상동맥우회로 조성수술에서 전방온혈심정지액을 사용할 때 희석되지 많은 고농도 포타슘은 fliud overload와 수혈을 피하고 delivery kit를 사용하지 않음으로써 효과적이고 만족할 만한 심근보호 효과를 보였다.를 보였다.4주까지에서는 비교적 폐포는 정상적 구조를 유지하면서 부분적으로 소폐동맥 중막의 비후와 간질에 호산구 침윤의 소견이 특징적으로 관찰되었다. 결론: 분리 폐 관류는 정맥주입 방법에 비해 고농도의 cisplatin 투여로 인한 다른 장기에서의 농도 증가 없이 폐 조직에 약 50배 정도의 고농도 cisplatin을 투여할 수 있었으며, 또한 분리 폐 관류 시 cisplatin에 의한 직접적 폐 독성은 발견되지 않았

  • PDF